• Title/Summary/Keyword: fuel cell membrane

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A Study on Performance Characteristics of PEMFC with Thermal Variation (온도에 따른 고분자 전해질형 연료전지시스템의 출력 특성 연구)

  • Park, Se-Joon;Shin, Young-Sik;Jeong, Seong-Chan;Choi, Jeong-Sik;Cha, In-Su
    • Proceedings of the KIEE Conference
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    • 2009.04b
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    • pp.212-214
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    • 2009
  • The polymer electrolyte membrane fuel cell(PEMFC) with the advantages of low-operating temperature, high current density, low cost and volume, fast start-up ability, and suitability for discontinuous operation becomes the most reasonable and attractive power system for transportation vehicle and micro-grid power plant in a household. 200W PEMFC(Polymer electrolyte membrane fuel cell) system applied to middle and small-scaled micro-grid power system was constructed by this study, then the electrical characteristics and diagnosis of the fuel cell were analyzed with thermal variation.

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Performance Analysis of Polymer Electrolyte Membrane Fuel Cell by AC Impedance Measurement (교류 임피던스 측정법을 이용한 고분자 전해질 연료전지의 성능특성 분석)

  • Seo, Sang-Hern;Lee, Chang-Sik
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.4
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    • pp.283-290
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    • 2009
  • This study focuses on the performance characteristics of polymer electrolyte membrane fuel cell (PEMFC) using the AC impedance technique. The experiment was carried out to investigate the optimal operating conditions of PEMFC such as cell temperature, flow rate, humidified temperature and back-pressure. The fuel cell performance was analyzed by DC electronic-loader with constant voltage mode and expressed by voltage-current density. Additionally, AC impedance was measured to analysis of ohmic and activation loss and expressed by Nyquist plot. The results showed that the cell performance increased with increase of cell temperature, air flow rate, humidified temperature and backpressure. Also, the activation loss decreased as the increase of cell temperature, air flow rate, humidified temperature and backpressure.

The Effect of sGO Content in sPEEK/sGO Composite Membrane for Unitized Regenerative Fuel Cell (일체형 재생연료전지 적용을 위한 sGO 함량 변화에 따른 sGO/sPEEK 복합막의 특성 평가)

  • Jung, Ho-Young;Kim, Min-Woo;Lim, Ji-Hun;Choi, Jin H.;Roh, Sung-Hee
    • KEPCO Journal on Electric Power and Energy
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    • v.2 no.1
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    • pp.127-131
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    • 2016
  • Polymer electrolyte membrane for unitized regenerative fuel cells requires high proton conductivity, high dimensional stability, low permeability, and low cost. However, DuPont's Nafion which is a commercial polymer electrolyte membrane has high permeability, high cost, and decreasing proton conductivity and dimensional stability over $80^{\circ}C$. To address these problems, sulfonated poly ether ether ketone (sPEEK) which is a low cost hydrocarbon polymer is selected as matrix polymer for the preparation of polymer electrolyte membrane. In addition, composite membrane with improved proton conductivity and dimensional stability is prepared by introducing sulfonated graphene oxide (sGO). The fundamental properties of polymer electrolyte membranes are analyzed by investigating membrane's water content, dimensional stability, proton conductivity, and morphology. The cell test is conducted to consider the possibility of application of sPEEK/sGO composite membrane for an unitized regenerative fuel cell.

Comparison of Polymer Electrolyte Membrane Fuel Cell performance obtained by 1D and CFD simulations (1D와 CFD(Computational fluid dynamic) 시뮬레이션을 통한 PEMFC(Polymer Electrolyte Membrane Fuel Cell) 성능 비교)

  • Wonwoo Jeon;Sehyeon An;Jaewan Yang;Jiwon Lee;Hyunbin jo;Eunseop Yeom
    • Journal of the Korean Society of Visualization
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    • v.21 no.3
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    • pp.49-56
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    • 2023
  • The Polymer electrolyte membrane fuel cell (PEMFC) operates at ambient temperature as a low-temperature fuel cell. During its operation, voltage losses arise due to factors such as operating conditions and material properties, effecting its performance. Computational simulations of fuel cells can be categorized into 1D simulation and CFD, chosen based on their specific application purposes. In this study, we carried out an analysis validation using 1D geometry and compared its performance with the results from 2D geometry analysis. CFD allows for the representation of pressure, velocity distribution, and fuel mass fraction according to the geometry, enabling the analysis of current density. However, the 1D simulation, simplifying governing equations to reduce time cost, failed to accurately account for fuel distribution and changes in fuel concentration due to fuel cell operations. As a result, it showed unrealistic results in the cell voltage region dominated by concentration loss compared to CFD.

Dead-end Mode Operation of a Large Scale PEM Fuel Cell Stack (대면적 고분자전해질 연료전지의 데드엔드 운전)

  • Jeong, Jeehoon;Shin, Hyunkhil;Han, In-Su;Seo, Hakyu;Kim, Minsung;Cho, Sungbaek;Hur, Taeuk
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.83.1-83.1
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    • 2010
  • A Dead-end mode operation is one of the best way to maximize the gas usage rate. But, some components of fuel cell stack like gas diffusion layer(GDL) or membrane can be damaged in dead-end mode operation. In this study, a Large Scale Polymer electrolyte membrane fuel cell(PEMFC) for a dead-end operation has been developed. The stack is composed with 4 cells which has over 400cm2 of active area. Hydrogen is used as a fuel, and oxygen is used as a oxidant. The dead-end operation performance was evaluated by a long-term dead-end mode operation. The fuel cell stack is operated over 1,500 hours in dead-end mode operating fuel cell test station. And the performance change of the fuel cell stack was investigated.

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Moisture Permeation Characteristics of Hollow Fiber Membrane Tube for Humidification According to Input Conditions of Wet Steam (습증기 투입 조건에 따른 가습용 중공사막 튜브 수분 투과 특성)

  • CHAE, JONGMIN;YU, SANGSEOK
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.6
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    • pp.620-626
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    • 2018
  • Recently, fuel cell field is receiving much attention as an environmentally friendly energy in the world. Among the various types of fuel cells, in the case of PEMFC, ions move through the membrane in the middle of the unit cell. Therefore, proper moisture is required inside the PEMFC. In the case of membrane type humidifier, flat membrane or hollow fiber membrane is mainly used. Since various parameters can change the performance, the performance investigation has to be carried out with parameters. In this study, water transport of hollow fiber membrane was investigated in terms of principle operating conditions such as temperature and flow rate.

Effect of Temperature and Humidity on the Performance Factors of a 15-W Proton Exchange Membrane Fuel Cell

  • Dien Minh Vu;Binh Hoa Pham;Duc Pham Xuan;Dung Nguyen Dinh;Vinh Nguyen Duy
    • Applied Chemistry for Engineering
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    • v.34 no.3
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    • pp.241-246
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    • 2023
  • Fuel cells are one of the renewable energy sources that have sparked a lot of scientific attention for solving problems related to the energy crisis and environmental pollution. One of the most crucial subjects concerning the utilization of fuel cells is modeling. Therefore, an analytical steady-state and dynamic fuel cell model was described in this study. The parameter for the identification process was investigated, and the MATLAB/Simulink implementation was demonstrated. A 15-W proton exchange membrane fuel cell was used to apply the suggested modeling methodology. Comparing experimental and simulation findings indicated that the model error was constrained to 3%. This study showed that temperature and humidity affect fuel cell performance.

Development of Anion Exchange Membrane based on Crosslinked Poly(2,6-dimethyl-1,4-phenylene oxide) for Alkaline Fuel Cell Application (화학적 가교를 이용한 Poly(2,6-dimethyl-1,4-phenylene oxde)계 음이온 교환막의 제조 및 알칼리 연료전지용 특성평가)

  • Sung, Seounghwa;Lee, Boryeon;Choi, Ook;Kim, Tae-Hyun
    • Membrane Journal
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    • v.29 no.3
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    • pp.173-182
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    • 2019
  • Much research has been made for finding new and eco-friendly alternative sources of energy to solve the problems related with the pollution caused by emissions of greenhouse gases such as carbon dioxide as the use of fossil fuels increases worldwide. Among them, fuel cells draws particular interests as an eco-friendly energy generator because only water is obtained as a by-product. Anion exchange membrane-based alkaline fuel cell (AEMFC) that uses anion exchange membrane as an electrolyte is of increased interest recently because of its advantages in using low-cost metal catalyst unlike the PEMFC (potton exchange membrane fuel cell) due to the high-catalyst activity in alkaline conditions. The main properties required as an anion exchange membrane are high hydroxide conductivity and chemical stability at high pH. Recently we reported a chemically crosslinked poly(2-dimethyl-1,4-phenylene oxide) (PPO) by reacting PPO with N,N,N',N'-tetramethyl-1,6-hexanediamine as novel anion exchange membranes. In the current work, we further developed the same crosslinked polymer but having enhanced physicochemical properties, including higher conductivity, increased mechanical and dimensional stabilities by using the PPO with a higher molecular weight and also by increasing the crosslinking density. The obtained polymer membrane also showed a good cell performance.

Preparation and Characterization of Polysulfone Substrate for Reinforced Composite Membrane Fuel Cell Membrane (연료전지 전해질 복합막 제조를 위한 폴리설폰계 지지체의 제조와 물성)

  • Nam, Sang-Yong;Kim, Deuk-Ju;Hwang, Rae-Young;Kim, Hyoung-Juhn
    • Membrane Journal
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    • v.19 no.1
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    • pp.63-71
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    • 2009
  • In this study, polysulfone which has excellent mechanical and thermal stability with low cost was used for preparing a non-conducting polymer matrix as a reinforced composite membrane for fuel cell application. The membranes were prepared by phase separation method. Polymer concentration and retention time were controlled to investigate the effects on the membrane morphology. The resaltant membranes showed all sponge-like structure independent of polymer concentration. The mechanical and thermal stability were improved with increasing polymer concentration in contrast to the membrane porosity. As a result, the membranes prepared with the retention time for 2 mins using 20 wt% of polymer solution was suitable for a fuel cell compositite membrane providing optimum properties such as approximately 80% of high porosity, 1.3 MPa of tensile strength, and less than 1% of thermal shrinkage both machine and transverse direction.