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Development of an IoT Smart Sensor for Detecting Gaseous Materials (사물인터넷 기술을 이용한 가스상 물질 측정용 스마트센서 개발과 향후과제)

  • Kim, Wook;Kim, Yongkyo;You, Yunsun;Jung, Kihyo;Choi, Won-Jun;Lee, Wanhyung;Kang, Seong-Kyu;Ham, Seunghon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.32 no.1
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    • pp.78-88
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    • 2022
  • Objectives: To develop the smart sensor to protect worker's health from chemical exposure by adopting ICT (Information and Communications Technology) technologies. Methods: To develope real-time chemical exposure monitoring system, IoT (Internet of Things) sensor technology and regulations were reviewed. We developed and produced smart sensor. A smart sensor is a system consisting of a sensor unit, a communication unit, and a platform. To verify the performance of smart sensors, each sensor has been certified by the Korea Laboratory Accreditation Scheme (KOLAS). Results: Chemicals (TVOC; Total Volatile Organic Compounds, Cl2: Chlorine, HF: Hydrogen fluoride and HCN: Hydrogen cyanide) were selected according to a priority logic (KOSHA Alert, acute poisoning statistics, literature review). Notifications were set according to OEL (occupational exposure limit). Sensors were selected based on OEL and the capabilities of the sensors. Communication is designed to use LTE (Long Term Evolution) and Wi-Fi at the same time for convenience. Electronic platform were applied to build this monitoring system. Conclusions: Real-time monitoring system for OEL of hazardous chemicals in workplace was developed. Smart sensor can detect chemicals to complement monitoring of traditional workplace environmental monitoring such as short term and peak exposure. Further research is needed to expand the scope of application, improve reliability, and systematically application.

Composite-Based Material and Process Technology Review for Improving Performance of Piezoelectric Energy Harvester (압전 에너지 수확기의 성능 향상을 위한 복합재료 기반 소재 및 공정 기술 검토)

  • Kim, Geon Su;Jang, Ji-un;Kim, Seong Yun
    • Composites Research
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    • v.34 no.6
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    • pp.357-372
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    • 2021
  • The energy harvesting device is known to be promising as an alternative to solve the resource shortage caused by the depletion of petroleum resources. In order to overcome the limitations (environmental pollution and low mechanical properties) of piezoelectric elements capable of converting mechanical motion into electrical energy, many studies have been conducted on a polymer matrix-based composite piezoelectric energy harvesting device. In this paper, the output performance and related applications of the reported piezoelectric composites are reviewed based on the applied materials and processes. As for the piezoelectric fillers, zinc oxide, which is advantageous in terms of eco-friendliness, biocompatibility, and flexibility, as well as ceramic fillers based on lead zirconate titanate and barium titanate, were reviewed. The polymer matrix was classified into piezoelectric polymers composed of polyvinylidene fluoride and copolymers, and flexible polymers based on epoxy and polydimethylsiloxane, to discuss piezoelectric synergy of composite materials and improvement of piezoelectric output by high external force application, respectively. In addition, the effect of improving the conductivity or the mechanical properties of composite material by the application of a metal or carbon-based secondary filler on the output performance of the piezoelectric harvesting device was explained in terms of the structure of the composite material. Composite material-based piezoelectric harvesting devices, which can be applied to small electronic devices, smart sensors, and medicine with improved performance, can provide potential insights as a power source for wireless electronic devices expected to be encountered in future daily life.

Prediction of Chemical Acceleration Durability Time of Polymer Membrane in Polymer Electrolyte Membrane Fuel Cells (고분자 전해질 연료전지에서 고분자막의 화학적 가속 내구 시간 예측)

  • Sohyeong Oh;Donggeun Yoo;Sunggi Jung;Jihong Jeong;Kwonpil Park
    • Korean Chemical Engineering Research
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    • v.61 no.1
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    • pp.26-31
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    • 2023
  • For durability improvement of polymer electrolyte membrane fuel cell (PEMFC) polymer membrane, accelerated durability evaluation methods that can evaluate durability in a short time have been researched and developed. However, the lifespan of fuel cells for large commercial vehicles such as trucks and buses is more than three times that of passenger cars, and the chemical accelerated stress test (AST) time is also longer, reaching 1,500 hours or more. Therefore, in this study, as a method to evaluate the chemical durability of a membrane within a short time, it was examined whether the durability could be predicted by the pristine membrane characteristics. Hydrogen crossover current density (HCCD) and short resistance (SR) were estimated as initial characteristics, and AST time was predicted through the Fenton experiment, which was possible as an out-of-cell experiment for 3 hours. As the HCCD and fluoride ion emission concentration increased, the AST time tended to be linearly shortened, but there was a deviation (R2 ≒0.65). When the SR decreased, the AST time showed a linear increase, and the accuracy was high (R2 =0.93), so the AST time could be predicted with the initial SR of the membrane.

Defect analysis of calcium fluoride single crystal substrates with (100) and (111) orientation ((100) 및 (111) 배향을 갖는 CaF2 단결정 기판의 결함 분석)

  • Ye-Jin Choi;Min-Gyu Kang;Gi-Uk Lee;Mi-Seon Park;Kwang-Hee Jung;Hea-Kyun Jung;Doo-Gun Kim;Won-Jae Lee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.34 no.1
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    • pp.8-15
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    • 2024
  • The CaF2 single crystal has notable characteristics such as a large band gap (12 eV), excellent transparency over a wide wavelength range, low refractive index and dispersion. Due to these outstanding properties, CaF2 single crystal has considered as a promising material for short-wavelength light sources in recent lithography processes. However, there is an inherent birefringence of the material at 157 nm and the resulting aberration can be compensated for through the combination of the (100) plane and the (111) plane. Therefore, it is necessary to investigate the characteristics according to the plane. In this study, we analyzed crystallinity, optical properties of commercial CaF2 single crystal wafers grown by the Czochralski method. In particular, through chemical etching under various conditions, it was confirmed that the shape of etch pits appears differently depending on the plane and the shape and array of specific etch pits affected by dislocations and defects were examined.

Necessity of oral health education for students major in early childhood education (유아교육 관련 학과 학생의 구강보건교육 필요도에 관한 연구)

  • Goo, Hyo-Jin;Lee, Myeong-Ju
    • Journal of Korean Dental Hygiene Science
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    • v.1 no.1
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    • pp.11-21
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    • 2018
  • This research is intended to develop oral health education program that can improve quality of oral health of infants by investigating the actual condition of oral health education provided to students major in early childhood education and contents and method of oral health education that they needed. A questionnaire survey was conducted for 427 students enrolled in related departments such as the Early Childhood Education Division and the Early Childhood Education Department at five universities in Gyeongsangnam-do. Questionnaires consisted of general characteristics, awareness of oral health, presence of experience in oral health education, necessity of oral health education, preference for oral health education method, oral health education contents. The collected data were analyzed by SPSS(Statistical Package for the Social Science) Ver 20.0. 1. Presence of experience in oral health education based on the general characteristics showed statistically significant differences only concerning the 'school system' and the 'school year' (p<0.05), and subjective awareness of oral health based on the presence of oral health education experiences showed statistically significant differences concerning the 'interest in oral health' and the 'importance of oral health' (p<0.05). 2. Necessity of oral health education based on the subjective awareness of oral health showed statistically significant differences concerning the 'interest in oral health' and the 'importance of oral health' (p<0.05). 3. Necessity of oral health education based on the preference for oral health education method showed statistically significant differences concerning the 'intention to participate in oral health education' and the 'oral health education cycle' (p<0.05). 4. The most necessary information for oral health education is proper toothbrushing method 4.24, cause of tooth decay and prevention method 4.13, helpful food and poor food for tooth 3.97, toothbrush selection and storage method 3.85. Fluoride application and fissure sealant were lowest 3.38. As a result of this research, necessity of oral health education was large regardless of general characteristics, experience in oral health education, subjective awareness of oral health, and preference for oral health education. Also the more the 'interest in oral health' in 'subjective awareness of oral health', the more the 'necessity of oral health education' and 'intention to participate in oral health education'. Therefore it is necessary to develop systematic and repetitive oral health education for students major in early childhood education.

Examination of Soil Contamination Status and Improvement Strategies within Urban Development Projects (도시개발사업 내 토양 오염 현황과 개선 방안 고찰)

  • Heo, Sujung;Lee, Dong-Kun;Kim, Eunsub;Jeon, Seong-Woo;Jin, Zhiying
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.27 no.3
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    • pp.45-56
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    • 2024
  • Heavy metals emitted from urban development do not decompose in the soil and remain for long periods, continually impacting the environment. Since the mid-1990s, there has been increasing societal concern in South Korea regarding soil contamination, prompting various legislative revisions to reduce pollution. This study utilizes the Environmental Impact Assessment Support System (EIASS) to investigate projects in the metropolitan area that have exceeded the Ministry of Environment's soil contamination concern levels from 1989 to 2022 and to examine improvements in the environmental impact assessment (EIA) process. The results reveal that the average concentrations of nine contaminants-cadmium (Cd), copper (Cu), arsenic (As), mercury (Hg), lead (Pb), hexavalent chromium (Cr6+), zinc (Zn), nickel (Ni), and fluoride (F)-have all increased over the years. Among these, Zn had the highest relative proportion, with 37.5% of the 40 sites exceeding environmental concern levels. Investigation of 19 specific projects at these exceedance sites showed that only 7 had documented analyses of contamination causes and remediation plans, and just one had contracted additional remediation services, though results from these efforts were found to be lacking. Furthermore, since 2019, a significant proportion of these sites were involved in residential developments, likely due to government initiatives in new city development and extensive housing supply plans. This research emphasizes the importance of public disclosure of the processes and outcomes of remediation efforts on historically contaminated soils prior to project development. It discusses improvements to the EIA by reviewing current legislation and international examples. The findings of this study are expected to heighten public awareness about heavy metal contamination and enhance transparency in soil remediation efforts, contributing to sustainable environmental management and development.

Enhanced Crystallinity of Piezoelectric Polymer via Flash Lamp Annealing (플래시광 열처리를 통한 압전 고분자의 결정성 향상 연구)

  • Donghun Lee;Seongmin Jeong;Hak Su Jang;Dongju Ha;Dong Yeol Hyeon;Yu Mi Woo;Changyeon Baek;Min-Ku Lee;Gyoung-Ja Lee;Jung Hwan Park;Kwi-Il Park
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.4
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    • pp.427-432
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    • 2024
  • The polymer crystallization process, promoting the formation of ferroelectric β-phase, is essential for developing polyvinylidene fluoride (PVDF)-based high-performance piezoelectric energy harvesters. However, traditional high-temperature annealing is unsuitable for the manufacture of flexible piezoelectric devices due to the thermal damage to plastic components that occurs during the long processing times. In this study, we investigated the feasibility of introducing a flash lamp annealing that can rapidly induce the β-phase in the PVDF layer while avoiding device damage through selective heating. The flash light-irradiated PVDF films achieved a maximum β-phase content of 76.52% under an applied voltage of 300 V and an on-time of 1.5 ms, a higher fraction than that obtained through thermal annealing. The PVDF-based piezoelectric energy harvester with the optimized irradiation condition generates a stable output voltage of 0.23 V and a current of 102 nA under repeated bendings. These results demonstrate that flash lamp annealing can be an effective process for realizing the mass production of PVDF-based flexible electronics.

Electrical Properties of 0.77(Bi1/2Na1/2)TiO3-0.23SrTiO3 (BNST23)/PVDF-TrFE Composites (스마트 페인트 센서용 0.77(Bi1/2Na1/2)TiO3-0.23SrTiO3 (BNST23)/PVDF-TrFE 복합소재 제조 및 전기적 특성에 관한 연구)

  • Sung Jae Hyoung;Eun Seo Kang;Yubin Kang;Chae Ryeong Kim;Chang Won Ahn;Byeong Woo Kim;Jae-Shin Lee;Hyoung-Su Han
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.4
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    • pp.433-438
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    • 2024
  • Piezoelectric ceramics play an important role in various electronic applications. However, traditional ceramics are difficult to be used in some complicated structures, due to their low flexibility and high brittleness. To solve this problem, this study prepared and investigated ceramic/polymer composites that can utilize a good flexibility of polymers. Polyvinylidene fluoride-trifluoroethylene (PVDF-TrFE) and 0.77(Bi1/2Na1/2)TiO3-0.23SrTiO3 (BNST23) ceramics were selected to fabricate the composites. Ceramic/polymer composites were prepared using various volume fractions of BNST23 ceramics. The distribution of piezoceramic particles in BNST23/PVDF-TrFE composites was investigated using optical microscopy (OM) and scanning electron microscopy (SEM). The dielectric and piezoelectric properties of the composites were significantly influenced by the volume fraction of the piezoelectric ceramics. As a result, the highest piezoelectric constant (d33) of 56 pC/N was obtained in a composites with 70% volume fraction of BNST23 ceramics. Accordingly, it is expected that BNST23/PVDF-TrFE composites can be applied to various sensor applications.

Degree of Interest for Dental Caries Prevention and Child's Oral Health Behaviors in Korean Adults: Gallup Survey (한국 성인의 우식예방 인식과 자녀의 우식예방 실천행위조사: 한국갤럽자료분석)

  • Jin, Hye-Jung;Hwang, Yoon-Sook;Jin, Myoung-Uk;Choi, Youn-Hee;Song, Keun-Bae
    • Journal of dental hygiene science
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    • v.12 no.4
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    • pp.359-367
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    • 2012
  • This study was to evaluate the influence of dental caries prevention-related concerned and perceived in Korean adults and oral health behavior of their first child if they had children. A cross-sectional study in 1,014 adults over 19 years old were conducted in Korean adults, asked to answer a computer-assisted telephone interview regarding their oral health-related knowledge, behavior, concerned of caries prevention and child's behaviors such as frequencies of tooth brushing, chewing the xylitol gum and dental checkup. The statistical analysis was done by using the SPSS 19.0 program (IBM Co., Armonk, NY, USA). Awareness of caries prevention in the female than male, 40~49 years old age group was higher. Parents of school-age children were higher level of awareness of the dental caries prevention than other group. As knowledge and behavior of dental caries prevention were higher, the child's conduct regular oral health checkups, fluoride topical application and dental sealant was significantly higher. The higher the concerned of caries preventive, the intention of oral health behaviors and child's oral health behaviors was more increased. Awareness of caries prevention had effect on the perception of the impact of the child's oral health behaviors.

A Study on Oral Health Awareness, Oral Health Behavior and Dental Caries among low Socio-Economic Status Children: the cases of local children's center in Incheon (저소득층 아동의 구강보건인식과 행위 및 치아우식실태 조사 (인천광역시 지역아동센터를 중심으로))

  • Han, Su-Jin;Hwang, Yoon-Sook;Yoo, Jung-Sook;Kim, Yoon-Sin
    • Journal of dental hygiene science
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    • v.8 no.3
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    • pp.147-153
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    • 2008
  • The purpose of this study was to attempt to lay the foundation for the development of oral health programs geared toward promoting the oral health of low socioeconomic class children. The subjects in this study were 257 school children who used local children's centers. The findings of the study were as follows: 1. The children mean scored 5.74 on oral health knowledge. 2. In terms of oral health awareness, 47.1% viewed the right toothbrushing as the best way to stay away from dental caries. 3. 45% of the subjects reported toothbrushing at least three times daily. 21.4% visited dental institutions three or more times in the past year. 33.1% had never undergone application of fluoride. 30.4% had never received oral health education. 4. The mean level of caries was 4.61 dft index in 1-2th grade, 3.27 DMFT index in 5-6th grade, 1.47 DMFT index in the 3-4th grad and 1.19 DMFT index in the 1-2th grade. 5. The mean level of Patient Hygiene Performance (PHP index) was 3.59, and there was no significant association was pound between PHP index and grade. 6. Oral health behavior wasn't affected by their oral health awareness, and knowledge.

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