• Current Optics and Photonics
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• v.3 no.1
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• pp.16-21
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• 2019

We present a broad-bandwidth comb-spacing-swept source (CSWS) based on a differential polarization delay line (DPDL) for interferometric three-dimensional (3D) imaging. The comb spacing of the CSWS is repeatedly swept by the tunable DPDL in the multiwavelength source to provide depth-scanning optical coherence tomography (OCT). As the polarization differential delay of the DPDL is tuned from 5 to 15 ps, the comb spacing along the wavelength continuously varies from 1.6 to 0.53 nm, respectively. The wavelength range of various semiconductor optical amplifiers and the cavity feedback ratio of the tunable fiber coupler are experimentally selected to obtain optimal conditions for a broader 3-dB bandwidth of the multiwavelength spectrum and thus provide a higher axial resolution of $35{\mu}m$ in interferometric OCT imaging. The proposed CSWS-OCT has a simple imaging interferometer configuration without reference-path scanning and a simple imaging process without the complex Fourier transform. 3D surface images of a via-hole structure on a printed circuit board and the top surface of a coin were acquired.

• Bulletin of the Korean Chemical Society
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• v.20 no.3
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• pp.285-290
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• 1999

In the present paper, we report a molecular dynamics (MD) simulation study for the structure and dynamics of H+ ions in non-rigid dehydrated H12-A zeolite framework at 298.15 K, using the same method we used in our previous studies of rigid and non-rigid zeolite-A frameworks. It is found that two different structures appear, depending on the choice of the Lennard-Jones parameter (σ) for the H+ ion, as is also observed in the study of rigid dehydrated H12-A zeolite framework, but the ranges of σ are different for the two structures. It is also found that some of the H+ ions exchanged their sites without changing the number of H+ ions at each site. The agreement between experimental and calculated structural parameters for non-rigid dehydrated H12-A zeolite is generally quite good. The calculated IR spectrum by Fourier transform of the total dipole moment auto-correlation function shows two major peaks, one around 2700 cm-1 and the other around 7000 cm-1. The former appears in the calculated IR spectra of non-rigid zeolite-A framework only system and the latter remains unexplained except, perhaps, as an indication of a new formation of a vibrational mode of the framework due to the adsorption of the H+ ions.

• Journal of the Korean Physical Society
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• v.73 no.10
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• pp.1486-1494
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• 2018

Based on the semiclassical theory of chaotic scattering, Tanner et al. [J. Phys. B 40, F157 (2007)] proposed the fluctuation in the partial photoionization cross section of helium below the double-ionization threshold would show the same characteristics as in the total cross section, predicting that the Fourier spectrum of the fluctuation reveals peaks at the classical actions of closed triple collision orbits and the amplitude of the fluctuation decreases algebraically as the energy approaches the double-ionization threshold. In that paper, however, the predictions were not clearly confirmed due to the lack of experimental data with sufficient accuracy. So instead, we calculate the partial photoionization cross sections of collinear eZe helium for the energy range from the single-ionization threshold $I_{20}$ to $I_{32}$ in order to numerically confirm the predictions. Analysis of the fluctuation in the partial cross section shows that the predictions are indeed valid. Our findings mean that the fluctuation in the partial photoionization cross section can be described by classical triple collision orbits in the semiclassical limit. Thus it explains in a natural way the mirroring and mimicking structures observed in cross section signals for different ionization channels.

• Corrosion Science and Technology
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• v.21 no.2
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• pp.111-120
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• 2022

To solve the corrosion problem of industrial equipment and other constructions containing metals, corrosion protection can be performed by using coating which provides a barrier between the metal and its environment. Coatings play a significant role in protecting irons and steels in harsh marine and acid environments. This study was conducted to identify an anti-corrosive epoxy coating for carbon steel composite with 0.1, 0.3, and 0.5 wt% concentrations of nanoparticles of SiO₂ using the dip-coating method. The electrochemical behavior was analyzed with open circuit potential (OCP) technics and polarization curves (Tafle) in 3.5 wt% NaCl and 5 vol% H₂SO₄ media. The structure, composition, and morphology were characterized using different analytical techniques such as X-ray Diffraction (XRD), Fourier Transform Infrared spectrum (FT-IR), and Scanning Electron Microscopy (SEM). Results revealed that epoxynano SiO₂ coating demonstrated a lower corrosion rate of 2.51 × 10^-4 mm/year and the efficiency of corrosion protection was as high as 99.77%. The electrochemical measurement showed that the nano-SiO₂ / epoxy coating enhanced the anti-corrosive performance in both NaCl and H₂SO₄ media.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2020.10a
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• pp.208-208
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• 2020

The aim of this study was to investigate changes in the weight of Zophobas morio larvae and mass of polystyrene foam when the larvae were fed polystyrene for 27 days. Fourier-transform infrared (FTIR) spectrometry was used to determine whether the polystyrene was broken down by the larvae. Forty Z. morio larvae (four replicates with 10 larvae per replicate) were reared in a chamber under controlled conditions with polystyrene foam blocks as their sole diet. The weight of the Z. morio larvae and mass of the polystyrene foam decreased as a function of time. The average weight of the larvae and mass of the polystyrene foam blocks decreased by 16.3 and 6.5%, respectively, over the 27-day period. The FTIR spectrum of Z. morio larvae fed with polystyrene foam did not reveal the unique peaks associated with polystyrene. In conclusion, this study suggests the possibility of using Z. morio larvae as a management technology for degrading waste plastics without a negative environmental effect. Key words : FTIR spectra, plastic biodegradation, polystyrene foam, Zophobas morio larvae.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.7
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• pp.426-439
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• 2017

This review summarizes advantage and limitation in infrared spectroscopy and computational chemistry to understand rhizospheric interaction among organic acids, oxyanions and metal oxides. Since organic acids and metal oxides determine dynamics of oxyanions in the soil environment, knowledge of fundamental mechanisms is a prerequisite for understanding the interactions at soil-water interface. Attenuated total reflectance-fourier transform infrared spectroscopy (ATR-FTIR) is a powerful tool to measure the interfacial reactions. However, the ATR-FTIR measurements are abstruse, because the optical characteristics for measurements are variable depending on the experimental setup. In addition, spectral overlapping is a primary obstacle to the analysis of the interfacial reaction; thus, it is essential to detect and to deconvolute bands for signal interpretation. In this review, we expained the fundamental principle for spectrum processing, and four band identification methods, such as derivative spectroscopy, two-dimension correlation spectroscopy, multivariate curve resolution, and computational chemistry with example of aqueous phosphate speciation. As a result, spectrum processing and computational chemistry improved interpretation and spectral deconvolution of overlapped spectra in relatively simple systems, but it was still unsatisfactory for the problems in more complexed system like nature. Nevertheless, we believed that our challenge would contribute practically to develop adequate analytical procedure, signal processing and protocols that could help to improve interpretation and to understand the interfacial interactions of oxyanions in natural systems.

• The Journal of the Acoustical Society of Korea
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• v.21 no.4
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• pp.361-373
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• 2002

In this paper, we propose a channel normalization method to improve the performance of CMS (cepstral mean subtraction) which is widely adopted to normalize a channel variation for speech and speaker recognition. CMS which estimates the channel effects by averaging long-term cepstrum has a weak point that the estimated channel is biased by the formants of voiced speech which include a useful speech information. The proposed Formant-broadened Cepstral Mean Subtraction (FBCMS) is based on the facts that the formants can be found easily in log spectrum which is transformed from the cepstrum by fourier transform and the formants correspond to the dominant poles of all-pole model which is usually modeled vocal tract. The FBCMS evaluates only poles to be broadened from the log spectrum without polynomial factorization and makes a formant-broadened cepstrum by broadening the bandwidths of formant poles. We can estimate the channel cepstrum effectively by averaging formant-broadened cepstral coefficients. We performed the experiments to compare FBCMS with CMS, PFCMS using 4 simulated telephone channels. In the experiment of channel estimation, we evaluated the distance cepstrum of real channel from the cepstrum of estimated channel and found that we were able to get the mean cepstrum closer to the channel cepstrum due to an softening the bias of mean cepstrum to speech. In the experiment of text-independent speaker identification, we showed the result that the proposed method was superior than the conventional CMS and comparable to the pole-filtered CMS. Consequently, we showed the proposed method was efficiently able to normalize the channel variation based on the conventional CMS.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.27 no.4
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• pp.293-302
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• 1991

The anomalous sea level deviation or storm surge caused by the typhoon Thelma in 1987 are studied analysing tidal observation data at 7 stations in the south coast of Korean peninsula. The surges are calculated by subtracting the predicted tidal height from the observed tidal record. The tidal deviation at these stations along the coast are discussed in association with meteorological data. The sea level anomalies are studied by means of the empirical orthogonal function (EOF) analysis and the fast fourier transform (FFT) method. The results of analysis suggest that the peak value of surges are higher at the tidal stations in semi-enclosed bay and in long narrow channel than at the ones facing with the open sea. From the result of EOF analysis, the temporal and spatial fluctuations of storm surge can be described by the first EOF mode, which explains 63% of the total variances during the passage of typhoon Thelma. The deviation of storm surge in the studied areas indicates bi-modal peak during the passage of typhoon Thelma. From the results of FFT spectrum analysis, the peak of energy of autospectrum for surge, atmospheric pressure, and wind stress appeared at low frequency fluctuations band of 0.008-0.076 cph over the 4 stations. Auto-correlation function of surge showed periodicity, while that of atmospheric pressure and wind stress indicates no periodicity. The result of FFT analysis shows that the typhoon surges are related chiefly with the change of atmospheric pressure in an open bay (Cheju Harbor), but with the wind stress in a semi-enclosed bay (Yeosu Harbor).

• The Journal of Engineering Geology
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• v.14 no.1
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• pp.29-46
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• 2004

It is important to identify geometries of fracture that act as a conduit of fluid flow for characterization of ground water flow in fractured rock. Fracture geometries control hydraulic conductivity and stream lines in a rock mass. However, we have difficulties to acquire whole geometric data of fractures in a field scale because of discontinuous distribution of outcrops and impossibility of continuous collecting of subsurface data. Therefore, it is needed to develop a method to describe whole feature of a target fracture geometry. This study suggests a new approach to develop a method to characterize on the whole feature of a target fracture geometry based on the Fourier transform. After sampling of specimens along a target fracture from borehole cores, effective frequencies among roughness components were selected by the Fourier transform on each specimen. Then, the selected effective frequencies were averaged on each frequency. Because the averaged spectrum includes all the frequency profiles of each specimen, it shows the representative components of the fracture roughness of the target fracture. The inverse Fourier transform is conducted to reconstruct an averaged whole roughness feature after low pass filtering. The reconstructed roughness feature also shows the representative roughness of the target subsurface fracture including the geometrical characteristics of each specimen. It also means that overall roughness feature by scaling up of a fracture. In order to identify the characteristics of permeability coefficients along the target fracture, fracture models were constructed based on the reconstructed roughness feature. The computation of permeability coefficient was performed by the homogenization analysis that can calculate accurate permeability coefficients with full consideration of fracture geometry. The results show a range between $10^{-4}{\;}and{\;}10^{-3}{\;}cm/sec$, indicating reasonable values of permeability coefficient along a large fracture. This approach will be effectively applied to the analysis of permeability characteristics along a large fracture as well as identification of the whole feature of a fracture in a field scale.

• Journal of Food Hygiene and Safety
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• v.32 no.4
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• pp.284-289
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• 2017

Oxidized polyethylene wax (OPEW) is, one of the food additives, used as a coating agent in citrus fruits and nuts. OPEW is authorized to quantum satis in EU, USA, and is acceptable less than 250 mg/kg in Australia and New Zealand. But OPEW is unauthorized as a food additive in Korea. This study was to establish the analytical method of OPEW and demonstrate the effective application of various food samples. We first conducted to compare the various analytical method including acid value (AV), high temperature gel permeation chromatography (HT-GPC), matrix-assisted laser desorption ionization time-of-flight mass spectrometry (MALDI-TOF/MS), gas chromatography flame ionization detector (GC-FID) and fourier transform infrared spectroscopy (FT-IR). This result indicated that FT-IR spectrum of OPEW treated food sample displayed absorption bands for carbonyl group (C=O, $1714cm^{-1}$), ester group (C-O, $1463cm^{-1}$), aliphatic group (C-H, $2916cm^{-1}$). Furthermore, IR spectrum of OPEW treated food sample showed similar tendency with IR spectrum of OPEW standard. Therefore, it is confirmed that analytical method using FT-IR can be detected on analysis of OPEW in food. As a result of monitoring of 111 samples using established analytical method, OPEW was not detected in the food samples.