• Title/Summary/Keyword: fourier series

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Phase Behaviors of the GAP/PTMG Polyurethanes Chain Extended with 3-Azidopropane-1,2-Diol (3-Azidopropane-1,2-diol로 쇄연장된 GAP/PTMG 폴리우레탄의 상거동)

  • Kim, Hyoung-Sug;You, Jong-Sung;Kweon, Jung-Ohk;Kim, Jung-Su;Lee, Tong-Sun;Noh, Si-Tae;Jang, Young-Ok;Kim, Dong-Kuk;Kwon, Sun-Kil
    • Applied Chemistry for Engineering
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    • v.21 no.4
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    • pp.377-384
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    • 2010
  • We perform a comparative study to investigate the properties of the new energetic chain extender (AzPD). A series of poly(glycidyl azide)/poly(tetramethylene oxide)-based energetic segmented polyurethane (GAP/PTMG ESPU) with different chain extender, which is 3-azidopropane-1,2-diol (AzPD), 1,4-butane diol (1,4-BD), or 1,5 pentane diol (1,5-PD), was synthesized by solution polymerization in dimethyl formamide (DMF) and their phase behaviors were investigated. The ESPUs were characterized with Fourier transform infrared-attenuated total reflection spectroscopy (ATR FT-IR), differential scanning calorimetry (DSC), and dynamic mechanical analysis (DMA). The results of the ATR FT-IR analysis of the urethane carbonyl group region showed that the 'free' C=O fraction was higher in GAP/PTMG AzESPU (0.5) than GAP/PTMG BDESPU (0.44) and GAP/PTMG PDESPU (0.41) for 7 days samples after preparation and that it was similar in the range of 0.26~0.29 for three 60 days ESPU samples. DMA curves of the GAP/PTMG AzESPU for 7 days samples showed amorphous polymers, but GAP/PTMG BDESPU and GAP/PTMG PDESPU showed viscoelastic behaviors with rubbery plateau and the flow region. However, DMA curves of the GAP/PTMG AzESPU for 60 days samples showed viscoelastic behaviors with rubbery plateau and the flow region like GAP/PTMG PDESPU, but GAP/PTMG BDESPU did not show the flow region. From phase behaviors with ATR FT-IR, DSC and DMA analysis, GAP/PTMG AzESPU showed good phase-mixing between components. However, it represented viscoelastic behavior of TPE similar to GAP/PTMG PDESPM according to phase equilibrium progress with aging time.

Chemical Characterisation of Organic Functional Group Compositions in PM2.5 Collected at Nine Administrative Provinces in Northern Thailand during the Haze Episode in 2013

  • Pongpiachan, Siwatt;Choochuay, Chomsri;Chonchalar, Jittiphan;Kanchai, Panatda;Phonpiboon, Tidarat;Wongsuesat, Sornsawan;Chomkhae, Kanokwan;Kittikoon, Itthipon;Hiranyatrakul, Phoosak;Cao, Junji;Thamrongthanyawong, Sombat
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.6
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    • pp.3653-3661
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    • 2013
  • Along with rapid economic growth and enhanced agricultural productivity, particulate matter emissions in the northern cities of Thailand have been increasing for the past two decades. This trend is expected to continue in the coming decade. Emissions of particulate matter have brought about a series of public health concerns, particularly chronic respiratory diseases. It is well known that lung cancer incidence among northern Thai women is one of the highest in Asia (an annual age-adjusted incidence rate of 37.4 per 100,000). This fact has aroused serious concern among the public and the government and has drawn much attention and interest from the scientific community. To investigate the potential causes of this relatively high lung cancer incidence, this study employed Fourier transform infrared spectroscopy (FTIR) transmission spectroscopy to identify the chemical composition of the $PM_{2.5}$ collected using Quartz Fibre Filters (QFFs) coupled with MiniVol$^{TM}$ portable air samplers (Airmetrics). $PM_{2.5}$ samples collected in nine administrative provinces in northern Thailand before and after the "Haze Episode" in 2013 were categorised based on three-dimensional plots of a principal component analysis (PCA) with Varimax rotation. In addition, the incremental lifetime exposure to $PM_{2.5}$ of both genders was calculated, and the first derivative of the FTIR spectrum of individual samples is here discussed.

Analysis of the MODIS-Based Vegetation Phenology Using the HANTS Algorithm (HANTS 알고리즘을 이용한 MODIS 영상기반의 식물계절 분석)

  • Choi, Chul-Hyun;Jung, Sung-Gwan
    • Journal of the Korean Association of Geographic Information Studies
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    • v.17 no.3
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    • pp.20-38
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    • 2014
  • Vegetation phenology is the most important indicator of ecosystem response to climate change. Therefore it is necessary to continuously monitor forest phenology. This paper analyzes the phenological characteristics of forests in South Korea using the MODIS vegetation index with error from clouds or other sources removed using the HANTS algorithm. After using the HANTS algorithm to reduce the noise of the satellite-based vegetation index data, we were able to confirm that phenological transition dates varied strongly with altitudinal gradients. The dates of the start of the growing season, end of the growing season and the length of the growing season were estimated to vary by +0.71day/100m, -1.33day/100m and -2.04day/100m in needleleaf forests, +1.50day/100m, -1.54day/100m and -3.04day/100m in broadleaf forests, +1.39day/100m, -2.04day/100m and -3.43day/100m in mixed forests. We found a linear pattern of variation in response to altitudinal gradients that was related to air temperature. We also found that broadleaf forests are more sensitive to temperature changes compared to needleleaf forests.

VARIABLE STARS IN THE REGION OF THE OPEN CLUSTER NGC 1039 (M34) (산개성단 NGC 1039(M34) 영역의 변광성)

  • JEON, YOUNG-BEOM;PARK, YOON-HO;LEE, SANG-MIN;LEE, UIRYEOL;KIM, DONGHYEON;JANG, HYEEUN;CHO, SUNGYOON
    • Publications of The Korean Astronomical Society
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    • v.30 no.3
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    • pp.821-832
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    • 2015
  • As a part of the short-period variability survey (SPVS) at Bohyunsan Optical Astronomy Observatory, we obtained time-series BV CCD images in the region of the open cluster NGC 1039 (M34). The observations were performed for 22 nights from July 29, 2008 to September 26, 2010. We also made LOAO observations for 10 days from September 18, 2009 to October 30, 2010 to confirm the small variabilties of ${\delta}$ Scuti-type variable stars. In this paper we presented the observational properties of 28 variable stars found in the region. They are seven ${\delta}$ Scuti-type variable stars, two ${\gamma}$ Doradus-type variable stars, four-teen eclipsing binary stars and five semi-long periodic or slow irregular variables, respectively. Only three variables were listed in the GCVS and the rest are newly discovered ones. We have performed multiple-frequency analysis to determine pulsation frequencies of the ${\delta}$ Scuti-type and ${\gamma}$ Doradus-type variable stars, using the discrete Fourier transform and linear least-square fitting methods. We also have derived the periods and amplitudes of 12 eclipsing binaries from the phase fitting method, and presented the light curves of all variable stars.

Analysis of the CATR Equipped with the Novel Shark-Fin Shaped Serrations by the Height Modulation (높이가 다른 Shark-Fin 형태의 서레이션을 갖는 CATR의 특성 해석)

  • Choi, Dong-Won;Choi, Hak-Keun;Park, Jae-Hyun;Lim, Seong-Bin
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.21 no.4
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    • pp.371-380
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    • 2010
  • The CATR(Compact Antenna Test Range) is a testing facility which is to provide the uniform plane wave by using the reflector. As the ripple of the uniform plane wave caused by the diffraction rays at the edge of the reflector, serrations are attached at the edge of the reflector to minimize the ripple of the uniform plane wave in the CATR. The diffraction field of the serration is normally analyzed by the Fresnel diffraction formula which is expressed as the double integration, and the structure of the serration is expressed as Fourier series to apply the double integration of the Fresnel diffraction formula. In this paper, the novel shark-fin shaped serrations which have the height modulation of the adjacent serrations are proposed. And the triangular serrations and the novel shark-fin shaped serrations are compared to confirm that the performance of the quiet zone by the shark-fin shaped serrations is better than by the triangular serrations. It is also confirmed that the novel shark-fin shaped serrations which have the height modulation of the adjacent serrations are lower ripple than which have the same height of the adjacent serrations. Accordingly, the novel shark-fin shaped serrations with the height modulation can be used at the edge of the reflector to provide the uniform plane wave in CATR.

Surface Elevation Recovery Methods from Pressure Gage for Irregular Waves (불규칙파(不規則波에) 대한 압력식(壓力式) 파고계(波高計)의 적용성(適用性)에 관한 연구(研究))

  • Kwon, Jung Gon;Kang, Ju Bok
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.12 no.4_1
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    • pp.129-136
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    • 1992
  • A precedure for recovering surface displacement from a time series of pressure measured by a pressure gage in a shallow water (that is, FFTM, LCM. IWM) is investigated with respect to a proper cut-off-frequency of a frequency response function for the accurate recovery of wave height and period. The authors examined the applicability of above mentioned three transformation procedures through field observations and laboratory experiments and the following results are obtained. i) The cut-off-frequency of the frequency response function used in FFTM is deeply depend on both the frequency response of the pressure sensor and the water depth at the sensor. In this study, a relatively accurate surface displacement can be recovered when the frequency response function is cut off at the frequency corresponding to kh=3.0 where k is a wave number at the depth of h. The frequency response function in the region higher than the cut-off-frequency is set constant to be the value at the cut-off-frequency. ii) The transformed surface displacements by LCM are affected by the small waves of short periods included in the measured pressure. It is found that pressure variation whose local frequency is higher than kh=1.5 has to be neglected to recover surface displacement sufficiently. iii) In IWM, the linear pressure response function is usually utilized by multiplying a coefficient N which is a function of the frequency (or kh) and takes a value around unity. However, in this study, a constant value of N(=1.0) gives a relatively accurate recovery of surface displacements.

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VARIABLE STARS IN THE REGION OF CYG OB3 ASSOCIATION CENTERED ON THE OPEN CLUSTER NGC 6871 I: δ SCUTI TYPE STARS (산개성단 NGC 6871을 중심으로 한 Cyg OB3 성협 영역의 변광성 I: δ Scuti 형 변광성)

  • Jeon, Young-Beom;Lee, Uiryeol;Park, Yoon-Ho;Kim, Donghyeon;Jang, Hyeeun;Cho, Sungyoon
    • Publications of The Korean Astronomical Society
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    • v.27 no.5
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    • pp.399-409
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    • 2012
  • As a part of the short-period variability survey (SPVS) at Bohyunsan Optical Astronomy Observatory, we obtained time-series BV CCD images in the region of Cyg OB3 association centered on the open cluster NGC 6871. The observations were performed for 18 nights from September 5, 2008 to September 1, 2009. We found 15 short-period variable stars in the region. They are ${\delta}$ Scuti type stars belonging to the local spiral arm, Orion spur. Among them, only two stars were previously known, and the rest are newly discovered ones. In this paper, we have performed a multiple-frequency analysis to determine frequencies of the 15 ${\delta}$ Scuti type stars, using the discrete Fourier transform and linear least-square fitting methods. One of the newly discovered variable stars is a double-mode ${\delta}$ Scuti type star with the fundamental and the first overtone modes, and two are high amplitude ${\delta}$ Scuti stars.

Development of Macro-Element for the Analysis of Elastically Supported Plates (탄성 지지된 판구조 해석을 위한 매크로 요소의 개발)

  • 강영종;박남회;앙기재;최진유
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.13 no.1
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    • pp.25-35
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    • 2000
  • The superstructure of general bridge like slab bridge and slab on girder bridge is composed of elastically supported isotropic plate. The objective of this study is to develop the new analysis method for elastically supported plate with general edge beam or girder(boundaries) under arbitrary out of plane loading. The displacement solutions for the macro-element of plate and beam are obtained by solving for the unknown interactive forces and moments at the beam or nodal line locations after satisfying equilibrium equation along the nodal line. The displacement functions for macro-elements ate proposed in single Fourier series using harmonic analysis, and the equilibrium equations of nodal line are composed by using slope-deflection method. The proposed analysis method is programmed by MS-Fortran and can be applied to all types of isotropic decks with bridge-type boundaries. Numerical examples involving elastically supported plates with various aspect ratio, loading cases, and bridge-type boundary conditions are presented to demonstrate the accuracy of this program. The major advantage of this new analysis method is the development of a simple solution algorithm, leads to obtain rapidly responses of bridge deck system. This proposed method can be used in parametric study of behavior of bridge decks.

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Clustering of Web Objects with Similar Popularity Trends (유사한 인기도 추세를 갖는 웹 객체들의 클러스터링)

  • Loh, Woong-Kee
    • The KIPS Transactions:PartD
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    • v.15D no.4
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    • pp.485-494
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    • 2008
  • Huge amounts of various web items such as keywords, images, and web pages are being made widely available on the Web. The popularities of such web items continuously change over time, and mining temporal patterns in popularities of web items is an important problem that is useful for several web applications. For example, the temporal patterns in popularities of search keywords help web search enterprises predict future popular keywords, enabling them to make price decisions when marketing search keywords to advertisers. However, presence of millions of web items makes it difficult to scale up previous techniques for this problem. This paper proposes an efficient method for mining temporal patterns in popularities of web items. We treat the popularities of web items as time-series, and propose gapmeasure to quantify the similarity between the popularities of two web items. To reduce the computation overhead for this measure, an efficient method using the Fast Fourier Transform (FFT) is presented. We assume that the popularities of web items are not necessarily following any probabilistic distribution or periodic. For finding clusters of web items with similar popularity trends, we propose to use a density-based clustering algorithm based on the gap measure. Our experiments using the popularity trends of search keywords obtained from the Google Trends web site illustrate the scalability and usefulness of the proposed approach in real-world applications.

Suitability evaluation of magnesium substituted biphasic calcium phosphates prepared by coprecipitation method (공침법을 이용한 마그네슘이 첨가된 biphasic calcium phosphate의 적합성 평가)

  • Lee, Hyoung-Sin;Kim, Tae-Wan;Kim, Dong-Hyun;Park, Hong-Chae;Yoon, Seog-Young
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.5
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    • pp.237-242
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    • 2010
  • Magnesium-substituted BCP (biphasic calcium phosphate) powders were prepared by incorporating small amounts of magnesium into the structure of different hydroxyapatite (HAp)/${\beta}$-tricalcium phosphate (${\beta}$-TCP) ratios through coprecipitation method. A series of magnesium substitutions ranging from 0, 0.5, and 1.0 wt%, which are comparable to the measured magnesium contents, were performed. The obtained powders were characterized by the following analytical techniques: X-ray diffraction analysis (XRD), Thermo Gravimetric Analyzer (TGA) and Fourier transform infrared spectroscopy (FT-IR). The results have shown that substitution of magnesium in the calcium-deficient apatites resulted in the formation of biphasic mixtures of different HAP/${\beta}$-TCP ratios after heating above $1000^{\circ}C$. The 1.0 wt% magnesiumsubstituted-BCP were soaked in Hank's solutions after 2 weeks to observe the morphology of the biocement, especially needle-like hydroxyapatite crystals and to estimate the length and diameter of nanoneedle crystals.