• 분석과학
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• 제16권6호
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• pp.450-457
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• 2003

사용후핵연료 내 U 및 동위원소 정량분석을 동위원소 희석 질량분석법 (isotope dilution mass spectrometry, IDMS)으로 수행하였다. 시료는 산화우라늄 사용후핵연료 시료를 $HNO_3$(1+1) 또는 이 용액과 14 M $HNO_3-0.05M$ HF 혼합용액으로 용해한 후 막 거르게 ($1.2{\mu}m$)로 여과하여 준비하였다. 시료 및 스파이크를 첨가한 시료 중의 U은 AG lX8 음이온교환 수지관에서 0.1 M HCl 용액으로 용리하였다. 시료 중의 총 U 량과 성분 동위원소 ($^{234}U$, $^{235}U$, $^{236}U$ 및 $^{238}U$)의 조성은 $^{233}U$을 스파이크로 이용하는 동위원소 희석 질량분석법으로 정량하였다. 제조한 U-233 스파이크 용액은 천연 및 감손 U을 이용한 역동위원소 희석 질량분석법 (reverse isotope dilution mass spectrometry, R-IDMS)으로 표정하였다. 동위원소 희석 질량분석법에 의한 핵연료시료 중의 총 U 량 측정결과를 전위차 적정으로 측정한 결과와 비교하였을 때 0.34% 평균 상대오차 범위에서 일치하였다.

• 대한기계학회논문집B
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• 제33권7호
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• pp.477-485
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• 2009

The study of nitrogen dilution effect on the flame stability was experimentally investigated in a non-premixed turbulent lifted hydrogen jet with coaxial air. Hydrogen gas was used as a fuel and coaxial air was used to make flame liftoff. Each of hydrogen and air were injected through axisymetric inner and outer nozzles ($d_F=3.65\;mm$ and $d_A=14.1\;mm$). And both fuel jet and coaxial air velocity were fixed as $u_F=200\;m/s$ and $u_A=16\;m/s$, while the mole fraction of nitrogen diluents gas was varied from 0.0 to 0.2 with 0.1 step. For the analysis of flame structure and the flame stabilization mechanism, the simultaneous measurement of PIV/OH PLIF laser diagnostics had been performed. The stabilization point was selected in the most upstream region of the flame base and defined as the point where the turbulent flame propagation velocity was equal to the axial component of local flow velocity. We found that the turbulent flame propagation velocity increased with the decrease of nitrogen mole fraction. We concluded that the turbulent flame propagation velocity was expressed as a function of turbulent intensity and axial strain rate, even though nitrogen diluents mole fraction was changed.

• 한국가스학회지
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• 제12권2호
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• pp.77-84
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• 2008

제트상사성 이론에 의해 잘 이해되어온 층류부상화염의 부상화염 거동에 대해 연료 노즐 직경 변화 효과를 통한 부력효과의 중요성을 밝히기 위한 실험적 연구를 수행하였다. 부력 효과를 평가하기 위해 연료노즐 직경을 $0.1{\sim}6\;mm$ 정도의 크기까지 변화시켰고, 헬륨을 희석제로 프로판과 메탄 화염을 순수 연료로부터 희석하면서 부상 거동을 체계적으로 관찰하였다. 부상화염 거동 설명을 위해 중요 물리 변수인 희석율로 표현되는 연료강도, 화염 스트레치, 화염 곡률 효과로 부상 거동을 체계적으로 설명하기 위해 척도 법칙(scaling law)을 통한 중요 물리 변수를 실험 변수로 유도하였다. 노즐 직경이 큰 경우와 연료 희석율이 큰 경우에 대해서는 부력 효과가 중요하다는 것을 실험 결과로부터 입증하였다. 또한, Chen 등의 결과에 따라 0.5

• 한국연소학회:학술대회논문집
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• 한국연소학회 2001년도 제23회 KOSCO SYMPOSIUM 논문집
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• pp.90-96
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• 2001

Catalytic ignition of $H_2/O_2/CO_2$ mixtures over platinum catalyst is experimentally investigated by using microcalorimetry. For comparison, $N_2$ and Ar is also used as diluent gas. The gas mixture flows toward platinum foil heated by electric current at atmosphere pressure and ambient temperature. The ignition temperature range 350-445K according to the fuel ratio, dilution ratio and diluent gas. It increases as the fuel ratio and dilution ratio increase. $H_2/O_2$ mixture with $CO_2$ ignites at higher temperature than with other diluents by 30-50K. Several experimental evidences show the inhibition effects of $CO_2$ in $H_2-O_2$ heterogeneous reaction is considerable

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 2004년도 학술대회지
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• pp.233-236
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• 2004

An experimental study was conducted to evaluate characteristic variation of diluted engine oil by diesel fuel and its effects on engine components. Especially, engine oil was made to have $15\%$ fuel content. To predict existing diesel fuel content in engine oil after test was used the viscosity calibration curve. About $54\%$ percent of diesel fuel in diluted engine oil was distillated by various paths related to reciprocating motion of piston and the rest diesel fuel plays an important role for decreasing engine oil viscosity. Test results show that lowered engine ell viscosity by diesel fuel dilution become a reason of increasing engine elements wear, Therefore, this caused the quantity of blow-by gas to increase and main gallery pressure to decrease.

• 한국에너지공학회:학술대회논문집
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• 한국에너지공학회 1999년도 춘계 학술발표회 논문집
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• pp.89-93
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• 1999

Experimental studies are conducted to investigate the flame stability and the thermal/fuel NOx formation characteristics of the low calorific value(LCV) gas fuel. Synthetic LCV fuel gas is produced through mixing carbon monoxide, hydrogen, nitrogen and ammonia on the basis that the thermal input of the syngas fuel into a burner is identical to that of natural gas, and then the syngas mixture is fed to and burnt with air on flat flame burner. Flame behaviors are observed to identify flame instability due to blow-off or flash-back when burning the LCV fuel gas at various equivalence ratio conditions. Measurements of NOx in combustion gas are made for comparing thermal and fuel NOx emissions from the LCV syngas combustion with those of the natural gas one, and for analyzing ammonia to NOx conversion mechanism. In addition, the nitrogen dilution of the LCV syngas is preliminarily attempted as a NOx reduction technique.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2011년도 제37회 추계학술대회논문집
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• pp.763-768
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• 2011

최근 대두되고 있는 바이오가스(Biogas)를 이중 희박 예혼합 가스터빈 연소기에 적용하기 위한 연구로써, 기존 개발된 실물형 이중 희박 예혼합 연소기 버너헤드에 바이오가스 조성을 모사한 $CO_2$ 희석 연료를 사용하여, 가스터빈 연소기의 연소불안정에 미치는 영향을 연구하였다. 이중 스월이 적용된 이중화염에서 연료분배율(Pilot fuel mass fraction)에 따라 화염구조가 상이하며 이에 따라 연소장의 온도분포와 연소불안정 특성이 결정된다. 동압신호와 phase-resolved $OH^*$ 이미지를 통해 연료분배율 변화와 $CO_2$ 희석률 증가에 따른 연소불안정 크기 감소와 그 경향을 알 수 있었다. $CO_2$ 희석에 의해 열방출 섭동의 크기가 감소하고 화염속도가 감소하며 이에 따라 화염면의 팽창 즉, 체적의 증가로 인해 연소불안정이 감소되는 것을 실험을 통해 확인하였다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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• pp.319-321
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• 2012

The flammability limit and the flame instability of nitrogen-diluted LPG fuel was experimentally studied on a co-flow flame configuration. The combustion reaction of nitrogen-diluted hydrocarbon with air could be interpreted as the equivalent reaction of pure fuel with nitrogen-diluted air. Nitrogen-diluted LPG with nitrogen up to 90 % of nitrogen mole fraction in fuel, which is close to the flammability limit, could form a co-flow flame. Various parameters such as laminar or turbulent flame, the existence of diffusion flame with pure fuel, air temperature could affect the limit of flame formation.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2013년도 제46회 KOSCO SYMPOSIUM 초록집
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• pp.55-58
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• 2013

A new soot particle generation system has been developed and tested. The soot generation system consists of two sections, a fuel supply and a soot production. In the fuel supply module, either liquid fuel precisely controlled by a syringe pump is mixed with preheated carrier gas and rapidly evaporated or gaseous fuel controlled by a MFC is diluted with dilution gas. The soot production module contains a heater that can raise the gas/fuel temperature up to $1400^{\circ}C$. The physical and chemical properties of produced soot particles depend on the type and concentration of fuel, the residence time, and temperature in the soot production section. The soot generation system will be utilized to produce well-defined soot particles for soot studies such as the evaluation of experimental sampling and analysis processes for the quantitative assessment of PM and BC from ships and the adverse health effects on pulmonary and cardiovascular systems of human body.

• 한국수소및신에너지학회논문집
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• 제15권4호
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• pp.348-354
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• 2004

Hydrogen gas has several merits such as lower ignition energy, wide flammability and shorter quenching distance. It leads to high thermal efficiency but backfire occurrence. In this study, feasibility of expansion of BFL(Back-Fire Limit) equivalence ratio and combustion characteristics by a dilution of hydrogen fuel are experimently examined by using experimental heavy duty single cylinder hydrogen fueled engine. As results, it is found that BFL equivalence ratio is expanded to rich range and torque is increased.