• Title/Summary/Keyword: frequency-dependent

Search Result 1,819, Processing Time 0.026 seconds

Extracting Frequency-Frequency Correlation Function from Two-Dimensional Infrared Spectroscopy: Peak Shift Measurement

  • Kwak, Kyung-Won
    • Bulletin of the Korean Chemical Society
    • /
    • v.33 no.10
    • /
    • pp.3391-3396
    • /
    • 2012
  • Two-dimensional infrared (2D-IR) spectroscopy can probe the fast structural evolution of molecules under thermal equilibrium. Vibrational frequency fluctuation caused by structural evolution produced the time-dependent line shape change in 2D-IR spectrum. A variety of methods has been used to connect the evolution of 2D-IR spectrum with Frequency-Frequency Correlation Function (FFCF), which connects the experimental observables to a molecular level description. Here, a new method to extract FFCF from 2D-IR spectra is described. The experimental observable is the time-dependent frequency shift of maximum peak position in the slice spectrum of 2D-IR, which is taken along the excitation frequency axis. The direct relation between the 2D-IR peak shift and FFCF is proved analytically. Observing the 2D-IR peak shift does not need the full 2D-IR spectrum which covers 0-1 and 1-2 bands. Thus data collection time to determine FFCF can be reduced significantly, which helps the detection of transient species.

Effect of Loading Frequency Dependent Soil Behavior on Seismic Site Effect (하중의 주파수에 의하여 지배받은 흙의 동적 거동이 부지증폭현상에 미치는 영향)

  • Park Du-Hee;Hashash Y.M.A;Lee Hyun-Woo;Kim Jae-Yoen
    • Journal of the Korean Geotechnical Society
    • /
    • v.22 no.3
    • /
    • pp.23-35
    • /
    • 2006
  • Equivalent linear analysis is widely used in estimating local seismic site effects. The soil behavior in the analysis is often assumed to be rate-independent and is not influenced by the seismic loading frequency. Laboratory results, however, indicate that cohesive soil behavior is greatly influenced by the loading frequency. A new equivalent linear analysis method that accounts for the loading frequency dependent soil behavior is developed and used to perform a series of one dimensional site response analyses. Results indicate that while frequency dependent shear modulus has limited influence on computed site response, frequency dependent soil damping greatly filters out high frequency components of the ground motion and thus results in lower response.

The Frequency-Dependent First-, Second-, and Third-Order Polarizabilities of Thiophene-, Furan-, Pyrrole-Nitro Polyene Systems

  • Choe, Yu Seong
    • Bulletin of the Korean Chemical Society
    • /
    • v.17 no.1
    • /
    • pp.61-65
    • /
    • 1996
  • The semiempirical time-dependent Hartree-Fock PM3 calculations have been performed on three polyene systems. In order to study the nonlinear optical properties, we calculated the frequency-dependent first-, second-, and third-order polarizabilities of thiophene-, furan-, pyrrole-nitro polyene systems. The PM3 predicted average and longitudinal polarizabilties increase in the order: thiophene- > pyrrole- > furan-nitro polyene systems. The PM3 predicted limiting average second-order polarizabilities show the order: pyrrole- > furan- > thiophene-nitro polyene systems. The average and longitudinal third-order polarizabilties have the following order: pyrrole- > thiophene- > furan-nitro polyene systems. In these trends, we sugest that pyrrole group is the best donor group among the three polyene systems.

A Method of Simulating the Frequency-dependent Ground Impedance of Counterpoises (매설지선의 접지임피던스의 주파수의존성에 대한 모사기법)

  • Lee, Bok-Hee;Shin, Hee-Kyung;Seong, Chang-Hoon
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
    • /
    • v.26 no.3
    • /
    • pp.73-79
    • /
    • 2012
  • A counterpoise is commonly employed in grounding systems installing near the ground surface of low resistivity soils and radial-type counterpoises are used in the limited space. Recently some studies on the evaluation of ground impedance of paralleling ground electrodes have carried out, but the data for providing the frequency-dependent ground impedances considering potential interferences are not yet sufficient. In order to provide the information about the design of grounding systems for surge protection, the simulations of the frequency-dependent ground impedance of various shaped counterpoises are carried out by using the distributed parameter circuit model including the effect of potential interferences. This paper presents the theoretical simulations and actual experiments of the frequency-dependent ground impedance of paralleling and 3 or 4-arms star counterpoises. The accuracy of the simulation methodology is examined by the comparison with the measured results, and the results show a good agreement between the simulation and the experiment.

Simulation Method for Radio-Frequency Single-Electron Transistor (RF-SET) Operation (고주파 단일전자 트랜지스터 (RF-SET) 동작의 시뮬레이션 방법)

  • Yu Yun Seop;Park Hyun-Sik
    • Journal of the Institute of Electronics Engineers of Korea SD
    • /
    • v.42 no.5 s.335
    • /
    • pp.9-14
    • /
    • 2005
  • Simulation method for a pure radio-frequency (rf) mode of reflection-type and a pure rf mode of transmission-type radio-frequency single-electron transistor (RF-SET) operation is introduced. In this method, the solutions of differential equations based on Kirchhoff's law are obtained self-consistently at frequency-domain. Also, the steady-sate single-electron transistor (SET) current model and the time-dependent SET current model are used in this method. The reflected wave of a typical reflection-type RF-SET and the transmitted wave of a typical transmission-type RF-SET are calculated, and the accuracy of our developed method including the steady-state SET current model is verified with the method introduced by reference 2. At high frequency over GHz, results of our developed method including the time-dependent SET current model are considerably different from that including the steady-state SET current model. At high frequency over GHz, an exact time-dependent SET current model is needed to analyze RF-SET operation.

Driving-Condition-Dependent Optical Transmission Characteristics of an STN LCD (구동조건에 따른 STN LCD의 광투과 특성)

  • 고형일;정태혁;이상찬;윤태훈;김재창
    • Journal of the Korean Institute of Telematics and Electronics A
    • /
    • v.32A no.10
    • /
    • pp.35-42
    • /
    • 1995
  • In this paper the driving-condition-dependent optical transmission characteristics of an STN LCD are studied. The optical transmission properties are measured for the applied voltage waveform is varied. Also, the optimum ranges of the M signal frequency and the frame frequency are investigated. An LCD is modeled by the equivalent circuit to study the effect of the parameter variation on the frequency response.

  • PDF

Canonical Transformations for Time-Dependent Harmonic Oscillators

  • Park, Tae-Jun
    • Bulletin of the Korean Chemical Society
    • /
    • v.25 no.2
    • /
    • pp.285-288
    • /
    • 2004
  • A canonical transformation changes variables such as coordinates and momenta to new variables preserving either the Poisson bracket or the commutation relations depending on whether the problem is classical or quantal respectively. Classically canonical transformations are well established as a powerful tool for solving differential equations. Quantum canonical transformations have been defined and used relatively recently because of the non-commutativeness of the quantum variables. Three elementary canonical transformations and their composite transformations have quantum implementations. Quantum canonical transformations have been mostly used in time-independent Schrodinger equations and a harmonic oscillator with time-dependent angular frequency is probably the only time-dependent problem solved by these transformations. In this work, we apply quantum canonical transformations to a harmonic oscillator in which both angular frequency and equilibrium position are time-dependent.

Verification of Frequency-Dependent Equivalent Linear Method (주파수 의존성을 고려한 등가선형해석기법의 검증)

  • Jeong, Chang-Gyun;Kwak, Dong-Yeop;Park, Du-Hee
    • Journal of the Korean Geotechnical Society
    • /
    • v.24 no.12
    • /
    • pp.113-120
    • /
    • 2008
  • One-dimensional site response analysis is widely used to simulate the seismic site effects. The equivalent linear analysis, which is the most widely used type of site response analysis, is essentially a linear method. The method applies constant shear modulus and damping throughout the frequency range of the input motion, ignoring the dependence of the soil response on the loading frequency. A new type of equivalent linear analysis method that can simulate the frequency dependence of the soil behavior via frequency-strain curve was developed. Various forms of frequency-strain curves were proposed, and all curves were asserted to increase the accuracy of the solution. However, its validity has not been extensively proven and the effect of the shape of the frequency-strain curve is not known. This paper used two previously proposed frequency-strain curves and three additional curves developed in this study to evaluate the accuracy of the frequency-dependent equivalent linear method and the influence of the shape of the frequency-strain curves. In the evaluation, six recordings from three case histories were used. The results of the case study indicated that the shape of the frequency-strain curve has a dominant influence on the calculated response, and that the frequency dependent analysis can enhance the accuracy of the solution. However, a curve that results in the best match for all case histories did not exist and the optimum curve varied for each case. Since the optimum frequency-strain curve can not be defined, it is recommended that a suite of curves be used in the analysis.

Predistortion for Frequency-Dependent Nonlinearity of a Laser in RoF Systems

  • Najarro, Andres C.;Kim, Sung-Man
    • Journal of information and communication convergence engineering
    • /
    • v.14 no.3
    • /
    • pp.147-152
    • /
    • 2016
  • In radio-over-fiber (RoF) systems, nonlinear compensation is essential to improve performance. Among the several existing nonlinear compensation techniques, we investigate a predistortion technique for a directly modulated laser in an RoF system. First, we obtain the input-to-output response of a directly modulated laser at 160, 820, and 1,540 MHz. The results show that the laser response is dependent on the frequency band. Second, we design an optimal predistortion circuit to compensate for the nonlinear responses of three frequency bands. We design the predistortion circuit with two options: each predistortion circuit for each frequency band and one single predistortion circuit for all the three frequency bands. Finally, we present the simulation results of the predistortion system obtained using a commercial simulator. These results show that the third intermodulation distortion (IMD3) is improved by 0.6-9 dB for the three frequency bands with only a single predistortion circuit.

A study on nonlinear seismic response analysis of building considering frequency dependent soil impedance in time domain

  • Nakamura, Naohiro
    • Interaction and multiscale mechanics
    • /
    • v.2 no.1
    • /
    • pp.91-107
    • /
    • 2009
  • In order to accurately estimate the seismic behavior of buildings, it is important to consider both nonlinear characteristics of the buildings and the frequency dependency of the soil impedance. Therefore, transform methods of the soil impedance in the frequency domain to the impulse response in the time domain are needed because the nonlinear analysis can not be carried out in the frequency domain. The author has proposed practical transform methods. In this paper, seismic response analyses considering frequency dependent soil impedance in the time domain are shown. First, the formulation of the proposed transform methods is described. Then, the linear and nonlinear earthquake response analyses of a building on 2-layered soil were carried out using the transformed impulse responses. Through these analyses, the validity and efficiency of the methods were confirmed.