• Title/Summary/Keyword: formaldehyde emission

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Analytical Methods for Spatial Distribution of Hazardous Air Pollutants (HAPs)

  • Amagai, Takashi
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2010.04a
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    • pp.41-44
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    • 2010
  • Hazardous air pollutants such as benzo[a]pyrene (BaP), benzene, formaldehyde have been concerned about the adverse health effect of long-term exposure. Contour map is useful for finding high-concentration region, emission source, and distributions of HAPs in the ambient air. To make a contour map, we have developed simple analytical method for selected HAPs; polycyclic aromatic hydrocarbons such as BaP, benzene and its derivatives such as toluene and xylene, and aldehydes and ketones. We have applied these methods to investigate air pollution by HAPs in some cities in Japan. The results show that these methods reveal actual emission sources if the PRTR emission report was not submitted.

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Characteristics of Volatile Organic Compounds Emitted in Building Materials and Their Predictions of Time-dependent Variation

  • Pang, Seung Ki;Sohn, Jang Yeul;Lee, Kwang Ho
    • Architectural research
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    • v.7 no.1
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    • pp.19-26
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    • 2005
  • Unlike other countries, Korea uses various kinds of wall-paper as finishing material. Conventional wall-paper consists of paper and vinyl, and petrochemical ink is used for the decoration of the surface. Adhesive is used to paste the wall with the wall-paper, which emit substantial amounts of VOCs and formaldehyde. In this study, VOCs characteristics emitted from specimens made of concrete, mortar, gypsum board and wall-paper were investigated using small chamber method. Moreover, concentration and emission factor of BTEX(Benzene, Toluene, Ethylbenzene, m,p,o-Xylene) and TVOC were investigated, and concentration and emission factor decay were estimated. As a result of the prediction, both time-dependent concentration decay and cumulative concentration can be converted into the logarithmic scale. Furthermore, prediction equations were developed from the experimental results under accurately controlled experimental conditions. Therefore, there may be difference if the estimated equations are directly applied to real buildings. Further research should be done on the generalization of the developed prediction equations.

A Study on the HCHO Grade of Architectural Material's Standard for Greenness with Consideration for Residents' Safety (거주자 안전을 고려한 친환경건축자재의 HCHO 듬급에 관한 고찰)

  • Song, Hyuk;Go, Seong-Seok;Chung, Woo-Yang
    • Journal of the Korean Society of Safety
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    • v.21 no.1 s.73
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    • pp.133-140
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    • 2006
  • According to Tokyo protocol which suggests the prevention of global environmental pollution, Korean government establishes the standard of architectural materials emission consistency with best effort to decrease the environmental pollution. But many current architectural materials which are used for constructing and remodeling buildings are composed of a variety of chemicals. These include stimuli bad for the residents' health and safety and harmful discharged air polluting substances such as volatile organic compounds(TVOCs) and formaldehyde(HCHO) that in tern include a variety of carcinogen substances. These discharged substances are also researched into inducing 'sick building syndrome' which induces headache, dizziness, vomiting and concentration failure among residents. But the standard of architectural materials according to the Korean apartment provision is limited to emission factors: HCHO and TVOCs. So the aim of this study is to present a standard of functional material's emission consistency about TVOCs including glues and paints, and a certification grade for green building by instituting a materials standard for green building which has consideration for the residents' safety.

Distributions of Formaldehyde in Seoul in June, 2005 (2005년 6월의 서울시 대기의 포름알데히드 농도분포 특징)

  • Hwang Jung hoon;Lee Mee hye;Lee Gang woong;Han Jin seock
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.1
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    • pp.63-71
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    • 2006
  • An automated carbonyl measurement system was constructed. Atmospheric carbonyl compounds were extracted onto DNPH containing collection solution while flowing through a glass coil. Each carbonyl species was separated on a HPLC column and quantified by UV absorption detector. Using this system, carbonyl compounds were continuously measured at the campus of Korea University in Seoul, Korea during June, 2005. Sampling resolution was 30 minutes and the detection limit of HCHO was 0.19 ppbv. Also, $\O_{3}$, it's precursors, and meteorological parameters were measured. The maximum, minimum, average, and median concentrations of HCHO during the whole experiment was 35.8 ppbv, 1.4 ppbv, 11.7 ppbv, and 9.3 ppbv respectively. Formaldehyde showed a distinct diurnal variation with a broad maximum around 13 $\sim$ 15, which was 1 $\sim$ 3 hours ahead of an ozone maximum. During a couple of days, however, HCHO concentrations were kept high through the night or increased concomitantly with NOx in the morning. These results imply that HCHO was mainly produced from the photochemical oxidation of VOCs, but local emission sources couldn't be ruled out. The differences between daily maximum and minimum of $O_{3}$ and HCHO were calculated for 11 days of June, when typical diurnal variations were observed for the two species. A strong positive correlation was found between $\Delta O_{3}$ and $\Delta HCHO$ and the average mole ratio of $\Delta HCHO$ to $\Delta O_{3}$ was 2.6. It indicates that formaldehyde played a key role in $\Delta O_{3}$ production as an indicator species in Metropolitan Seoul during June, 2005.

Emission Characteristics of Carbonyl Compounds Depending on Different Finishing Materials in a Wooden House (목조주택 내 마감자재에 따른 카르보닐화합물의 방산특성)

  • Lee, Hee-Young;Park, Sang-Bum;Kang, Young-Suk;Lee, Sang-Min;Park, Jong-Young
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.1
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    • pp.12-18
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    • 2009
  • This study was attempted to investigate indoor air quality of a wooden house. Emission characteristics of carbonyl compounds from indoors whose interiors were finished using ecofriendly materials were detected. From the results of the examination, the carbonyl compounds mostly consisted of formaldehyde, acetaldehyde, and hexaldehyde. Especially, formaldehyde accounted for the largest portion of the compounds at 25.6~30.5%. All the rooms except for R2-2 contained formaldehyde less than criteria of indoor air quality of newly-constructed houses. In addition, all the rooms except for room R1-3, contained acetaldehyde more than the level of $48{\mu}g/m^3$ recommended by Japan's Ministry of Health, Labour and Welfare. As a results of the different wall covering, the room R1-1 of Hwangto emitted relatively higher levels of carbonyl compounds than the room R2-1 of phytoncide. In addition, the room R2-2 of the bamboo charcoal panels emitted more carbonyl compounds than the room R1-2. The living room R1-3 of Japanese cypress (Cryptomeria Japonica) emitted lower levels of carbonyl compounds than other rooms.

A Study on the Emission of VOCs in Parking Lot Floor Coating (주차장 바닥 코팅제의 휘발성유기화합물 배출에 관한 연구)

  • Lee, Seung-Chan;Yoon, Gil-Ho;Park, Yong-Soon;Kil, Bae-Su;Yoon, Hyun-Do
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.4
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    • pp.152-158
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    • 2019
  • Measure the type and content of VOCs for A-company epoxy coating and B-company floor coating(Type A, B), which are used as flooring materials for parking lots. Than the VOCs used gas detectors to measure gas emissions, assuming the worst environment to reduce errors in external environments in the formaldehyde, toluene and xylene harmful to workers and tenants. As a result, A-company epoxy coating has the largest amount of VOCs, and compared to A-company epoxy coating, B-company floor coating of A type represented about 79% less and B type about 96% less. In addition, A-company epoxy coating was also the highest in gas emission measurement for formaldehyde, toluene and xylene using gas detector after 1 hour and 8 hours in closed environment conditions. B-company floor coating A type was less than A-company epoxy coating, which was about 42.3% less measured. And type B satisfied all TWA even in closed environment conditions.

Formulation of Liquid Coating Agent using Bamboo Charcoal and its Characteristics (대나무숯 액상코팅제의 제조 및 특성)

  • Park, Sang-Bum;Lee, Hee-Young;Lee, Sang-Min;Park, Jong-Young
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.6
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    • pp.113-120
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    • 2008
  • This study was performed to develop environmentally-friendly finishing materials for construction. In order to abate formaldehyde and ammonia in indoor air, liquid coating agents for indoor finishing were formulated with bamboo charcoal powder, cypress extracted water, and water-borne acrylic binder. Deodorization rate, far-infrared ray emission rate, anions emission amount, and anti-bacterial effect were investigated. Deodorization rate was increased as cypress extracted water content increased. Deodorization rates of the coating agents were 60.0~98.6% on formaldehyde and 76.7~86.2% on ammonia. No differences on far-infrared ray emission rate, anions emission amount, and anti-bacterial effect were found depending on different formulations. A 91.7% of far-infrared ray emission rate, 77 ea/cc of anions emission amount, and 99.4% of anti-bacterial effect were detected for all formulations. More effective application method of the coating agents revealed was a spray-gun. A $0.66kg/m^2$ of coating agent with a spray-gun and $0.94kg/m^2$ of coating agent with a brush was consumed each.

Evaluation on Emission Characteristics of Trace Hazardous Material from Motorcycle Exhaust by EURO III (EURO III에 의한 이륜자동차의 미량유해물질 배출특성평가)

  • Yoo, Heung-Min;Son, JiHwan;Park, Gyu-Tae;Mun, SunHee;Yun, ChangWan;Kim, JeongSoo;Lee, JongTae
    • Journal of ILASS-Korea
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    • v.20 no.4
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    • pp.207-216
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    • 2015
  • Recently, the researches for air pollutant control technologies have been performing in Korea, while considering an one of the latest main topics as problems on air pollutant control. However, it is difficult to investigate emission amount of air pollutant by passenger cars, because of lack of the domestic information about mobile source; the number of research institutes are less in the whole. Especially, the informations on registered numbers and emissions of motorcycles are less. Thus, in this study, the analysis that is based on experimental results was conducted for finding out source profiling and emission characteristics on motorcycles exhaust. For these experiments, the domestic motorcycles were chosen and evaluated by EURO III standard. From the result, controlled pollutants (CO, HC, NOx) were met to EURO III, but low displacement motorcycles showed a higher incomplete combustion reaction than that of 250 cc motorcycles. Additionally, uncontrolled pollutants (BTEX and 1,3-butadiene) were decreased with increasing a displacement of motorcycles. However, the emission trend of aldehydes was not followed that of those; the formaldehyde ratio increased upto approximately 33%, with increasing a displacement of motorcycles. In the future, it would be used to support the CAPSS as basic data of Korea.

A Prediction of Pollutant Emission Rate using Numerical Analysis and CFD in Double-Layered Building Materials (수치해석 및 CFD를 이용한 소형챔버내 복합건축자재의 오염물질 방출량 예측)

  • Kim, Chang-Nam;Leigh, Seung-Bok;Kim, Tae-Yeon
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.277-282
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    • 2006
  • In order to predict the indoor air pollutant, the VOCs emission rate is used through small chamber in the design process. However, the small chamber method has limitations as the convective mass transfer coefficient, the most important factor when predicting VOCs contamination of indoor air, is different between the small chamber result and the measured data in the actual building. Furthermore, the existing studies which analyzed mass transfer coefficient in the small chamber were directed on the small chambers developed at the time and FLEC(Field and Laboratory Emission Cell), thus, are different from the current small chamber which has been changed with improvements. The purpose of this study is to determine the emission rate of pollutant in double-layered building materials through the CFD(Computational of Fluid Dynamics) and Numerical analysis based on the mass transfer coefficient on singled-layered building material by using the current small chamber widely used in Korea. Futhermore, this study used the new convective mass transfer coefficient($h_m'$) which indicates the existing convective mass transfer coefficient($h_m$) including VOC partition coefficient(k). Also, formaldehyde was selected as target pollutant.

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