• 대한화학회지
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• 제58권3호
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• pp.283-288
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• 2014

A column solid phase extraction procedure based on modified polyurethane foam (PUF) by a newly synthesized Schiff base ionophore, named 2,2'-{iminobis[propane-3,1-diylnitrilo(1E)prop-1-yl-1-ylidene]}diphenol, was developed for preconcentration step of trace amounts determination of copper ions in water samples by atomic absorption flame spectroscopy. The influence of parameters on the adsorption process such as sample pH, amount of modified PUF packed in the column, type and volume of stripping reagent and its flow rate were investigated and optimized. Under optimum experimental conditions, the calibration graph was linear in a relatively wide range ($0.005-210{\mu}g/ml$) with a limit of detection $0.002{\mu}g/ml$ of copper. The proposed method allows achieving to a concentration factor of >133. The capacity of a column (1.6 cm i.d.) packed by 6 g of PUF modified by 12 mg of the Schiff base was found to be $247.7({\pm}2.1){\mu}g$ of copper. It was found that the adsorption process was highly selective towards copper ions with respect to some associated metal ions. The presented procedure was successfully applied for determination of copper in some water samples.

• 펄프종이기술
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• 제48권2호
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• pp.56-60
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• 2016

Neutral or alkaline papermaking provides many advantages in paper strength and processing conditions. It also provides the opportunity of using calcium carbonate fillers in papermaking. These diverse advantages have made almost all paper machines of printing and writing papers run under neutral and alkaline conditions. On the other hand, linerboard machines, which use recycled papers as a raw material, are running under acid conditions using a rosin sizing system. Because the recycled raw materials used by the linerboard industry contain significant amounts of alkaline papers, the linerboard industry has an interest in the possibility of using the neutral or alkaline papermaking opportunity. In this study, the compatibility of the recycled linerboards under neutral or alkaline papermaking conditions was examined by recycling them under various pH conditions. The sizing degree of the papers recycled under neutral or alkaline was significantly lower than that of acid formed papers indicating that during the neutral or alkaline recycling process the rosin sized papers lost their sizing efficiency. Recycling of acid formed linerboards under neutral or alkaline conditions increased the amount of foam, and the foam contained substantial amount of solid materials derived from the acid sizing systems. Use of cationic polyelectrolytes including PEI and poly-DADMAC improved the sizing degree of the recycled papers under neutral and alkaline conditions. PEI decreased the foam generation as well while poly-DADMAC did not show any reducing effect of the foam. These results suggest that PEI forms coordinate bonds with rosin acid and precipitate them onto the surface of recycled fibers, while the reaction products between poly-DADMAC and rosin acid ions still remain water soluble under neutral or alkaline conditions.

• 기술사
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• 제17권3호
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• pp.22-31
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• 1984

Sardine ant mackerel so called dark muscled fish have been underutilized due to the disadvantages in bloody meat color, high content of fat, and postmortem instability of protein. Recent efforts were made to overcome these defects and develope new types of product such as texturized protein concentrates and dark muscle eliminated minced fish. Approach of this study is based on the rapicl dehydration of foamed fish-starch paste by dielectric heating. In process comminuted sardine meat was washed more than three times by soaking and decanting in chilled water and finally centrifuged. The meat was ground in a stone mortar added with adequate amounts of salt, foaming agent, and other ingredients for aid to elasticity and foam stability. The ground meat paste was extruded in finger shape and heated in a microwave oven to give foamed, expanded, and porous solid structure by dehydration. Dielectric constant ($\varepsilon$′) and dielectric loss ($\varepsilon$") vcalues of sardine meat paste were influenced by wavelength and moisture level. Those values at 100KHz and 15MHz were ranged 2.25∼9.86 ; 2.22∼4.18 for $\varepsilon$′ and 0.24∼19.24 ; 0.16∼1.25 for $\varepsilon$", respectively, at the moisture levels of 4.2∼13.8％. For a formula for fish-starch paste preparation, addition of 20∼30% starch (potato starch) to the weight of fish meat, 2∼4% salt, and 5∼10% soybean protein was adequate to yield 4∼5 folds of expansion in volume when heated. Addition of egg yolk was of benefit to micronize foam size and better crispness. In order to provide better foaming and dehydration, addition of 0.2∼0.5% sodium bicarbonate foaming agent, was proper to result in foam size of 0.5∼0.7mm and foam density of 200∼400/$\textrm{cm}^2$ which gave a good crispness.

• 한국도로학회논문집
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• 제10권4호
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• pp.19-29
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• 2008

최근에 $135^{\circ}C^{\circ}C$ 이하의 온도에서 생산되는 중온형 아스팔트 혼합물의 새로운 생산 기술이 전세계적으로 개발되고 있다. 본 연구에서는 가열 아스팔트보다 낮은 온도에서 아스팔트를 효과적으로 골재에 분산시켜 코팅할 수 있는 폼드 아스팔트 기술을 이용하여 중온형 아스팔트 혼합물을 생산하였으며, 최근 개발된 새로운 Simple Performance Testing 장비를 이용하여 다양한 온도와 하중조건 하에서 중온형 폼드 아스팔트 혼합물의 공용성 특성을 평가하였다. 중온형 폼드 아스팔트 혼합물은 FG 64-22의 아스팔트를 거품상태로 만들어 중온으로 가열된 골재에 뿌려서 제조하였으며, 중온형 아스팔트 혼합물은 중온의 골재에 FG 64-22의 아스팔트를 액상 상태로 첨가하여 제조하였다. 중온형 폼드 아스팔트 혼합물은 중온형 아스팔트 혼합물보다 높은 동탄성계수와 Flow Number를 나타내었다. 따라서, $100^{\circ}C$로 가열된 골재를 사용하여 생산된 중온형 폼드 아스팔트 혼합물은 중온형 아스팔트 혼합물에 비하여 피로균열 및 소성변형 저항에 우수한 것으로 평가되었다.

• 한국세라믹학회지
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• 제53권6호
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• pp.604-609
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• 2016

This study reports on wet-foam stability with respect to porous ceramics from a particle-stabilized colloidal suspension that is achieved through the addition of polymethyl methacrylate (PMMA) using a wet process. To stabilize the wet foam, an initial colloidal suspension of $Al_2O_3$ was partially hydrophobized by the surfactant propyl gallate (2 wt.%) and $SiO_2$ was added as a stabilizer. The influence of the PMMA content on the bubble size, pore size, and pore distribution in terms of the contact angle, surface tension, adsorption free energy, and Laplace pressure are described in this paper. The results show a wet-foam stability of more than 83%, which corresponds to a particle free energy of $2.7{\times}10^{-12}J$ and a pressure difference of 61.1 mPa for colloidal particles with 20 wt.% of PMMA beads. It was possible to control the uniform distribution of the open/closed pores by increasing the PMMA content and by adding thick struts, leading to the achievement of a higher-stability wet foam for use in porous ceramics.

• 대한기계학회논문집B
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• 제41권2호
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• pp.135-143
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• 2017

밀폐된 공간내의 공조 문제에 있어서 실내의 기류 및 온도 특성을 전산유체역학기법을 통해 쉽게 예측할 수 있는 맞춤형 시뮬레이터를 개발하였다. 본 시스템에서는 사용자가 직접 해석 대상 평면도를 입력하고 적절한 경계조건을 설정하면 전산유동해석을 위한 계산 격자가 자동으로 생성되고 유한체적법으로 이산화된 공개 전산유체코드를 통해 주어진 공간내의 열유체 해석 결과를 얻게 된다. 초기 실내 평면도면 입력부터 경계조건 설정, 전산유동해석 결과까지 하나의 사용자 인터페이스 상에서 작업할 수 있으며 격자생성과 유동해석 알고리듬은 공개 라이브러리를 사용하여 구현하였다. 간단한 실험 데이터를 통해 해석결과를 검증하였으며 실제 실내 공조에 대한 기류해석을 통해 유동의 경향성을 파악할 수 있는 맞춤형 유동전산모사 시스템을 구성하였다.

• 대한조선학회논문집
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• 제55권6호
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• pp.490-496
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• 2018

The consistency of the initially designed waves in the domain is essential for accurate calculation of the added resistance in waves through CFD. In particular, unwanted reflected waves at domain boundaries can cause incorrect numerical solutions due to the superposition with initially designed waves. Euler Overlay Method(EOM) is one of the methods for reducing wave reflections by adding an additional source term to momentum and phase conservation equations, respectively. In this study, we apply the Euler Overlay Method(EOM) to the open-source CFD library, OpenFOAM(R), to simulate the accurate free-surface waves in the domain and the parametric study is performed for efficient implementation of Euler Overlay Method(EOM). Considering that the damping efficiency depends on the selection of the overlay parameter in the added source terms, the size of overlay zone and the wave steepness, the influences of these factors are tested through the wave elevation measured at constant time intervals in the 2D numerical wave tank. Through this process, guidelines for selection of optimal overlay parameter and overlay zone size that can be applied according to the scaling law are finally presented.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2007년도 춘계학술대회 논문집
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• pp.423-424
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• 2007

• 한국정밀공학회지
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• 제22권10호
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• pp.26-30
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• 2005

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2015년도 추계학술논문요약집
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• pp.339-340
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• 2015