• Title/Summary/Keyword: foam process

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Effect of Cell Size on the High Temperature Oxidation Properties of Fe-Cr-Al Powder Porous Metal Manufactured by Electro-spray Process (정전 분무 공정으로 제조된 Fe-Cr-Al 분말 다공체 금속의 고온 산화 특성에 미치는 기공 크기의 영향)

  • Oh, Jae-Sung;Kong, Young-Min;Kim, Byoung-Kee;Lee, Kee-Ahn
    • Journal of Powder Materials
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    • v.21 no.1
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    • pp.55-61
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    • 2014
  • Fe-Cr-Al powder porous metal was manufactured by using new electro-spray process. First, ultra-fine fecralloy powders were produced by using the submerged electric wire explosion process. Evenly distributed colloid (0.05~0.5% powders) was dispersed on Polyurethane foam through the electro-spray process. And then degreasing and sintering processes were conduced. In order to examine the effect of cell size ($200{\mu}m$, $450{\mu}m$, $500{\mu}m$) in process, pre-samples were sintered for two hours at temperature of $1450^{\circ}C$, in $H_2$ atmospheres. A 24-hour thermo gravimetric analysis test was conducted at $1000^{\circ}C$ in a 79% $N_2$ + 21% $O_2$ to investigate the high temperature oxidation behavior of powder porous metal. The results of the high temperature oxidation tests showed that oxidation resistance increased with increasing cell size. In the $200{\mu}m$ porous metal with a thinner strut and larger specific surface area, the depletion of the stabilizing elements such as Al and Cr occurred more quickly during the high-temperature oxidation compared with the 450, $500{\mu}m$ porous metals.

Study on Reaction Behavior of Rigid Polyurethane Foam with Various Types and Contents of Gelling Catalysts (젤화 촉매의 종류 및 함량에 따른 경질 폴리우레탄 폼의 반응거동에 관한 연구)

  • Eom, Se Yeon;Lee, Hyeong Il;Lee, Kee Yoon
    • Polymer(Korea)
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    • v.39 no.2
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    • pp.210-218
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    • 2015
  • The reaction behavior of rigid polyurethane foams were studied on the effects of gelling catalysts of amine type, such as; dimethylcyclohexyl amine (DMCHA) and of potassium type, such as; potassium octoate (PO). Rigid polyurethane foams were provided with polymeric 4,4'-diphenylmethane diisocyanate, polyester polyol, silicone surfactant, blowing agent and a few gelling catalysts. As the contents of catalyst, DMCHA increased from 0 to 2.0 g, the reaction time decreased from ca. 330 to ca. 35 sec and due to the exothermic reaction, the maximum temperature increased from ca. 217 to ca. $234^{\circ}C$, respectively. As the contents of PO increased from 0 to 2.5 g, the reaction time decreased from ca. 79 to ca. 38 sec and the maximum temperature increased from ca. 182 to ca. $271^{\circ}C$, respectively. The kinetic parameters were calculated and the conversions were based on the temperature rising method of adiabatic process. As the content of DMCHA increased, the rate constant $k_0$ increased. But in the case of PO catalyst, $k_0$ did hardly depend upon its amount, and showed us similar reaction rate constants.

Adhesion Properties of UV-curable Acrylic PSA Tape for Automotive Sidemolding and Emblem (자동차용 사이드 몰딩과 엠블럼 적용을 위한 UV 경화형 아크릴 점착 테이프의 점착물성)

  • Park, Ji-Won;Lee, Seung-Woo;Kim, Hyun-Joong;Won, Dong-Bok;Kim, Dong-Bok;Lee, Kang-Shin;Woo, Hang-Soo;Kim, Eun-Ah
    • Journal of Adhesion and Interface
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    • v.12 no.3
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    • pp.81-87
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    • 2011
  • In this study, UV curing and crosslinking process was introduced for synthesis of acrylic foam tape that can be applied to the the automotive assembly process. Polymerized adhesive are laminated to baseform and varying the thickness of specimens were prepared. To measure basic mechanical properties, stainless steel was used. And in the test peel, dynamic shear and t-block were used. The acrylform adhesive show better results compare with typical adhesive and the properties depand on external factors - thick, wetting time -. To analysis functions of acrylic foam adhesive used to automobile production, evaluate the adhesive properties on the various plastic substrate. In PP and PE are categorized low surface energy materials, their properties have not been expressed. But dynamic shear tests show that some properties could be expressed by the difference break mechanism.

Dehydration of Foamed Fish (Sardine)-Starch Paste by Microwave Heating 1. Formulation and Processing Conditions (어육(정어러) 발포건조제품가공에 관한 연구 1. 원료$\cdot$첨가물의 배합 및 가공조건)

  • LEE Kang-Ho;LEE Byeong-Ho;You Byeong-Jin;SONG Dong-Suck;SUH Jae-Soo;JEA YOi-Guan;RYU Hong-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.15 no.4
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    • pp.283-290
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    • 1982
  • Sardine and mackerel so called dark muscled fish have been underutilized due to the disadvantages in bloody meat color, high content of fat, and postmortem instability of protein. Recent efforts were made to overcome these defects and develope new types of product such as texturized protein concentrates and dark muscle eliminated minced fish. Approach of this study is based on the rapid dehydration of foamed fish-starch paste by dielectric heating. In process comminuted sardine meat was washed more than three times by soaking and decanting in chilled water and finally centrifuged. The meat was ground in a stone mortar added Ivith adequate amounts of salt, foaming agent, and other ingredients for aid to elasticity and foam stability. The ground meat paste was extruded in finger shape and heated in a microwave oven to give foamed, expanded, and porous solid structure by dehydration. Dielectric onstant $(\varepsilon')$ and dielect.ic loss $(\varepsilon")$ values of sardine meat paste were influenced by wavelength and moisture level. Those values at 100 KHz and 15 MHz were ranged 2.25-9.86; 2.22-4,18 for E' and 0.24-19.24; 0.16-1.20 for E", respectively, at the moisture levels of $4.2-13.8\%$. For a formula for fish-starch paste preparation, addition of $20-30\%$ starch (potato starch) to the weight of fish meat, $2-4\%$ salt, and $5-10\%$ soybean protein was adequate to yield 4-5 folds of expansion in volume when heated. Addition of e99 yolk was of benefit to micronize foam size and better crispness. In order to provide better foaming and dehydration, addition of $0.2-0.5\%$sodium bicarbonate, foaming agent, was proper to result in foam size of 0.5-0.7 mm and foam density of $200-400\;/cm^2$ which gave a good crispness. Heating time was depended upon the moisture level of fish-starch paste. For a finger shaped paste (1.0cm. $D\times10cm.L$) heating for 150-200 sec. in a microwave oven (700W. 2.45GHz) was sufficient to generate foams, expand, and solidify the porous structure of fish-starch paste. When the moisture content was above $55\%$ browning and scorching was deepened due to over-expansion and over-heating whereas the crispness was hardened by insufficient expansion at lower moisture content. In quality evaluation of the product, chemical composition of $30\%$ starch and $3\%$ salt added product was moisture $8.8\%$, lipid $2.4\%$, carbohydrate $46.7\%$, protein $36.1\%$, and ash $6.0\%$. Eleven membered panel test evaluated that fish-starch paste was acceptable in color, crisp-ness, taste, except a trace of fishy odour which could be masked by the addition of spice extracts.

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A Study on Life-Cycle Environmental Impact of Synthetic Resin Formwork (합성수지 거푸집의 전과정 환경영향평가에 관한 연구)

  • Nam, Kyung-Yong;Yang, Keun-Hyeok;Lee, Young-Do
    • Journal of the Korea Institute of Building Construction
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    • v.20 no.3
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    • pp.245-252
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    • 2020
  • Synthetic resin formwork is made of lightweight high-density polyethylene(HDPE). This study used a process flow chart that satisfies the system boundary (such as Cradle-to- Product shipmen ) required by ISO FDIS 13352 to evaluate the entire process of synthetic resin foam using. The entire life cycle inventory (LCI) database calculated from input energy sources, materials used, transportation methods, and manufacturing processes at the system boundary was analyzed. Based on the environmental impact assessment index methodology of the Ministry of Environment from the LCI data analysis of synthetic resin formwork, the environmental impact assessment was carried out through classification, normalization, characterization, and weighting process. The experimental results are as follows the amount of CO2 (carbon) emission considering the number of conversions was about 32% lower than that of the Euroform. This shows that the use of synthetic resin formwork reduces material production by half compared to Euroform and reduces CO2 (carbon) emissions.

An Experimental Study on the Fire Risk at Welding·Cutting Process (용접·절단 작업시 화재위험성에 관한 실험적 연구)

  • Lee, Sung-Ryong
    • Fire Science and Engineering
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    • v.26 no.3
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    • pp.60-66
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    • 2012
  • In this study, it was evaluated the fire risk during welding cutting tasks. Welding-cutting machines are representatively used at construction sites. Inverter AC/DC TIG welding macnine and inverter air plasma cutting machine were used in experiments. Temperature of spreaded cinders was measured using a thermal camera. Cinder sizes and spread range were measured according to the height and input current. It was also evaluated the fire risk during welding-cutting process, when flammable materials were located around the working area. There were used hay, dust fence, urethane foam, vinyl, paper and oil as flammable materials. Temperature of spreaded cinders was reached at about $450^{\circ}C$. Cinders were spread approximately 4.7 m, when a worker carried out cutting process at 2.5 m height. The possibility of a fire is very high, when flammable materials were located around the working area.

The Comparison on Treatment Method of Liquid Radioactive Waste in Yonggwang #3&4 and #5&6 (영광 3&4와 5&6호기에서 액체 방사성폐기물 처리방법의 비교)

  • Yeom, Yu-Seon;Kim, Soong-Pyung;Lee, Seung-Jin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.3
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    • pp.219-230
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    • 2004
  • Most of the low-level liquid radioactive wastes generated from PWR plants are classified into high or low total suspended solid(HTDS or LTDS), and into radiochemical and radioactive laundry waste. Although the evaporation process has a high decontami- nation ability, it has several problems such as corrosion, foam, and congestion. A new liquid waste disposal process using the ion-exchange demineralizer(IED), instead of the current evaporation process, has been introduced into the Yonggwang NPP #5 and 6. These two methods have been compared to understand the differences in this study. Aspects compared here were the released radioactivity amount of the liquid radioactive wastes, the dose of off-site residents, the decontamination factor, and the amount of the solid radioactive wastes. The IED system is designed to discharge higher radioactivity about 20% than the evaporating system, and the actual radioactivity released from the evaporating and IED system were 0.473mCi and 1.098mCi, respectively. The radioactivity released from the IED was 2.32 times higher than that of the evaporating system. The dose of off-site residents was $2.97{\times}10^{-6}$mSv for the evaporating system, and $6.47{\times}10^{-6}$mSv for IED. The decontamination factor(DF) of the evaporator is, in most cases, far lower than the lower limits of detection(LLD) with the Ge-Li detector. Due to the low concentration of the liquid wastes collected from the liquid waste system, the decontamination factor of IED is very low. Since there is not enough data on the amount of solid radioactive wastes generated by the evaporation system, the comparison on these two systems has been conducted on the basis of the design, and the comparison result was that the evaporating system generated more wastes about 40% than IED.

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Mycolic Acid-Containing Actinomycetes Associated with Activated Sludge Foam

  • Seong, Chi-Nam;Kim, Young-Sook;Baik, Ken-Shik;Lee, Soon-Dong;Hah, Yung-Chil;Kim, Seung-Bum;Goodfellow, Michael
    • Journal of Microbiology
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    • v.37 no.2
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    • pp.66-72
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    • 1999
  • Mycolic acid-containing actinomycetes associated with extensive foaming in the aeration basin of the activated sludge process were isolated and analyzed by phenotypical, chemotaxonomical and phylogenetic methods. Whole cell sugar patterns of two isolates were pattern A. The nearly complete sequences of the 16S rRNA genes (rDNAs) of the isolates were determined and compared by using several tree-making algorithms. With polyphasic methods, strain SCNU1 was identified as Gordona sputi, and strain SCNU5 assigned to the genus Tsukamurella. The presence of opportunistic pathogens of chronic lung infections within foams can cause public health problems and render waste-treatment processes inefficient.

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Synthesis of Carbon Nanofibers Based on Resol Type Phenol Resin and Fe(III) Catalysts

  • Hyun, Yu-Ra;Kim, Hae-Sik;Lee, Chang-Seop
    • Bulletin of the Korean Chemical Society
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    • v.33 no.10
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    • pp.3177-3183
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    • 2012
  • The carbon nanofibers (CNFs) used in this study were synthesized with an iron catalyst and ethylene as a carbon source. A concentration of 30 wt % iron(III) acetylacetonate was dissolved in resol type phenol resin and polyurethane foam was put into the solution. The sample was calendered after being cured at $80^{\circ}C$ in air for 24 h. Stabilization and carbonization of the resol type phenol resin and reduction of the $Fe^{3+}$ were completed in a high-temperature furnace by the following steps: 1) heating to $600^{\circ}C$ at a rate of $10^{\circ}C/min$ with a mixture of $H_2/N_2$ for 4 h to reduce the $Fe^{3+}$ to Fe; 2) heating to $1000^{\circ}C$ in $N_2$ at a rate $10^{\circ}C/min$ for 30 minutes for pyrolysis; 3) synthesizing CNFs in a mixture of 20.1% ethylene and $H_2/N_2$ at $700^{\circ}C$ for 2 h using a CVD process. Finally, the structural characterization of the CNFs was performed by scanning electron microscopy and a synthesis analysis was carried out using energy dispersive spectroscopy and X-ray photoelectron spectroscopy. Specific surface area analysis of the CNFs was also performed by $N_2$-sorption.

Recent Emulsion Technology in Cosmetics (화장품용 유화 제조기술 최근동향)

  • Hwang, So-Ra;Nam, Jin-Oh;Lee, Byung-Jin;Song, Woo-Ho;Lee, Chang-Soo
    • KSBB Journal
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    • v.27 no.4
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    • pp.207-214
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    • 2012
  • Emulsions are mixture of immiscible liquids in which one is dispersed in all over the other. They have been applied to many applications including cosmetics, foods, drug delivery system (DDS), fine chemicals, and chemical separations. Especially, emulsion technology is one of the most useful technique to formulate cosmetics such as eye cream, foundation, and foam cleansing. In general, the emulsions can be generated by mechanical agitation of two immiscible fluids. However, the emulsions obtained by conventional method have limited in stability, monodispersity, and complicate process. We describe here preparation techniques of representative cosmetic emulsions such as liposome, liquid crystal emulsion, nanoemulsion, multiple emulsion, and pickering emulsion. Furthermore, various factors which can control the physical properties of each cosmetic emulsions are briefly discussed.