• Title/Summary/Keyword: freezing, thawing

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Study on the Analysis of Failure Cause and Determination of Life Test Mode of Capsule (축열조 캡슐 고장원인 분석과 수명시험 모드 결정에 관한 연구)

  • Kang, Bosik;Lee, Yongbum;Jung, Dongsoo;Lee, Chungsung
    • Journal of Applied Reliability
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    • v.18 no.3
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    • pp.260-270
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    • 2018
  • Purpose: The purpose of this study is to evaluate the life of the capsule, which is a core part of the heat storage cooling system. This paper will develop a life test mode that can reproduce environment conditions through the analysis of capsule shrinkage and expansion characteristics. Methods: In order to determine the life test mode of the capsule, this paper analyzed the case of field failures and analyzed the deformation characteristics according to the pressure fluctuation of the capsule. The method to find out whether the field failure and deformation analysis results are consistent is the testing with the construction of the repetition pressure test equipment and the thermal cycle test to reproduce the freezing and thawing characteristics. Results: In this study, failure mode analysis and analysis of freezing and thawing characteristics regarding to the capsule positions were completed. Based on this test & analysis results, this paper have been able to determine the main parameters for determining the life test mode, the freezing and thawing time. Conclusion: Determining the lifetime mode of the capsule can be used to improve the life and performance of the thermal storage system.

Influence of Initial Water Content, Specific Surface, Air Drying and Freezing-thawing Action on the Liquid Limit of Soils (초기함수비, 비표면적, 풍건 및 동결.융해작용이 흙의 액성한계에 미치는 영향)

  • 류능환
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.38 no.5
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    • pp.116-124
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    • 1996
  • The purpose of The work described in this paper is to clear up the initial moisture content, specific surface, air drying and freezing-thawing process on liquid limit of clayey soils distributed widely at estuary of three main rivers in the west coast. To this end, a series of tests were conducted on clayey soils samples with natural state and treated state. From the test results, the liquid limit was decreased with decrement of initial moisture content, air drying process, and freezing-thawing cycles and increased with increment of specific surface. The specific surface which influenced on the liquid limit is over $25 m^2$m$^2$/g, and their relationships are well formulated. Air drying process is expected to improve the engineering properties of the soils such the pro-water properties were changed to anti-water proper-ties through lowering of water holding as resulted to incline from A-7-5 to A-5 on the soil classificaction plastic chart. The freezing-thawing process decreased 20% of liquid limit, especially under the first cycle of the behavious, as a result of above mentioned reasons, phase change of soil-water system brought the decrement of specific surface and affected to the liquid limit.

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An Experimental Study on the Freeze-Thaw Resistance of Concrete Incorporating Waste Foundry Sand (폐주물사를 혼입한 콘크리트의 동결-융해 저항성에 관한 실험적 연구)

  • Yong, Suk-Ung;Lee, Joo-Hyung;Hong, Chang-Woo;Yun, Kyong-Ku;Park, Je-Seon
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.04a
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    • pp.117-122
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    • 1998
  • Concrete structures has been deteriorated by the freezing and thawing due to temperature gap. This study was conducted to evaluate durabilite of concrete which are increasingly demanded recently. Therefore the research of durability must be executed for application of waste foundry sand concrete real structures. Concrete durability must be executed for application of waste foundry sand concrete real structures. Concrete durability properties incorporating waste foundry sand was performed with the variable of W/C ratio, Sand/Waste foundry sand ratio and Air entrainment-Non air entrainment. Cylinder specimens were made and subjected to freezing and thawing cycle at $-18^{\cire}C$ and $4^{\cire}C$. Dynamic modulus of elasticity were evaluated as F/T cycle increase. The results show that strength of concrete is increased the W/C ratio decrease, the Sand/Waste foundry sand ratio increase when the concrete contains AE agent and decreasing WC ratio and AE concrete makes improved resistance of freezing and thawing improved. Especially, resistance of freezing and thawing is improved by Fine aggregate/Waste foundry sand ratio which is 50%, 25%, 0% in a row. Therefore it is turn out the waste foundry sand could be applied to concrete from the experiment.

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Evaluation on Basic Properties of Crushed Sand Mortar in Freezing-Thawing and Sulfate Attack (동결융해와 황산염의 복합작용을 받는 부순모래 모르타르의 기초 특성 평가)

  • Kim, Myeong-Sik;Baek, Dong-Il;Choi, Kang-Seok
    • Journal of Ocean Engineering and Technology
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    • v.23 no.5
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    • pp.54-60
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    • 2009
  • Exposed to various environments, concrete confronts degradation by a lot of physical and chemical reaction. Though so many experiments and theorizations on the single condition of concrete degradation have been carried out by constant studies, the truth for now is that there are few studies on the compound phenomenon of degradation related with marine environments. Accordingly, this study measured the degree of degradation in the change of external shape, the change of unit weight and compressive strength, ultrasonic velocity test, and the change of length, etc. after exposing the specimen of cement mortar to the environment between 0 cycle and the maximum of 300 cycles under the condition of aquatic curing, freezing and thawing, and compound degradation, using mineral admixture effective for concrete degradation as a binder. The result indicated that the case of adding mineral admixture showed greater resistance than that of using OPC only, and specifically, the specimen with the additive of slag powder and three component system showed very excellent resistance to freezing and thawing, and compound degradation.

The Strength Characteristics By Freezing and Thawing of Controlled Low Strength Material Using Coal Ash (석탄회를 활용한 CLSM의 동결융해에 의한 강도 특성)

  • Hyun, Ho-Gyu;Kim, Sun-Tae;Jung, Hyuk-Sang;Chun, Byung-Sik
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.09b
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    • pp.32-37
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    • 2010
  • Recently, the land area for many people has been limited because of industrialization and modernization in Korea. The large-scale constructions like the reclamation development projects have been progressed to resolve this problem mentioned above. Therefore, as many of the usefulconstruction materials as possible are needed to perform the large-scale construction projects. Many studies for the utilization of pond ash which has a similar characteristic of sand have been conducted and there has been often occurred many structural problems on roadbed in winter. Therefore, the characteristics of the freezing and thawing for Controlled Low-Strength Material (CLSM) using pond ash were analyzed and evaluated by unconfined compressive strength test in this study. As a result of this study, it was confirmed that new CLSM using pond ash with cement (8.2% by weight)was able to stand for the freezing and thawing behavior.

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Preparation and Reconstitution of Core-shell Type Nanoparticles of Poly(ε -caprolactone)/Poly(ethyleneglycol)/Poly(ε -caprolactone) Triblock Copolymers

  • Jeong, Young-Il;Ryu, Jae-Gon;Kim, Young-Hoon;Kim, Sung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.23 no.6
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    • pp.872-879
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    • 2002
  • One of the improtant characteristics of core-shell type nanoparticles is the long-term storage and reuse as an aqueous injection solution when required. For this reason, reconstruction of lyophilized core-shell type nanoparticles is considered to be essential . BAB type triblock copolymers differ from AB type diblock copolymers, which contain the A block as a hydrophilic part and the B block as a hydrophobic part. by not being easily redistributed into phosphate-buffered saline (PBS, pH 7.4, 0.1 M). Therefore, lyophilized core-shell type nanoparticles of CEC triblock copolymer were reconstituted using a somication process with a bar-type sonicator in combination with a freezing-thawing process. Soncation for 30s only resuspended CEC nanoparticles in PBS; their particle size distribution showed a monomodal pattern with narrow size distribution. The bimodal size distribution pattern and the aggregates were reduced by further sonication for 120 s but these nanoparticles showed a wide size distribution. The initial burst of drug release was increased by reconstitution process. The reconstitution of CEC core-shell type nanoparticles by freezing-thawing resulted in trimodal distribution pattern and formed aggregates, although freezing-thawing process was easier than sonication . Drug release form CEC nanoparticles prepared by freezing-thawing was slower than from the original dialysis solution. Although core-shell typenanoparticles of CEC triblock copolymers were not easily performed. Cytotoxicity testing of core-shell type nanoparticles of CEC-2 triblock copolymers containing clonazepam (CNZ) was performed using L929 cells. Cytotoxicity of CNZ was decreased by incorporation into nanoparticles.

Long-Term Degradation Mechanism of GFRP Dowel Bar for Jointed Concrete Pavement under Repeated Freezing-Thawing (동결융해 반복을 받는 콘크리트 포장용 GFRP 다웰바의 장기성능저하 메커니즘)

  • Won, Jong Pil;Jang, Chang Il;Park, Chan-Gi;Lee, Sang Woo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.3D
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    • pp.325-330
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    • 2008
  • This study carried out the repeated freezing-thawing test in order to understand the long-term degradation mechanism of GFRP dowel bars. The mechanical property measured by shear test. In addition, analyzes repeated freezing-thawing degradation mechanism of GFRP dowel bars by observe the microstructure through Scanning Electron Microscope (SEM) and Gas Physisorption techniques. As the result of test, it was found that the mechanical property didn't decreased as the exposure time to water and repeated freezing-thawing environment. It shows clearly observed microstructure investigations.

Physicochemical Characterization and Changes in Nutritional Composition of Onions Depending on Type of Freezing Process (냉동 조건에 따른 양파의 이화학적 특성 및 영양성분 변화)

  • Jang, Min-Young;Jo, Yeon-Ji;Hwang, In-Guk;Yoo, Seon-Mi;Choi, Mi-Jung;Min, Sang-Gi
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.43 no.7
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    • pp.1055-1061
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    • 2014
  • Innovative freezing technology is currently applied to preserve foodstuffs for long-term storage. Generally, the quality of frozen food is closely related to the types of freezing and thawing processes. In this study, we characterized the physicochemical properties of onions depending on freezing rate. When onions were frozen at $-40^{\circ}C$, freezing rates were 0.1, 0.5, and $0.7^{\circ}C/min$ depending on air-blast quick freezer mode. Onions were thawed by microwave irradiation at 400 W. Hardness of onion dramatically decreased after freezing and thawing compared with blanched onion. However, the fastest freezing rate did not affect hardness. Thawing loss of onion decreased with a faster freezing rate. For morphological observation, onion frozen at a faster rate showed a smaller ice-crystal size. Vitamin C content decreased upon blanching or freezing, but there was no significant difference according to freezing rate. Although free sugar content also decreased upon blanching and freezing, its highest content was at $0.7^{\circ}C/min$ freezing. Among organic acids, malic acid content was highest at $0.7^{\circ}C/min$ freezing. Based on this study, it could be suggested that a faster freezing rate is effective to improve frozen food quality in accordance with preventing tissue damage or minimizing destruction of nutrients.

Preparation and Characterization of PVAL/PVP/Hexylene Glycol/Chitosan Hydrogels by $\gamma$-Ray ($\gamma$-선을 이용한 PVAL/PVP/헥실렌 글리콜/키토산 수화젤의 제조 및 특성)

  • 최은경;김형일;노영창
    • Polymer(Korea)
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    • v.27 no.4
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    • pp.349-357
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    • 2003
  • Hydrogels for wound dressing from a mixture of poly(vinyl alcohol) (PVAL), poly(N-vinyl pyrrolidone) (PVP), hexylene glycol (HG) and chitosan were made. The hydrogels were obtained by physical crosslinking of freezing and thawing, chemical crosslinking of irradiation, and irradiation after freezing and thawing of mixture solutions. The solid concentration of PVAL/PVP/HG/chitosan was 15 wt%. The concentration of chitosan was 0.3 wt%, and the ratio of PVAL/PVP was 6:4. The concentration of HG was in the range of 1∼5 wt%. The number of repeated freezing and thawing was in the range of 1∼3 times, and gamma irradiation doses were 25, 35 and 50 kGy. The physical properties such as gelation, water absorption and gel strength of hydrogels were examined. Gel content and gel strength decreased as HG concentration increased, whereas degree of swelling increased. Gel content and gel strength increased as irradiation dose and the number of freezing and thawing increased, whereas degree of swelling decreased. The hydrogels were evaluated for the healing effect for animals and for the antibacterial effect.

Studies on the Development of Easy Cryopreservation Technique of Bovine Embryos II. Effects of Equilibration of Cryoprotectants, Temperature and Time of Thawing and 1 Step Straw Method on In Vitro Developmental Rates of Embryos (소 수정란의 간이 동결기법 개발에 관한 연구 II. 내동제의 평형시간, 융해온도, 융해시간 및 1단계 Straw법이 체외발생에 미치는 영향)

  • 김상근;남윤이;현병화
    • Korean Journal of Animal Reproduction
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    • v.21 no.2
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    • pp.103-109
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    • 1997
  • The studies on the carried out to investigate to determine the optimum thawing temperature and equilibration time and 1 step straw method of frozen bovine embryos. The follicular oocytes were cultured in TCM-199 medium containing 10 IU/ml PMSG(Sigma, USA), 10 IU/ml hCG(Sigma, USA), 1 $\mu\textrm{g}$/ml $\beta$-estradiol(Sigma, USA) and 10% FCS for 24~48 hrs in incubator with 5% CO2 in air at 38.5$^{\circ}C$ and then matured oocytes were again cultured for 12~18 hrs with motile capacitated sperm by preincubation of heparin. The bovine embryos following dehydration by cryoprotective agents and various concentration of sucrose were directly plunged into liquid nitrogen and thawed in 3$0^{\circ}C$ water. Survival and in vitro developmental rate was defined as developmental rate on in vitro culture or FDA-test. The results are summarized as followes : 1. The equilibration time on in vitro developmental rates of bovine embryos was attained after short period of time(2.5~5 min.) in the freezing medium higher than long period of time (10~20 min.). 2. The temperature thawed at 3$0^{\circ}C$ after rapid freezing of bovine embryos resulted in a significantly higher in vitro developmental rate than did at 2$0^{\circ}C$ and 35$^{\circ}C$. 3. The thawing time on in vitro developmental rates of bovine embryos was attained after short period of time(1~5 min.) in the freezing mediuim higher than long period of time(10min.). 4. The in vitro developmental rates of bovine embryos after rapid frozen-thawing by 1 step straw method in the freezing medium added 1.5M, 2.0M glycerol, DMSO, propanediol and 0.25M, 0.50M, 0.75M, 1.00M sucrose were 12.5~19.4%, 10.0~15.6%, 9.1~13.8% and 6.7~12.9%, respectively.

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