• Title/Summary/Keyword: free VOCs

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A Field Study on the Evaluation of Slurping and Bioaugmentation Effect in Petroleum Contaminated Area (유류오염지역 정화를 위한 슬러핑과 미생물증진법의 효율평가에 관한 현장 적용성 연구)

  • Park, Eung-Ryeol;Lee, Kwang-Ryeol;Seo, Chang-Il;Cho, Chang-Hwan
    • Journal of Soil and Groundwater Environment
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    • v.17 no.3
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    • pp.32-38
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    • 2012
  • This study was conducted to evaluate the slurping process affecting the variation of free product and VOCs concentration and the bioaugmentation effect on bioremediation process. Free products and soil gas were extracted from 30 extraction wells installed in a petroleum contaminated area. The extraction system was operated for 10 hours per day with 1 hour on-and-off mode. The thickness of free product in extraction well was decreased from 11.7 cm to 4.5 cm and the VOCs concentration was increased from 10.37 ppm to 30.78 ppm during the operation period. After the slurping process for 2 months, contaminated soil was treated with bioremediation process in 2 cells, $15{\times}40$ m, biologically enhanced with adjusting oxygen, moisture and nutrients concentration. Total 1,400 L of microbial inoculant, Naturesys. (Dong Myung Ent. Co.) was added to the pile B, which has an outstanding ability for degrading petroleum hydrocarbons. The results showed that bioremediaton effect in soil with the microorganisms solution is 33% higher than that in soil with only residual bacteria.

Characteristics of VOCs Oxidation using Copper Phthalocyanine Catalysts (구리 프탈로시아닌 촉매의 VOCs 산화 특성)

  • 서성규;윤형선
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.4
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    • pp.515-521
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    • 2004
  • The catalytic oxidation of volatile organic compounds (methanol. acetaldehyde) has been characterized using the copper phthalocyanine catalyst in a fixed bed flow reactor under atmospheric pressure. The catalytic activity for pretreatment conditions was examined by this reaction system. The catalytic activity was ordered as follows: metal free-PC<Cu ($\alpha$)-PC<Cu ($\beta$)-PC The formaldehyde, carbon monoxide as a partial oxidation product of methanol and acetaldehyde over Cu ($\alpha$)-PC catalyst were detected and the conversions of methanol and acetaldehyde were accomplished above 95% over Cu ($\alpha$) -PC, Cu ($\beta$) - PC catalyst at 35$0^{\circ}C$. The pretreated metal free -PC, Cu($\alpha$)-PC, Cu($\beta$)-PC catalysts have been characterised by TGA, EA and XRD analysis. The catalytic activity pretreated with air and $CH_3$OH mixture (P-4) or air only (P-5) was very excellent. XRD and EA results showed that Cu($\alpha$)-PC, Cu($\beta$)-PC were destroyed an(1 new metal oxide such as CuO were formed.

A Study on the Synthesis of Acrylic Phenol Resins and Their Properties as a Paint (아크릴계 페놀수지 합성과 이를 이용한 도료의 물성연구)

  • Hwang, Sue In;Kim, Young Jin;Kim, Dong Kwon
    • Applied Chemistry for Engineering
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    • v.24 no.2
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    • pp.171-176
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    • 2013
  • The need of volatile organic compound (VOC) free coating material has been increased to solve environmental problems such as the global warming. Nowadays, about 70~80% of coating materials used in the worldwide are a liquid type. Therefore, the development of non-solvent coating material that can minimize VOCs emissions is necessary to solve the global warming problem. In this study, acrylic monomers were added to develop non-solvent paints in order to improve disadvantages of the poor adhesion of a conventional phenolic resin caused by acidification. As a result, the blend resins of 2.818 Mpa phenol- formaldehyde resin/poly methyl methacrylate (PE/PMMA) has the best properties and performances for the adhesives.

Measurement of Atmospheric Nitrous Acid(HONO) using DNPH/HPLC in Seoul (DNPH/HPLC에 의한 서울시 대기 중의 Nitrous Acid 측정)

  • 정용국;홍상범;이재훈
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.325-326
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    • 2001
  • 오존은 태양광선의 존재 하에 질소산화물과 VOCs가 관련하여 발생하는 생성물이다. 대기중의 VOCs 는 히드록실 라디칼(hydroxyl radical, OHㆍ)과 같은 자유 라디칼(free radical)과 반응하여 하이드로퍼옥시 라디칼(hydroperoxy radical, HO$_2$ㆍ)과 알킬 퍼옥시 라디칼(alkyl peroxy radical, RO$_2$ㆍ)을 생성해 낸다. 이 퍼옥시 라디칼들은 NO를 NO$_2$ㆍ로 산화시키며 또한 히드록실 라디칼을 재생하며 이 히드록실 라디칼은 다시 VOCs와 반응한다. 그리고, 이때 산화된 NO$_2$는 햇빛에 의해 NO와 자유산소원자(free oxygen atom)로 광분해 되는데, 여기서 생성된 자유산소인자는 산소분자와 반응하여 오존을 생성한다. (중략)

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Studies on the Sensing Mechanism of Conducting Polymer for Volatile Organic Compound Sensing (휘발성 유기화합물 측정을 위한 전도성고분자 센서의 감응기구에 관한 연구)

  • Hwang, Ha-Ryong;Baek, Ji-Heum;Heo, Jeung-Su;Lee, Deok-Dong;Im, Jeong-Ok;Lee, Jun-Yeong
    • Korean Journal of Materials Research
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    • v.11 no.7
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    • pp.599-602
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    • 2001
  • In this study, we fabricated chemically polymerized PPy and PANi films with different selectivity by controlling dedoping time. And the sensing properties and mechanism of VOCs adsorption to conducting polymers were investigated. Thin sensor had higher sensitivity compared to thick one, and dedoped sensor for 1-minute highest sensitivity. Upon gas absorption, polypyrrole exhibited positive sensitivity while polyaniline had negative sensitivity. PPy film show hydrophilic property and PANi film show hydrophobic property. After the gas absorption, the sensitivity increased as a function of polarity of absorbed molecules. These behaviors are due to the polar molecules absorbed with the movable polaron or free carrier, and then it interrupt or generate the movement of polaron and carrier, and then it changes the conductivity of polymer. We found that conducting polymer sensors are very sensitive to the difference in polarity of gas molecules.

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Identification, Characterization, and Efficacy Evaluation of Bacillus velezensis for Shot-Hole Disease Biocontrol in Flowering Cherry

  • Han, Viet-Cuong;Yu, Nan Hee;Yoon, Hyeokjun;Ahn, Neung-Ho;Son, Youn Kyoung;Lee, Byoung-Hee;Kim, Jin-Cheol
    • The Plant Pathology Journal
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    • v.38 no.2
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    • pp.115-130
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    • 2022
  • Though information exists regarding the pathogenesis of the shot-hole disease (SH) in flowering cherry (FC), there has been a lack of research focusing on SH management. Therefore, here, we investigated the inhibitory activities of antagonistic bacteria against SH pathogens both in vitro and in vivo as well as their biochemical characteristics and bioactive compounds. Two biosurfactant-producing bacterial antagonists, identified as Bacillus velezensis strains JCK-1618 and JCK-1696, exhibited the best effects against the growth of both bacterial and fungal SH pathogens in vitro through their cell-free culture filtrates (CFCFs). These two strains also strongly inhibited the growth of the pathogens via the action of their antimicrobial diffusible compounds and antimicrobial volatile organic compounds (VOCs). Crude enzymes, solvent extracts, and biosurfactants of the two strains exhibited antimicrobial activities. Liquid chromatography/electrospray ionization time-of-flight mass spectrometric analysis of the partially purified active fractions revealed that the two antagonists produced three cyclic lipopeptides, including iturin A, fengycin A, and surfactin, and a polyketide, oxydifficidin. In a detached leaf assay, pre-treatment and co-treatment of FC leaves with the CFCFs led to a large reduction in the severity of the leaf spots caused by Epicoccum tobaicum and Bukholderia contaminans, respectively. In addition, the two antagonists produced indole-3-acetic acid, siderophore, and a series of hydrolytic enzymes, along with the formation of a substantial biofilm. To our knowledge, this is the first report of the antimicrobial activities of the diffusible compounds and VOCs of B. velezensis against the SH pathogens and their efficiency in the biocontrol of SH.

USN Environmental Gas Sensing System using Quad Rotor (초소형 비행체 Quad Rotor를 이용한 USN 환경 가스 센싱 시스템)

  • Lee, Byung-Seok;Lee, Joon-Hwa;Kim, Gyu-Sik;Kim, Jo-Chun
    • Proceedings of the KIEE Conference
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    • 2008.04a
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    • pp.45-46
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    • 2008
  • There are various polluting emissions related to the air quality such as $NO_x$, $CO_2$, CO, VOCs, $O_3$, $SO_2$, $CH_4$, $H_2S$, $NH_3$, etc. We need the system that reduces emission of these environment gases and detects risk factors in modern society. Therefore, if we use the USN(Ubiquitous Sensor Network) technology and a MAV(Micro Air Vehicle) Quad Rotor which can be hovering and moving free for setting up the environment gas sensing system, the realtime measurement on environment gases is facilitated and by extension, in application of traffic watchdog, forest fire surveillance and counter-terrorism efforts, we anticipate making better use of a Quad Rotor.

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Improvement of Strength in ALC using Admixtures and Grain Size (혼합재 및 입도에 따른 경량기포콘크리트의 강도특성 개선)

  • Kim, Young-Yup;Song, Hun;Lee, Jong-Kyu;Chu, Yong-Sik
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2007.11a
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    • pp.79-82
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    • 2007
  • Recently, the use of ALC has became increasingly popular. ALC is a unique building material. Because of its cellular nature, it is lightweight, self-insulating, sound and fireproof, as well as insect and mold resistant. Furthermore, ALC is free of VOCs and various fibers associated with wood and glass wool construction. However, ALC have high water absorption, low compressive strength and popout the origin of the low surface strength in its properties. These properties make troubles under construction such as cracking and popout. Thus, this study is to improve the fundamental strength by controls of increasing of admixtures, and grain size. Admixtures make use of metakaolin, silica fume, sodium silicate and sodium hydroxide. From the test result, the ALC using admixture have a good fundamental properties compared with plain specimen. Compressive strength, specific strength and abrasion's ratio were improved depending on increasing admixtures ratio's, and grain size.

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Economic Evaluation of National Highway Construction Projects using Real Option Pricing Models (실물옵션 가치평가모형을 이용한 국도건설사업의 경제적 가치 평가)

  • Jeong, Seong-Yun;Kim, Ji-Pyo
    • International Journal of Highway Engineering
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    • v.16 no.1
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    • pp.75-89
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    • 2014
  • PURPOSES : This study evaluates the economic value of national highway construction projects using Real Option Pricing Models. METHODS : We identified the option premium for uncertainties associated with flexibilities according to the future's change in national highway construction projects. In order to evaluate value of future's underlying asset, we calculated the volatility of the unit price per year for benefit estimation such as VOTS, VOCS, VICS, VOPCS and VONCS that the "Transportation Facility Investment Evaluation Guidelines" presented. RESULTS : We evaluated the option premium of underlying asset through a case study of the actual national highway construction projects using ROPM. And in order to predict the changes in the option value of the future's underlying asset, we evaluated the changes of option premium for future's uncertainties by the defer of the start of construction work, the contract of project scale, and the abandon of project during pre-land compensation stages that were occurred frequently in the highway construction projects. Finally we analyzed the sensitivity of the underlying asset using volatility, risk free rate and expiration date of option. CONCLUSIONS : We concluded that a highway construction project has economic value even though static NPV had a negative(-) value because of the sum of the existing static NPV and the option premium for the future's uncertainties associated with flexibilities.

Analyses of the current market trend and research status of indoor air quality control to develop an electrostatic force-based dust control technique (정전기적 힘을 이용한 실내공기 미세부유먼지 제거 요소기술의 개발을 위한 기술별 시장현황 및 연구 동향 분석)

  • Yoon, Young H.;Joo, Jin-Chul;Ahn, Ho-Sang;Nam, Sook-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.12
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    • pp.6610-6617
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    • 2013
  • This study examined the current and future Indoor Air Quality (IAQ) control device markets and analyzed the recent studies on indoor air pollutantr emoval to develop a new technology for fine dust control. Currently, the mechanical filter technique occupies the bulk of the IAQ control market but the electronic technique is emerging as an alternative to control fine dust efficiently. Among the gaseous VOCs and fine dust particles contaminating the indoor air quality, fine dust particles are more problematic because they threaten human health by penetrating deep into the body and producing secondary contaminants by chemical reaction with VOCs. The electronic IAQ control device using dielectrophoretic and electrostatic forces is a good option for public spaces where many people pass, and at the same time, it needs to consider temperature, humidity, and the particle properties of specific areas to highlight the control efficiency. Electronic-related technology is expected to be used widely in many public/private spaces wherever a dust-free environment is required.