• 제목/요약/키워드: formaldehyde emission

검색결과 183건 처리시간 0.025초

Analytical Methods for Spatial Distribution of Hazardous Air Pollutants (HAPs)

  • Amagai, Takashi
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2010년도 춘계학술대회 논문집
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    • pp.41-44
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    • 2010
  • Hazardous air pollutants such as benzo[a]pyrene (BaP), benzene, formaldehyde have been concerned about the adverse health effect of long-term exposure. Contour map is useful for finding high-concentration region, emission source, and distributions of HAPs in the ambient air. To make a contour map, we have developed simple analytical method for selected HAPs; polycyclic aromatic hydrocarbons such as BaP, benzene and its derivatives such as toluene and xylene, and aldehydes and ketones. We have applied these methods to investigate air pollution by HAPs in some cities in Japan. The results show that these methods reveal actual emission sources if the PRTR emission report was not submitted.

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Characteristics of Volatile Organic Compounds Emitted in Building Materials and Their Predictions of Time-dependent Variation

  • Pang, Seung Ki;Sohn, Jang Yeul;Lee, Kwang Ho
    • Architectural research
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    • 제7권1호
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    • pp.19-26
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    • 2005
  • Unlike other countries, Korea uses various kinds of wall-paper as finishing material. Conventional wall-paper consists of paper and vinyl, and petrochemical ink is used for the decoration of the surface. Adhesive is used to paste the wall with the wall-paper, which emit substantial amounts of VOCs and formaldehyde. In this study, VOCs characteristics emitted from specimens made of concrete, mortar, gypsum board and wall-paper were investigated using small chamber method. Moreover, concentration and emission factor of BTEX(Benzene, Toluene, Ethylbenzene, m,p,o-Xylene) and TVOC were investigated, and concentration and emission factor decay were estimated. As a result of the prediction, both time-dependent concentration decay and cumulative concentration can be converted into the logarithmic scale. Furthermore, prediction equations were developed from the experimental results under accurately controlled experimental conditions. Therefore, there may be difference if the estimated equations are directly applied to real buildings. Further research should be done on the generalization of the developed prediction equations.

거주자 안전을 고려한 친환경건축자재의 HCHO 듬급에 관한 고찰 (A Study on the HCHO Grade of Architectural Material's Standard for Greenness with Consideration for Residents' Safety)

  • 송혁;고성석;정우양
    • 한국안전학회지
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    • 제21권1호
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    • pp.133-140
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    • 2006
  • 1997년 도쿄의정서(protocol)에서는 지구환경오염에 대한 오염원방지를 제안하는 협정으로 우리나라에서도 배출기준에 감소하기 위한 노력의 일환으로 건축자재에 대한 방출농도 기준을 마련하고 있는 실정이다. 그러나, 최근 건축공사에는 많은 종류의 건축자재와 내장재료가 사용되고 있으며, 특히 화학기술의 발달로 복합재료로 구성된 건축재료들에 대한사용이 증가하고 있다. 실내건축자재에서 방출되는 물질로 인하여 재실자들에게 두통, 현기증, 메스꺼움, 졸음, 집중력 감퇴 등의 각종 질병을 불러일으키는 '새집 증후군'과 같은 현상을 야기 시켜 건강 상 많은 영향을 주고 있는 것으로 조사되고 있으며, 이러한 문제 해결을 위해서는 각 나라마다 건축물에 사용되어 지는 건축자재에 대한 유기 화합물의 방출농도를 최소화하는 친환경 건축자재의 선정을 권고하는 실정이다. 이에 본 연구에서는 건축자재의 TVOCs 에 대한 HCHO의 등급기준을 제안하고자 한다.

2005년 6월의 서울시 대기의 포름알데히드 농도분포 특징 (Distributions of Formaldehyde in Seoul in June, 2005)

  • 황정훈;이미혜;이강웅;한진석
    • 한국대기환경학회지
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    • 제22권1호
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    • pp.63-71
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    • 2006
  • An automated carbonyl measurement system was constructed. Atmospheric carbonyl compounds were extracted onto DNPH containing collection solution while flowing through a glass coil. Each carbonyl species was separated on a HPLC column and quantified by UV absorption detector. Using this system, carbonyl compounds were continuously measured at the campus of Korea University in Seoul, Korea during June, 2005. Sampling resolution was 30 minutes and the detection limit of HCHO was 0.19 ppbv. Also, $\O_{3}$, it's precursors, and meteorological parameters were measured. The maximum, minimum, average, and median concentrations of HCHO during the whole experiment was 35.8 ppbv, 1.4 ppbv, 11.7 ppbv, and 9.3 ppbv respectively. Formaldehyde showed a distinct diurnal variation with a broad maximum around 13 $\sim$ 15, which was 1 $\sim$ 3 hours ahead of an ozone maximum. During a couple of days, however, HCHO concentrations were kept high through the night or increased concomitantly with NOx in the morning. These results imply that HCHO was mainly produced from the photochemical oxidation of VOCs, but local emission sources couldn't be ruled out. The differences between daily maximum and minimum of $O_{3}$ and HCHO were calculated for 11 days of June, when typical diurnal variations were observed for the two species. A strong positive correlation was found between $\Delta O_{3}$ and $\Delta HCHO$ and the average mole ratio of $\Delta HCHO$ to $\Delta O_{3}$ was 2.6. It indicates that formaldehyde played a key role in $\Delta O_{3}$ production as an indicator species in Metropolitan Seoul during June, 2005.

목조주택 내 마감자재에 따른 카르보닐화합물의 방산특성 (Emission Characteristics of Carbonyl Compounds Depending on Different Finishing Materials in a Wooden House)

  • 이희영;박상범;강영석;이상민;박종영
    • Journal of the Korean Wood Science and Technology
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    • 제37권1호
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    • pp.12-18
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    • 2009
  • 본 연구는 실내마감자재가 실내공기질에 미치는 영향을 조사하기 위하여 목재주택 내 친환경 마감자재로 처리한 시험실 내부의 카르보닐화합물의 방산특성을 조사하였다. 실험 결과 포름알데히드, 아세톤 및 헥사알데히드가 카르보닐화합물의 대부분을 차지하였으며, 이 중 포름알데히드가 25.6~30.5%로 가장 높은 비중을 차지하였다. 시험실 R2-2를 제외한 모든 시험실에서 포름알데히드 방산량이 신축 공동주택의 실내공기질 권고기준치 이하를 나타내었고, 아세트알데히드의 경우 시험실 R1-3을 제외한 나머지 시험실에서 일본 후생노동성에서 제시한 기준($48{\mu}g/m^3$)을 초과하는 것으로 나타났다. 황토벽지를 사용한 R1-1에서 상대적으로 높은 방산량을 나타내었고, 대나무숯 패널을 설치한 R2-2에서 모든 카르보닐화합물에 대해 높은 방산량을 나타내었다. 편백으로 치장한 거실인 시험실 R1-3은 나머지 시험실에 비해 아세톤을 제외하고 전반적으로 낮은 포름알데히드와 카르보닐화합물 방산량을 나타내었다.

주차장 바닥 코팅제의 휘발성유기화합물 배출에 관한 연구 (A Study on the Emission of VOCs in Parking Lot Floor Coating)

  • 이승찬;윤길호;박용순;길배수;윤현도
    • 한국구조물진단유지관리공학회 논문집
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    • 제23권4호
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    • pp.152-158
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    • 2019
  • 주차장 바닥재로 많이 사용되는 A사 에폭시 코팅제와 B사 바닥코팅제(A, B type)에 대하여 GC/MS(Gaschromatography/Mass spectrometer)를 이용하여 제품별로 함유하고 있는 휘발성유기화합물(VOCs)의 종류와 함량을 측정해보고, 휘발성유기화합물(VOCs)중 작업자나 입주자들에게 유해한 폼알데하이드(Formaldehyde), 톨루엔(Toluene), 크실렌(Xylene)을 외부 환경에 따른 오차를 줄이고자 가장 안 좋은(밀폐) 환경을 가정하고 가스검지관을 이용하여 가스배출량을 측정해 보았다. 그 결과 A사 에폭시코팅제가 제품 자체에도 휘발성유기화합물(VOCs)을 가장 많은 양 함유하고 있고, A사 에폭시코팅제에 비하여 B사 바닥코팅제 A type은 약 79%, B type은 약 96% 이상의 적은 양을 나타냈다. 또한, 밀폐된 환경 조건에서 1시간과 8시간 경과 후 가스검지관을 이용하여 폼알데하이드(Formaldehyde), 톨루엔(Toluene), 크실렌(Xylene)에 대한 가스배출량을 측정하고 TWA값으로 환산한 결과에서도 A사 에폭시코팅제가 가장 높게 측정되었다. A사 에폭시코팅제보다 B사 바닥코팅제 A type은 약 42.3%이상의 적은 측정값을 나타냈으며, B type의 경우 밀폐된 환경 조건에서도 시간가중평균노출기준(TWA)을 모두 만족하였다.

대나무숯 액상코팅제의 제조 및 특성 (Formulation of Liquid Coating Agent using Bamboo Charcoal and its Characteristics)

  • 박상범;이희영;이상민;박종영
    • Journal of the Korean Wood Science and Technology
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    • 제36권6호
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    • pp.113-120
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    • 2008
  • 본 연구는 포름알데히드와 같은 유해화학물질을 저감하고, 인체에 무해한 친환경 건축마감재를 개발하기 위하여 대나무숯분말, 편백추출수 및 바인더를 원료로 이용하여 실내 건축마감재용 액상코팅제를 제조하였다. 편백추출수의 함유량에 따른 액상코팅제의 유해화학물질에 대한 탈취율, 원적외선방사율, 음이온방출량, 항균성 및 실제 소요량을 조사하였다. 액상코팅제의 포름알데히드 탈취율은 60.0~98.6%, 암모니아 탈취율은 76.7~86.2%였다. 편백추출수의 혼합량이 증가함에 따라 탈취율도 증가하는 경향을 보였다. 액상코팅제의 원적외선방사율은 91.7%, 음이온 방출량은 77개/cc 였으며, 세균감소율은 99.4%로 항균력이 우수하였으나, 편백추출수의 혼합량 증가에 따른 이들 값에는 차이가 인정되지 않았다. 액상코팅제의 소요량은 스프레이건을 사용할 경우 $0.66kg/m^2$, 붓칠의 경우 $0.94kg/m^2$로 스프레이건을 이용할 경우가 더 효율적이었다.

EURO III에 의한 이륜자동차의 미량유해물질 배출특성평가 (Evaluation on Emission Characteristics of Trace Hazardous Material from Motorcycle Exhaust by EURO III)

  • 유흥민;손지환;박규태;문선희;윤창완;김정수;이종태
    • 한국분무공학회지
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    • 제20권4호
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    • pp.207-216
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    • 2015
  • Recently, the researches for air pollutant control technologies have been performing in Korea, while considering an one of the latest main topics as problems on air pollutant control. However, it is difficult to investigate emission amount of air pollutant by passenger cars, because of lack of the domestic information about mobile source; the number of research institutes are less in the whole. Especially, the informations on registered numbers and emissions of motorcycles are less. Thus, in this study, the analysis that is based on experimental results was conducted for finding out source profiling and emission characteristics on motorcycles exhaust. For these experiments, the domestic motorcycles were chosen and evaluated by EURO III standard. From the result, controlled pollutants (CO, HC, NOx) were met to EURO III, but low displacement motorcycles showed a higher incomplete combustion reaction than that of 250 cc motorcycles. Additionally, uncontrolled pollutants (BTEX and 1,3-butadiene) were decreased with increasing a displacement of motorcycles. However, the emission trend of aldehydes was not followed that of those; the formaldehyde ratio increased upto approximately 33%, with increasing a displacement of motorcycles. In the future, it would be used to support the CAPSS as basic data of Korea.

수치해석 및 CFD를 이용한 소형챔버내 복합건축자재의 오염물질 방출량 예측 (A Prediction of Pollutant Emission Rate using Numerical Analysis and CFD in Double-Layered Building Materials)

  • 김창남;이승복;김태연
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2006년도 하계학술발표대회 논문집
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    • pp.277-282
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    • 2006
  • In order to predict the indoor air pollutant, the VOCs emission rate is used through small chamber in the design process. However, the small chamber method has limitations as the convective mass transfer coefficient, the most important factor when predicting VOCs contamination of indoor air, is different between the small chamber result and the measured data in the actual building. Furthermore, the existing studies which analyzed mass transfer coefficient in the small chamber were directed on the small chambers developed at the time and FLEC(Field and Laboratory Emission Cell), thus, are different from the current small chamber which has been changed with improvements. The purpose of this study is to determine the emission rate of pollutant in double-layered building materials through the CFD(Computational of Fluid Dynamics) and Numerical analysis based on the mass transfer coefficient on singled-layered building material by using the current small chamber widely used in Korea. Futhermore, this study used the new convective mass transfer coefficient($h_m'$) which indicates the existing convective mass transfer coefficient($h_m$) including VOC partition coefficient(k). Also, formaldehyde was selected as target pollutant.

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