• Title/Summary/Keyword: frequency shifts

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Solvent Effects upon Nitrile Group Frequency Shifts of Raman Spectra: Acetonitrile and Benzonitrile (라만 스펙트라의 니트릴기 파수 이동에 관한 용매효과: 아세토니트릴과 벤조니트릴)

  • Seo, Seong Hun;Jeong, Yeong Mi;Lee, Mu Sang
    • Journal of the Korean Chemical Society
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    • v.38 no.3
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    • pp.179-185
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    • 1994
  • The Raman stretching frequency of nitrile group was affected by change of solvents and its in concentration in same solvent. In the case of acetonitrile, nitrile group stretching frequencies were observed in the region of 2247.3∼2254.9 cm-1 with various solvents. While in benzonitrile, they were found in the region of 2226.1∼2230.3$ cm^{-1}. With the addition of water in acetonitrile,νC≡N was shifted to high frequency from 2250.1 cm^{-1} in pure acetonitrile to 2257.7 cm^{-1} in 90% water forwhich had with higher volume % of water caused higher hydrogen-bonded equilibrium between methyl protons and water. The νC≡N frequency for nitrile group was shifted to high frequency by solvent inductive effect with the increasing mixed solvent (CHCl_3/CCl_4)$mole% ratio.

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Design of Doppler-Frequency Tracking System based on the Optimum Synchronization Techniques for the Digital Satellite Communication System (최적 동기방식에 의한 디지틀 위성통신 시스템의 도플러 위상 추적 장치 설계)

  • 최재익;박진우
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.19 no.12
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    • pp.2498-2507
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    • 1994
  • This paper proposes the Doppler frequency tracking system by the optimum synchronization technique which compensates the frequency shifts caused by satellite movement in a coherent digital satellite communication system. A Doppler frequency shift caused by satellite movements and the design theories of the optimum synchronization system are mathematically described. Based on this theory, a Doppler frequency tracking system is implemented via digital signal processing techniques utilizing a DSP chip, RAMs, PROMs, and a 80286 microprocessor. The performance of the designed system was evaluated through the experiments with the INTELSATVA satellite.

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Vibration Analysis During Breaking Process of Phantom Induced by Shock Wave for Medical Treatment (의료용 충격파에 의할 대상물의 파쇄진행에 따른 진동해석)

  • Park Kyu-Chil;Jang Yun-Seok
    • The Journal of the Acoustical Society of Korea
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    • v.25 no.1
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    • pp.43-48
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    • 2006
  • When the vibration of a phantom induced by Extracorporeal Shock Wave Lithotripter (ESWL) was investigated. we found the fact that the Peak frequency in the Power spectrum shifts from high frequency to low frequency as the number of shots increases[2]. The fact was confirmed experimentally by detecting the peak frequency obtained from the vibrations of bronze models[3]. This Paper investigates the experimental results. For the Purpose. we carried out the computer simulation using the finite element method. It is found that the results from the experiments are computer by computer simulation.

Performance Improvement of VHF Train Radio Transmitter by Using Vibration-Proof Pads (방진패드를 이용한 VHF 열차무선 송신기 특성 개선)

  • Kim, Sung-Dong;Koo, Kyung-Heon
    • Journal of Advanced Navigation Technology
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    • v.13 no.4
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    • pp.475-481
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    • 2009
  • This paper focuses the performance improvement of the train radio system (TRS) supporting the safe and accurate operations. The causes of troubles and the performance drift in TRS have been analyzed and measurement indexes have been selected. Frequency shifts of transmitters causing from train vibrations have been shown, and the improvement of frequency stability has been confirmed by use of vibration- proof pads.

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Dynamic Loudness Compensation for Digital Hearing Aids (디지탈 보청기의 이득보상기법에 대한 연구)

  • Kim, Dong-Wook;Kim, Won-Ky
    • Proceedings of the KOSOMBE Conference
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    • v.1995 no.11
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    • pp.121-123
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    • 1995
  • This paper presents a new method which compensates loss of loudness for digital hearing aids. Loudness grows more rapidly in frequency domain with substantial shifts of hearing threshold, so that loud sounds reach the uncomfortable sound level (UCL) at about the same physical stimulus level as with normal hearing. The result is a compression of the available dynamic range of hearing. Many techniques have been developed to compensate for hearing losses. In this paper, we propose a digital hearing aid which uses a single digital filter for reducing distortion and the fuzzy function to calculate gain factors. This function describes how much gain is needed for every frequency to restore loudness perception of a normal ear.

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Frequency analysis of EMG signals using power spectrum density (전력 스펙트럼 밀도를 이용한 근전도 신호의 주파수 해석)

  • Kim, Kwnag-Soon;Byun, Youn-Sik;Park, Sang-Hui
    • Proceedings of the KOSOMBE Conference
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    • v.1985 no.06
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    • pp.5-8
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    • 1985
  • This paper describes the use of power spectral densing in the examination of the electromogram (EMG). The EMG signals were obtained with surface electrodes from the biceps brachii muscle. Shifts of the high-energy regions of the power spectra can be inferred from the changes in the mean frequency. This paper is consistent with result that most information of EMG signal is located 10-200 Hz.

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Oscillation Control for a Electro-Magnetic Vibratory Gyroscope (전자기력을 이용한 진동형 자이로의 가진루프제어)

  • Kong, Hyeong-Jik;Lee, Sug-Chon;Park, Sung-Su;Hong, Sung-Kyung
    • Journal of Institute of Control, Robotics and Systems
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    • v.11 no.3
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    • pp.187-192
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    • 2005
  • This paper presents the design of the Automatic Gain Control (AGC) system for the drive axis of a electro-magnetic driven cylinder gyroscope. The simulation and experimental results show that the designed AGC excites the cylinder at its natural frequency and maintains a specified amplitude of oscillations, and also track the natural frequency shifts due to temperature variations. The sensing performance of the AGC driven gyroscope is shown to be greatly improved compared to that of the open-loop driven one.

Accurate Measurement of THz Dielectric Constant Using Metamaterials on a Quartz Substrate

  • Park, Sae June;Ahn, Yeong Hwan
    • Current Optics and Photonics
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    • v.1 no.6
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    • pp.637-641
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    • 2017
  • We present dielectric constant measurements of thin films using THz metamaterials fabricated on a quartz substrate. The resonance shifts of the metamaterials exhibit saturation behavior with increasing film thickness. The saturation frequency shift varies with the real part of the dielectric constant, from which the numerical expression for the particular metamaterial design was extracted. We first performed finite-difference time-domain simulations to find an explicit relationship between the saturated frequency shift and the dielectric constant of a thin film, which was confirmed by the experimental results from conventional techniques. In particular, the quartz substrate enables us to determine their values more accurately, because of its low substrate index. As a result, we extracted the dielectric constants of various films whose values have not been addressed previously without precise control of the film thickness.

Intermolecular Hydrogen Bond between Phenol and DMAs (Phenol과 DMA 간의 수소결합)

  • Kim, Pock-Hye;Lee, Ik-Choon
    • Journal of the Korean Chemical Society
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    • v.10 no.1
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    • pp.15-17
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    • 1966
  • Intermolecular hydrogen-bonding between phenol and N,N'-dimethylanilines (DMA) has been studied by infrared spectrophotometry. Results show that DMA acts as n-and ${\pi}$-donor although n-complex predominates. O-H stretching frequency shifts (${\Delta}{\nu}$) were proportional to basicitys of DMA and excellent linearity was observed between ${\Delta}{\nu}$ and the Hammett substituent constant, ${\sigma}$.

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Frequency Tuning of Unimorph Cantilever for Piezoelectric Energy Harvesting (주파수 조정에 따른 에너지 하베스팅용 압전 캔틸레버의 특성)

  • Kim, Hyung-Chan;Song, Hyun-Cheol;Jeong, Dae-Yong;Kim, Hyun-Jai;Yoon, Seok-Jin;Ju, Byeong-Kwon
    • Korean Journal of Materials Research
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    • v.17 no.12
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    • pp.660-663
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    • 2007
  • Piezoelectric energy harvesting from our surrounding vibration has been studied for driving the wireless sensor node. To change the vibration energy into the electric-energy efficiently, the natural frequency of cantilever needs to be adjusted to that of a vibration source. When adding 6.80g mass on the end of the fabricated cantilever, a natural frequency shifts from 136 Hz into 49.5 Hz. In addition, electro-mechanical coupling factor increased from 10.20% to 11.90% and resulted in the 1.18 times increase of maximum output power.