• 한국세라믹학회지
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• 제37권7호
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• pp.645-650
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• 2000

Effects of the chemical composition and sintering atmosphere on the formation of reaction phases and physical properties of reactive hot-pressed TiB2-AlN-BN composites were investigated. At N2 atmosphere, TiN was formed by the reaction between Ti and N2, which inhibited the densification and results in inferior mechanical-and electrical properties of the composites. However, at Ar atmosphere, enhanced densification and physical properties of composites were obtained due to that the TiN formation reaction was excluded. Densification of the composites was also hindered by BN, therefore, inferior mechanical-and electrical properties of composites were obtained with amount of BN in the starting materials. At Ar atmosphere, TiB2-AlN-BN composites having 318 MPa of flexural strength, 3.5 MPa.m1/2 of fracture toughness and 276$\mu$Ω.cm of electrical resistivity were fabricated from mole ratio 1:2:1.6 of Ti-Al-BN mixtures.

• 한국세라믹학회지
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• 제27권8호
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• pp.1055-1063
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• 1990

The early hydration characteristics of the system $C_3S-C_3A-C_4AF$ according to the clinker composition variations, in order to establish the mutual interactionof clinker minerals during the portland cement hydration, have been studied. The early hydration rate of $C_3S$ was greatly effected by the change of $C_3S/C_3A$ ratio. The lower the $C_3S/C_3A$ ratio was, the faster the apex reaching time and the rate of heat liberation of the 2nd exothermic peak originating from the formation of $Ca(OH)_2$ were. The effect of $C_3S/C_3A$ ration on the amounts of $Ca(OH)_2$ formation was decreased, in process of hydration time, but the effect of $C_3S$ content was increased.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2001년도 제23회 KOSCO SYMPOSIUM 논문집
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• pp.27-34
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• 2001

The soot formation characteristics have been studied experimentally in concentric co-flow ethylene/propane diffusion flames. Comparing to the homogeneously mixed propane/ethylene case, the increase of soot formation is observed when propane is supplied through the outer nozzle, while the decrease is observed when propane is supplied through the inner nozzle. The reaction path of PAHs formed from the pyrolysis process of propane is likely to be responsible to the observed difference. When propane is supplied through the outer nozzle, PAHs formed during the combustion process are easy to be exposed to the oxidization environment; however, when propane is supplied through the inner nozzle, PAHs are not likely to be oxidized and thus get involved in soot formation process. The synergistic effect in ethylene/propane diffusion flames is affected not only by the composition of mixture but also by the way of mixing.

• Corrosion Science and Technology
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• 제5권4호
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• pp.141-148
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• 2006

The chemical composition and the semiconducting properties of the passive films formed on Alloy 690 in various film formation conditions were investigated by XPS, photocurrent measurement, and Mott-Schottky analysis. The XPS and photocurrent spectra showed that the passive films formed on Alloy 690 in pH 8.5 buffer solution at ambient temperature, in air at $400^{\circ}C$, and in PWR condition comprise $Cr_2O_3$, $Cr(OH)_3$, ${\gamma}-Fe_2O_3$, NiO, and $Ni(OH)_2$. The thermally grown oxide in air and the passive film formed at high potential (0.3 $V_{SCE}$) in pH 8.5 buffer solution were highly Cr-enriched, whereas the films formed in PWR condition and that formed at low potential (-0.3 $V_{SCE}$) in pH 8.5 buffer solution showed relatively high Ni content and low Cr content. The Mott-Schottky plots exhibited n-type semiconductivity, inferring that the semiconducting properties of the passive films formed on Alloy 690 in various film formation conditions are dominated by Cr-substituted ${\gamma}-Fe_2O_3$. The donor density, i.e., concentration of oxygen vacancy, was measured to be $1.2{\times}10^{21}{\sim}4.6{\times}10^{21}cm^{-3}$ and lowered with increase in the Cr content in the passive film.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 춘계학술대회
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• pp.1378-1383
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• 2003

Synthesis of carbon nanofibers on a metal substrate by an ethylene fueled inverse diffusion flame was illustrated. Stainless steel plates were used for the catalytic metal substrate. The effects of radial distance and residence time of the substrate were investigated. The role of hydrocarbon composition in the fuel was also viewed. Nanofibers with a diameter range of 30-70 nm were found on the substrate. The carbon nanofibers were formed and grown in the region from 4 to 5.5 mm from the central axis of a flame outside of the visible flame front in the radial direction. The minimum residence time required for the formation of carbon nanofibers were about 20 seconds, and over 60 seconds were required for the full-scale growth. The characteristic time of the formation of carbon nanofibers was much shorter than that of the substrate temperature growth. In this study, the variation in hydrocarbon composition had no significant effect on the formation and growth of the carbon nanofibers.

• Corrosion Science and Technology
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• 제7권1호
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• pp.1-5
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• 2008

The gas atmosphere in continuous annealing and galvanizing lines alters both composition and microstructure of the surface and sub-surface of sheet steel. The formation and morphology of the oxides of alloying elements in High Strength Interstitial Free (HS-IF), Dual Phase (DP) and Transformation-Induced Plasticity (TRIP) steels are strongly influenced by the furnace dew point, and the presence of specific oxide may result in surface defects and bare areas on galvanized sheet products. The present contribution reviews the progress made recently in understanding the selective formation of surface and subsurface oxides during annealing in hot dip galvanizing and conventional continuous annealing lines. It is believed that the surface and sub-surface composition and microstructure have a pronounced influence on galvanized sheet product surface quality. In the present study, it is shown that the understanding of the relevant phenomena requires a combination of precise laboratory-scale simulations of the relevant technological processes and the use of advanced surface analytical tools.

• Corrosion Science and Technology
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• 제9권6호
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• pp.247-253
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• 2010

The characteristics of selective oxidation prior to hot-dip galvanizing with the annealing atmosphere dew point and chemical composition in dual-phase steels and their effect on the inhibition layer formation relevant to coating adhesion have been studied using a combination of electron microscopic and surface analytical techniques. The annealed and also galvanized samples of 3 kinds of Si/Mn ratios with varied amounts of Si addition were prepared by galvanizing simulator. The dew point was controlled at soaking temperature $800^{\circ}C$ in 15%$H_2$ -85%$N_2$ atmosphere. It was shown that good adhesion factors were mainly uniformity of oxide particle distribution of low number density and low Si/Mn ratio prior to hot-dip galvanizing. Their effect was the greatly reduced coating bare spots and the formation of uniform inhibition layer leading to good adhesion of Zn overlay. The mechanism of good adhesion is suggested by two processes: the formation of inhibition layer on the oxide free surface uncovered with no $SiO_2$-containing particles in particular, and the inhibition layer bridging of oxide particles. The growth of inhibition layer was enhanced markedly by the delayed reaction of Fe and Al with the increase of Si/Mn ratio.

• 패션비즈니스
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• 제16권2호
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• pp.124-137
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• 2012

This study aims to identify the meaning and formation cause of a style, and the essential elements of style formation, through psychobiological research as well as an analysis of the designs of Iris Van Herpen, a fashion designer, who in just 6 years has developed into a world-renowned new designer. As a result, it has been found that the psychobiological causes to form a style stem from the action of 'long-term memory', which is consolidated by 'selective attention', 'perceptional subjectivity', the principle of the 'neuron's connection specificity and invariance', and the principle of a 'neuronal signal's unilateral flow'. With such action, Herpen could develop her own original composition techniques. The formative shapes created by such composition techniques are characterized by enumeration, superposition, and hanging. The study has also found that the essential elements for a designer to be able to form his/her own style include 'aesthetic originality' in which the designer views the property of a thing from his/her inherent perspective, and finds the uniqueness from the thing that only he/she can express, 'technical differences' that are creative and original, and 'formative specificity' that is summarized into one property through an impressive shape.

• 한국환경보건학회지
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• 제26권4호
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• pp.122-128
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• 2000

This study was carried out to survey trihalomethane formation potential(THMFP) levels in drinking underground water and to examine its characteristics in Kunsan area. In drinking underground water, THMFP increased with the lapse of reaction time and 96hr-THMFP was the highest of THMFPs examined. In many cases, 24hr-THMFP, 48hr-THMFP and 96hr-THMFP reflected 2hr-THMFP level due to the largest composition ratio of CHCl$_3$ decreased with the lapse of reaction of CHCl$_3$ among THM individuals. CHCl$_3$ was mostly formed within early 2hour of reaction time, but CHClBr$_2$ and CHBr$_3$ continued their formation until 48 hour. Accordingly, the composition ratio of CHCl$_3$ decreased with the lapse of reaction time while that of total Br derivatives increased. 96hr-THMFPs of drinking underground water in Kunsan area ranged from N.D.(not detected)~98.80 $\mu\textrm{g}$/$\ell$ and, in general, those of western section of Kunsan area, closer to the coast, showed the higher tendency. But, from their large range of variance, it could be considered that THMFPs differ individually even in the same section depending on such factors as the difference of water stream, circumstances of management and so on. All the parameters for water quality examined(pH, KMnO$_4$ consumption;UV$_{254}$ , TOC. Cl$^{[-10]}$ ) showed very week corelation with 96h-THMFP.

• 한국세라믹학회지
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• 제33권7호
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• pp.785-792
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• 1996

Formation of Solid Solution and Microstructure in Processureless sintered SiC-AlN compo-site using oxides as a sintering aid at 185$0^{\circ}C$ and 195$0^{\circ}C$ Regardless of SiC/AlN ratio in composition most of sintered specimens showed he complex structure mixed with 2H solid solution and SiC particles. High sintering temperature and large AlN content in starting composition enhanced the formation of 2H solid solution in sintered specimen 2H solid solution showed the spherical shape and core-rim structure. AlN content in the core is higher than that in the rim but SiC content . The size of 2H solid solution on fracture showed the transgranular fracture mode compared with the dispersed SiC particles which showed the intergranular fracture mode.