• Bulletin of the Korean Chemical Society
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• v.31 no.2
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• pp.453-456
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• 2010

The structural and energetic preferences of thiacalix[4]biscrown-5 with and without alkali metal ions ($Na^+$, $K^+$, $Rb^+$, and $Cs^+$) have been theoretically investigated for the first time using molecular dynamic (MD) simulations and density functional theory (MPWB1K/6-31G(d)//B3LYP/6-31G(d)) methods. The formation of the metal ion complex by the host is mainly driven by the electrostatic attraction between crown-5 oxygens and a cation together with the minor contribution of the cation-$\pi$ interaction between two facing phenyl rings around the cation. The computed binding energies and the atomic charge distribution analysis for the metal binding complexes indicate the selectivity toward a potassium ion. The theoretical results herein explain the experimentally observed extractability order by this host towards various alkali metal ions. The physical nature and the driving forces for cation recognition by this host are discussed in detail.

• Journal of The Korean Astronomical Society
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• v.37 no.5
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• pp.571-574
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• 2004

Clusters of galaxies are filled with X-ray emitted hot gas with the temperature of T ${\~}$2-10 keV. Recent X-ray observations have been revealing unexpectedly that many cluster cores have complicated, peculiar X-ray structures, which imply dynamical motion of the hot gas. Moreover, X-ray spectra indicate that radiative cooling of the cool gas is suppressed by unknown heating mechanisms (the 'cooling flow problem'). Here we propose a novel mechanism reproducing both the inhomogeneous structures and dynamics of the hot gas in the cluster cores, based on state-of-the-art hydrodynamic simulations. We showed that acoustic-gravity waves, which are naturally expected during the process of hierarchical structure formation of the universe, surge in the X-ray hot gas, causing a serous impact on the core. This reminds us of tsunamis on the ocean surging into an distant island. We found that the waves create fully-developed, stable turbulence, which reproduces the complicated structures in the core. Moreover, if the wave amplitude is large enough, they can suppress the cooling of the core. The turbulence could be detected in near-future space X-ray missions such as ASTRO-E2.

• International Journal of Fluid Machinery and Systems
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• v.3 no.2
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• pp.102-112
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• 2010

Artificial heart pumps have attracted the attention of researchers around the world as an alternative to the organ used in cardiac transplantation. Conventional centrifugal pumps are no longer considered suitable for long-term application because of the possibility of occurrence of blood leakage and thrombus formation around the shaft seal. To overcome this problem posed by the shaft seal in conventional centrifugal pumps, the magnetically suspended centrifugal pump has been developed; this is a sealless rotor pump, which can provide contact-free rotation of the impeller without leading to material wear. In Europe, clinical trials of this pump have been successfully performed, and these pumps are commercially available. One of the aims of our study is to numerically examine the internal flow and the effect of leakage flow through the gap between the impeller and the pump casing on the performance of the pump. The results show that the pressure head increases compared with the pump without a gap for all flow rates because of the leakage of the fluid through the gap. It was observed that the leakage flow rate in the pump is sufficiently large; further, no stagnant fluid or dead flow regions were observed in the pump. Therefore, the present pump can efficiently enhance the washout effect.

• The Bulletin of The Korean Astronomical Society
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• v.40 no.2
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• pp.31.1-31.1
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• 2015

For probing magnetic fields in the universe, rotation measure (RM) have been often used. RM allows us to obtain the information of integrated (or averaged) magnetic fields along a line of sight (LOS). On the other hand, the new technique so-called Faraday tomography will be used in practical in the near future thanks to the wide-band polarimetry by Square kilometre Array and/or its precursors. The technique allows us to obtain so-called Faraday dispersion function (FDF). FDF is the distribution function of magnetic fields and polarized sources along a LOS. Because of this fact, it is expected that the studies of magnetic fields associated with various astronomical objects will progress dramatically. Since FDF also includes information of cosmic-rays and thermal electrons, the investigation of FDF may advance the studies of dynamics of external galaxies and/or the star formation activities. We have studied the potentials of Faraday tomography such as a tool to probe the intergalactic magnetic field associated with filaments of galaxies in the large scale structure. We have also studied the realistic FDFs of galaxies for understanding global magnetic field, cosmic-ray and thermal electrons of external galaxies. In the talk, we briefly introduce the Faraday tomography technique and report the results related to the Faraday tomography.

• The Bulletin of The Korean Astronomical Society
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• v.38 no.2
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• pp.88.2-88.2
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• 2013

Exploration of the wave-mode identification and its propagating property in the solar pore is desirable to study the energy transfer in the solar atmosphere. The Fast Imaging Solar Spectrograph (FISS) installed at the New Solar Telescope (NST) is a unique system that can do imaging of H-alpha and Ca II 8542 band simultaneously, which is quite suitable for studying of dynamics of chromosphere. In this study, we inspect a relationship between the cross-sectional area and intensity of the pore at continuum (-0.4 nm) near the Ca II line. We find coherent oscillations of the area and intensity. They shows out-of-phase (~ 180 degree difference) in photosphere, which implies that the oscillation is fast sausage mode. We also investigate a relationship between LOS velocities above the pore obtained from the Ca II and the Ha line cores, and find no significant difference of the phase (~10 degree) between the formation heights of the lines in chromosphere.

• Journal of The Korean Astronomical Society
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• v.46 no.4
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• pp.173-181
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• 2013

We trace the dynamical evolution of dark matter (DM) content in NGC 6397, one of the native Galactic globular clusters (GCs). The relatively strong tidal field (Galactocentric radius of ~ 6 kpc) and short relaxation timescale (~0.3 Gyr) of the cluster can cause a significant amount of DM particles to evaporate from the cluster in the Hubble time. Thus, the cluster can initially contain a non-negligible amount of DM. Using the most advanced Fokker-Planck (FP) method, we calculate the dynamical evolution of GCs for numerous initial conditions to determine the maximum initial DM content in NGC 6397 that matches the present-day brightness and velocity dispersion profiles of the cluster. We find that the maximum allowed initial DM mass is slightly less than the initial stellar mass in the cluster. Our findings imply that NGC 6397 did not initially contain a significant amount of DM, and is similar to that of NGC 2419, the remotest and the most massive Galactic GC.

• The Transactions of the Korean Institute of Power Electronics
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• v.18 no.6
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• pp.593-600
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• 2013

The asymmetric pulsed DC reactive magnetron sputtering system is widely used for the high quality plasma sputtering process such as a thin film deposition. In asymmetric pulsed DC power supply a reverse voltage is applied to the target periodically to minimize arc discharging effect. When sputtering in the mid-frequency range (20-350 kHz), the periodic target voltage reversals suppress arc formation at the target and provide long-term process stability. Thus, high quality, defect-free coatings of these materials can now be deposited at competitive rates. In this paper, a new style asymmetric pulsed DC power supply including mid-transformer is presented. In the proposed, an energy recovery circuit is adopted to reduce the mutual inductance of the transformer. As a result, the system dynamics of the voltage control loop is increased highly and the non-linear voltage boosting effect of the conventional system is removed. This work was proved through simulation and laboratory based experimental study.

• Korea-Australia Rheology Journal
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• v.16 no.3
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• pp.117-128
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• 2004

The effect of molecular parameters on the steady vortex behaviors in the inertial viscoelastic flow past a cylinder has been investigated. FENE-CR model was considered as a constitutive equation. A recently developed iterative solution method (Kim et al., (in press)) was found to be successfully applicable to the computation of inertial viscoelastic flows. The high-resolution computations were carried out to understand the detailed flow behaviors based on the efficient iterative solution method armed with ILU(0) type pre-conditioner and BiCGSTAB method. The discrete elastic viscous split stress-G/streamline upwind Petrov Galerkin (DEVSS-G/SUPG) formulation was adopted as a stabilization method. The vortex size decreased as elasticity increases. However, the vortex enhancement was also observed in the case of large extensibility, which means that the vortex behavior is strongly dependent upon the material parameters. The longitudinal gradient of normal stress was found to retard the formation of vortex, whereas the extensional viscosity played a role in the vortex enhancement. The present results are expected to be helpful for understanding the inertial vortex dynamics of viscoelastic fluids in the flow past a confined cylinder.

• BMB Reports
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• v.45 no.11
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• pp.623-628
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• 2012

Tissue inhibitor of metalloproteinases (TIMPs; TIMP-1, -2, -3 and -4) are endogenous inhibitor for matrix metalloproteinases (MMPs) that are responsible for remodeling the extracellular matrix (ECM) and involved in migration, invasion and metastasis of tumor cells. Unlike under normal conditions, the imbalance between MMPs and TIMPs is associated with various diseased states. Among TIMPs, TIMP-1, a 184-residue protein, is the only N-linked glycoprotein with glycosylation sites at N30 and N78. The structural analysis of the catalytic domain of human stromelysin-1 (MMP-3) and human TIMP-1 suggests new possibilities of the role of TIMP-1 glycan moieties as a tuner for the proteolytic activities by MMPs. Because the TIMP-1 glycosylation participate in the interaction, aberrant glycosylation of TIMP-1 presumably affects the interaction, thereby leading to pathogenic dysfunction in cancer cells. TIMP-1 has not only the cell proliferation activities but also anti-oncogenic properties. Cancer cells appear to utilize these bilateral aspects of TIMP-1 for cancer progression; an elevated TIMP-1 level exerts to cancer development via MMP-independent pathway during the early phase of tumor formation, whereas it is the aberrant glycosylation of TIMP-1 that overcome the high anti-proteolytic burden. The aberrant glycosylation of TIMP-1 can thus be used as staging and/or prognostic biomarker in colon cancer.

• Journal of Advanced Marine Engineering and Technology
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• v.31 no.7
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• pp.842-851
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• 2007

Oscillating foil propulsion, the engineering application of fish-like movement of a hydrofoil, has received in recent decades as a possible competitor for propellers. The oscillating foil produces an effective angle of attack, resulting in a normal force vector with thrust and lift components, and it can be expected to be a new highly effective propulsion system. We have explored propulsion hydrodynamics as a concept in wake flow pattern. The present study has been examined various conditions such as oscillating frequencies and amplitudes in NACA0010 profile. Flow visualizations showed that high thrust was associated with the generation of moderately strong vortices, which subsequently combine with trailing-edge vorticity leading to the formation of a reverse $K\acute{a}rm\acute{a}n$ vortex street. Vortex generation was inherent to jet production and playeda fundamental role in the wake dynamics. And it was shown that the strong thrust coefficient obtained as the Strouhal number was larger.