• 한국세라믹학회지
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• 제28권6호
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• pp.495-501
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• 1991

This study is intended to make defect-free region, denuded zone at the silicon wafer surface for semiconductor device substrates. In this experiment, initial oxygen concentration of starting material CZ-grown silicon wafer, various heat treatment combinations, denuding ambient and the amounts of oxygen reduction were measured, and then denuded zone (DZ) formation and depth were investigated. In Low/High anneal (DZ formation could be achieved), the optimum temperature for Low anneal was 700$^{\circ}C$∼750$^{\circ}C$. In case of High anneal, with the time increased, DZ depth was increased at 1000$^{\circ}C$, 1150$^{\circ}C$ respectively, but on the contrary, DZ depth was decreased at low temperature 900$^{\circ}C$. As well, out-diffusion time below 2 hours was unsuitable for effective Gettering technique even though the temperature was high, and DZ formation could be achieved when initial oxygen concentration was only above 14 ppm in silicon wafer.

• 한국세라믹학회지
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• 제31권11호
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• pp.1346-1354
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• 1994

In this study, the formation of magnetite using Fe(II) and Fe(III) hydroxides was investigated; The effects of hydroxide synthesizing pH and temperature, reaction temperature, and total water volume of hydroxide suspensions on the magnetite formation were studied. And the basic reaction behaviors of magnetite formation was discussed in the view of hydroxide formation reaction of Fe(II) and Fe(III) by titration. The characteristics of products were examined by TEM, VSM, XRD. From these experimental data, solid-solid reaction between Fe(II) and Fe(III) hydroxides is proposed as a new ferrite formation mechanism.

• 대한기계학회논문집B
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• 제24권3호
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• pp.390-401
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• 2000

In this study, numerical calculation is carried out to investigate the influence of injection timing, fuel amount, intake $O_2$ concentration, and EGR on Nitric Oxide(NO) formation using a two-zone model in a diesel engine. Results can be summarized as follows. The NO formation is very sensitive to the burned gas temperature, so multi-zone model must be applied to combustion process to predict the burned gas temperature exactly. Since the burned gas temperature increases rapidly during the premixed combustion, most NO is formed within 20 crank angle degrees after ignition. As the injection timing is retarded, the combustion occurs later in the expansion process which causes the decrease of burned gas temperature and, as a result, NO formation decrease. The increase of fuel amount results in the increase of earlier formation of NO in the engine. As the intake $O_2$ concentration increases, the maximum pressure and burned gas temperature increase due to activate combustion. And, [O] mole fraction of equilibrium combustion products also increase. Therefore NO exponentially increases. If exhaust gas is recirculated, the burned gas temperature decreases which results in NO decrease. If exhaust gas is cooled, more NO can be decreased.

• 펄프종이기술
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• 제46권5호
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• pp.27-34
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• 2014

In-situ $CaCO_3$ formation onto recycled wood pulp was studied to improve optical properties and ash attachment to the fiber furnish in papermaking. We controlled initial reaction temperature of in-situ $CaCO_3$ formation method from $30^{\circ}C$ to $50^{\circ}C$. It was found that the attachment of newly formed $CaCO_3$ to recycled fibers, old newspaper (ONP) in this case, was stronger than that of ground calcium carbonate (GCC, mean dia. $2.4{\mu}m$) addition case, but was not much different among those formed at different temperature. Morphologies of newly formed $CaCO_3$ were changed according to the reaction temperature. More aragonite shape was seen at higher temperature. In-situ $CaCO_3$ formation increased brightness and lowered ERIC value of ONP sheet greatly at the same level of ash contents when compared to GCC addition method, but gave equivalent ERIC and brightness when compared to those of the precipitated calcium carbonate (PCC) addition method. However, tensile strength of the handsheets of the in-situ $CaCO_3$ formation method were much greater than those of the PCC addition method.

• 자원환경지질
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• 제15권4호
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• pp.177-188
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• 1982

The Chungju and Seosan Groups have been known usually as Precambrian formations in Korea. But their relative and absolute ages have been controvericial problem in relation with other geologic system such as so-called Ogcheon and Yeoncheon Systems in Korea. This study has mainly focused on the corelation of the Chungju Group with the Seosan Group in their stratigraphy, structure, metamorphism, and iron ore deposits. In the process of study, the auther surveyed and reclassified the Chungju and Seosan Groups and corelated with Gyeonggi and Ogch cheon metamorphic belts and got some new data. The Chungju iron-bearing formations showing transtitional relation with the Gyeonggi Gneiss Complex and the Jangamri Formation consisting mainly of pebble bearing calcarious phyllite, should be seperated from the Gyemyeongsan formation which is mainly composed of metavolcanic rocks. The Jangamri Formation and the coaly phyllite, which can be corelated respectively with the Hwaggangri Formation and Changri Formation in Ogcheon Group, are repeated in the Gyemyeonsan and Munjuri Formations with the overturned anticlinal folding(F1). So the Chungju Group which was defined as an indipendant geologic unit from the Ogcheon Group should be limited only on the Chungju iron Formation. The Seosan Group can be classified stratigraphically such as Seosan Formation consisting of iron-bearing quartzite and mica schist, Daesan Formation overlying unconformably on the Seosan Formation and Gyeonggi Gneiss Complex. Taean Formation overlying unconformably on the Daesan Formation should be seperated from Seosan Group. There are many similarity in the stratigrphy, structure, and metamorphic facies between Chungju and Seosan Groups exept the metavolcanic rocks in the Gyemyeongsan and Munjuri Formations and the pebble bearing calcareous phyllite in the Jangamri Formation. The two Groups were deformed with two kinds of differant stages, the first shows $N30^{\circ}-40^{\circ}E$ trend of fold axis, the second $N70^{\circ}-80^{\circ}W$ respectively. The Seosan Formation, which is the lowest formation in Seosan Group and bearing the iron formation, was metamorphosed at 2500 m. y. before. These age is similar with the metamorphic age of Gyeonggi metamorphic belt and with the age of Algoman and Kenoran Orogenies which devide the Precambrian into Archean and Proterozoic Era. So the Seosan Formation, which is included in some migmatitic rocks of Gyeonggi Gneiss Complex, is the oldest formation in Korea and can be corelated with the Anshan Group which bears the oldest iron formation in China. The metamorphic facies of the Precambrian metamorphism in Seosan area is simillar with that of Chungju area, showing high temperature-low pressure amphibolite facies which is corelated with the Gyeonggi metamorphic belt, the oldest metamorphic belt in Korea ($650^{\circ}-680^{\circ}C$, 3.2-4.4 Kb). The high temperature intermediate pressure amphibolite facies in Seosan area with the low temperature-intermediate presure greenschist facies of Taean formation is corelated with that of Ogcheon Group ($590^{\circ}-640^{\circ}$ C, 5.2-6.3 Kb). The Chungju and Seosan iron formations were deposited in Archean, showing geochemical composition of Precambrian iron formations. The Chungju iron formation was mainly formed by the chemical precipitation, on the other hand, the Seosan iron formation was formed by alternated action of chemical and detrital depositions.

• 한국세라믹학회지
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• 제29권12호
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• pp.981-989
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• 1992

This is a study on the effects of cristobalite transition of quartz in semi-vitrious whiteware body, as addition of alkali and alkali earth oxides, prepared by pottery stone, feldspar, kaolin and clay minerals. The amounts of ${\alpha}$-quartz to ${\alpha}$-cristobalite transition, F.O.C. (fraction of cristobalite), were increased with firing temperature. In MgO added body, ${\alpha}$-quartz was decreased and the formation of cristobalite was increased. Effects of K2O addition was remarkably decreased the formation of cristobalite. Additive effects of MgO and K2O were confirmed that it was very different to variation of transition temperature of metakaolinite to Si-Al spinel structure in thermal reaction of kaolinite minerals. Result CaO addition was ineffective to transition temperature, and the transition temperature in Na2O added body was decreased, but relative intensity of quartz and cristobalite crystal in XRD results was decreased. This was characterized by the effects on the formation of liquid phase much more.

• 한국세라믹학회지
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• 제37권4호
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• pp.332-337
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• 2000

Forming mechanism of fibrous TiC during self-propagating high temperature synthetic reaction was analyzed and suggested. It was revealed that critical temperature for the stable fiber formation was not the melting point of TiC, but the eutectic reaction temperature of TiC and C. Minimum amount of TiC diluent addition required to form fibers was calculated to be 25.6%, which was consistent with the experimental result. Synthesized fibers were found hollow tube-like. The morphology was explained by the diffusion rates of C and Ti in TiC, and by the molar volume chnage of C during the reaction. Expanding shell model was suggested for the hollow fiber formation mechanism.

• Nuclear Engineering and Technology
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• 제50권7호
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• pp.1190-1197
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• 2018

Analysis of the GRSW-A model coupled into the FALCON code is extended by simulation of central void formation in fuel pellets due to high-temperature fuel restructuring. The extended calculation is verified against published, well-known experimental data. Good agreement with the data for a central void diameter in pellets of the rod irradiated in an Experimental Breeder Reactor is shown. The new calculation methodology is employed in comparative analysis of modern BWR fuel behavior under assumed high-power operation. The initial fuel porosity is shown to have a major effect on the predicted central void diameter during the operation in question. Discernible effects of a central void on peak fuel temperature and Pellet-Cladding Mechanical Interaction (PCMI) during a simulated power ramp are shown. A mitigating effect on PCMI is largely attributed to the additional free volume in the pellets into which the fuel can creep due to internal compressive stresses during a power ramp.

• Bulletin of the Korean Chemical Society
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• 제8권2호
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• pp.118-122
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• 1987

The micelle formation of NaDC was studied by fluorometric and viscometric measurements. The thermodynamic parameters of the primary and secondary micellization of the bile salt were evaluated. The primary micelle formation was appeared to be an entropy driven process due to hydrophobic effect, while the major driving force for secondary micelle formation of the bile salt is the large negative enthalpy. The secondary micelle provides less hydrophobic environment to pyrene than the primary micelle does. The cooperative aggregation of primary micelles via hvdrogen bond formation was proposed for the secondary micelle formation.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.539-542
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• 2001

In SiC semiconductor device processing, it needs high temperature anneal for activation of ion implanted dopants. The macrosteps, 7~8nm in height, are formed on the surface of SiC substrates during activation anneal. We have investigated the effect of thermally-grown SiO$_2$layer on the suppression of macrostep formation during high temperature anneal. The cap oxide layer was found to be efficient for suppression of macrostep formation even though the annealing temperature is as high as the melting point of SiO$_2$. The thin cap oxide layer (10nm) was evaporated during anneal then the macrosteps were formed on SiC substrate. On the other hand the thicker cap oxide layer (50nm) remains until the anneal process ends. In that case, the surface was smoother and the macrosteps were rarely formed. The thermally-grown oxide layer is found to be a good material for the suppression of macrostep formation because of its feasibility of growing and processing. Moreover, we can choose a proper oxide thickness considering the evaporate rate of SiO$_2$at the given temperature.