• Journal of the Korean Chemical Society
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• v.58 no.3
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• pp.283-288
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• 2014

A column solid phase extraction procedure based on modified polyurethane foam (PUF) by a newly synthesized Schiff base ionophore, named 2,2'-{iminobis[propane-3,1-diylnitrilo(1E)prop-1-yl-1-ylidene]}diphenol, was developed for preconcentration step of trace amounts determination of copper ions in water samples by atomic absorption flame spectroscopy. The influence of parameters on the adsorption process such as sample pH, amount of modified PUF packed in the column, type and volume of stripping reagent and its flow rate were investigated and optimized. Under optimum experimental conditions, the calibration graph was linear in a relatively wide range ($0.005-210{\mu}g/ml$) with a limit of detection $0.002{\mu}g/ml$ of copper. The proposed method allows achieving to a concentration factor of >133. The capacity of a column (1.6 cm i.d.) packed by 6 g of PUF modified by 12 mg of the Schiff base was found to be $247.7({\pm}2.1){\mu}g$ of copper. It was found that the adsorption process was highly selective towards copper ions with respect to some associated metal ions. The presented procedure was successfully applied for determination of copper in some water samples.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.48 no.2
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• pp.56-60
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• 2016

Neutral or alkaline papermaking provides many advantages in paper strength and processing conditions. It also provides the opportunity of using calcium carbonate fillers in papermaking. These diverse advantages have made almost all paper machines of printing and writing papers run under neutral and alkaline conditions. On the other hand, linerboard machines, which use recycled papers as a raw material, are running under acid conditions using a rosin sizing system. Because the recycled raw materials used by the linerboard industry contain significant amounts of alkaline papers, the linerboard industry has an interest in the possibility of using the neutral or alkaline papermaking opportunity. In this study, the compatibility of the recycled linerboards under neutral or alkaline papermaking conditions was examined by recycling them under various pH conditions. The sizing degree of the papers recycled under neutral or alkaline was significantly lower than that of acid formed papers indicating that during the neutral or alkaline recycling process the rosin sized papers lost their sizing efficiency. Recycling of acid formed linerboards under neutral or alkaline conditions increased the amount of foam, and the foam contained substantial amount of solid materials derived from the acid sizing systems. Use of cationic polyelectrolytes including PEI and poly-DADMAC improved the sizing degree of the recycled papers under neutral and alkaline conditions. PEI decreased the foam generation as well while poly-DADMAC did not show any reducing effect of the foam. These results suggest that PEI forms coordinate bonds with rosin acid and precipitate them onto the surface of recycled fibers, while the reaction products between poly-DADMAC and rosin acid ions still remain water soluble under neutral or alkaline conditions.

• Journal of the Korean Professional Engineers Association
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• v.17 no.3
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• pp.22-31
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• 1984

Sardine ant mackerel so called dark muscled fish have been underutilized due to the disadvantages in bloody meat color, high content of fat, and postmortem instability of protein. Recent efforts were made to overcome these defects and develope new types of product such as texturized protein concentrates and dark muscle eliminated minced fish. Approach of this study is based on the rapicl dehydration of foamed fish-starch paste by dielectric heating. In process comminuted sardine meat was washed more than three times by soaking and decanting in chilled water and finally centrifuged. The meat was ground in a stone mortar added with adequate amounts of salt, foaming agent, and other ingredients for aid to elasticity and foam stability. The ground meat paste was extruded in finger shape and heated in a microwave oven to give foamed, expanded, and porous solid structure by dehydration. Dielectric constant ($\varepsilon$′) and dielectric loss ($\varepsilon$") vcalues of sardine meat paste were influenced by wavelength and moisture level. Those values at 100KHz and 15MHz were ranged 2.25∼9.86 ; 2.22∼4.18 for $\varepsilon$′ and 0.24∼19.24 ; 0.16∼1.25 for $\varepsilon$", respectively, at the moisture levels of 4.2∼13.8％. For a formula for fish-starch paste preparation, addition of 20∼30% starch (potato starch) to the weight of fish meat, 2∼4% salt, and 5∼10% soybean protein was adequate to yield 4∼5 folds of expansion in volume when heated. Addition of egg yolk was of benefit to micronize foam size and better crispness. In order to provide better foaming and dehydration, addition of 0.2∼0.5% sodium bicarbonate foaming agent, was proper to result in foam size of 0.5∼0.7mm and foam density of 200∼400/$\textrm{cm}^2$ which gave a good crispness.

• International Journal of Highway Engineering
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• v.10 no.4
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• pp.19-29
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• 2008

To produce asphalt mixtures at temperature significantly below $135^{\circ}C$, called "Warm Mix Asphalt (WMA)", new technologies are currently being developed worldwide. To produce WMA mixtures in this research, foaming technology is adopted to effectively disperse asphalt binder at lower temperature than hot mix asphalt (HMA) in the field. The main objectives of this study are to develop WMA process using foaming technology (WMA-foam) and evaluate its performance characteristics under various temperatures and loading conditions. WMA-foam mixtures were produced by injecting PO 64-22 foamed asphalt into warm aggregates whereas WMA mixtures were produced by adding PO 64-22 asphalt (without foaming) in the warm aggregates. Both dynamic modulus and flow number of WMA-foam mixtures were higher than those of WMA mixtures. Based on the limited dynamic modulus and repeated load test results, it is concluded that the WMA-foam mixtures using warm aggregates at $100^{\circ}C$ are more resistant to fatigue cracking and rutting than WMA mixtures.

• Journal of the Korean Ceramic Society
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• v.53 no.6
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• pp.604-609
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• 2016

This study reports on wet-foam stability with respect to porous ceramics from a particle-stabilized colloidal suspension that is achieved through the addition of polymethyl methacrylate (PMMA) using a wet process. To stabilize the wet foam, an initial colloidal suspension of $Al_2O_3$ was partially hydrophobized by the surfactant propyl gallate (2 wt.%) and $SiO_2$ was added as a stabilizer. The influence of the PMMA content on the bubble size, pore size, and pore distribution in terms of the contact angle, surface tension, adsorption free energy, and Laplace pressure are described in this paper. The results show a wet-foam stability of more than 83%, which corresponds to a particle free energy of $2.7{\times}10^{-12}J$ and a pressure difference of 61.1 mPa for colloidal particles with 20 wt.% of PMMA beads. It was possible to control the uniform distribution of the open/closed pores by increasing the PMMA content and by adding thick struts, leading to the achievement of a higher-stability wet foam for use in porous ceramics.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.41 no.2
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• pp.135-143
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• 2017

A customized CFD simulator to perform thermo-fluid dynamic simulations of an HVAC for an indoor space is presented. This simulation system has been developed for engineers studying architectural engineering, as the HVAC mechanical systems used in housings and buildings. Hence, all functions and options are so designed to be suitable that they are suitable for non-CFD experts as well as CFD engineers. A Computational mesh is generated by open-source libraries, FEMM (Finite Element Method Magnetics), and OpenFOAM. Once the boundary conditions are set, the fluid dynamic calculations are performed using the OpenFOAM solver. Numerical results are validated by comparing them with the experimental data for a simple indoor air flow case. In this paper, an entirely new calculation process is introduced, and the flow simulation results for a sample office room are also discussed.

• Journal of the Society of Naval Architects of Korea
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• v.55 no.6
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• pp.490-496
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• 2018

The consistency of the initially designed waves in the domain is essential for accurate calculation of the added resistance in waves through CFD. In particular, unwanted reflected waves at domain boundaries can cause incorrect numerical solutions due to the superposition with initially designed waves. Euler Overlay Method(EOM) is one of the methods for reducing wave reflections by adding an additional source term to momentum and phase conservation equations, respectively. In this study, we apply the Euler Overlay Method(EOM) to the open-source CFD library, OpenFOAM(R), to simulate the accurate free-surface waves in the domain and the parametric study is performed for efficient implementation of Euler Overlay Method(EOM). Considering that the damping efficiency depends on the selection of the overlay parameter in the added source terms, the size of overlay zone and the wave steepness, the influences of these factors are tested through the wave elevation measured at constant time intervals in the 2D numerical wave tank. Through this process, guidelines for selection of optimal overlay parameter and overlay zone size that can be applied according to the scaling law are finally presented.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2007.06a
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• pp.423-424
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• 2007

• Journal of the Korean Society for Precision Engineering
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• v.22 no.10 s.175
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• pp.26-30
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• 2005

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2015.10a
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• pp.339-340
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• 2015