• Title/Summary/Keyword: fluid inclusions

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Mineral Paragenesis and Fluid Inclusions of Geoje Copper Ore Deposits (거제동광상(巨濟銅鑛床)의 광물공생관계(鑛物共生關係)와 유체포유물(流體包有物))

  • Kim, Chan Jong;Park, Hee-In
    • Economic and Environmental Geology
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    • v.17 no.4
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    • pp.245-258
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    • 1984
  • Geoje copper ore deposits are fissure filled copper veins which developed in late Cretaceous pyroclastics, andesite and shale. Mineral paragenesis reveals a division of the hydrothermal mineralization into three stages: Stage I, deposition of pyrite, magnetite, specularite, quartz and chlorite; Stage II, deposition of chalcopyrite, sphalerite, galena, tetrahedrite, aikinite, cosalite, electrum, quartz and chlorite; Stage III, deposition of barren calcite. Filling temperatures of fluid inclusions in quartz of stage I range from 171 to $282^{\circ}C$ whereas fluid inclusions in quartz and sphalerite of stage II range from 213 to $262^{\circ}C$ and from 186 to $301^{\circ}C$ respectively. Salinities of fluid inclusions in quartz of stage I range from 5.2 to 11.2 weight percent equivalent to NaCl. Salinities of fluid inclusions in quartz and sphalerite of stage II range from 6.6 to 10.9 and from 7.1 to 14.4 weight percent equivalent NaCl. Salinities of ore fluid during major mineralization stage in this deposits reveal nearly the same ranges as those of many copper deposits in Koseong copper mining district which located about 30km apart from Geoje mine. But filling temperatures of fluid inclusions formed during major copper mineralization stage in this deposits show slightly lower than those of copper deposits in Koseong copper mining district.

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Fluid Inclusion Study of the Cretaceous Granite in the Yonghwa Area (용화(龍化)지역에 분포하는 백악기 화강암(化崗岩)에 포함된 유체포유물(流體包有物)에 관한 연구(硏究))

  • Youn, Seok-Tai;Park, Hee-In
    • Economic and Environmental Geology
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    • v.27 no.3
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    • pp.231-236
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    • 1994
  • Fluid inclusions have been studied in phenocryst quartz from the Cretaceous porphyritic granite. Three main types of fluid inclusion were found: liquid-rich inclusion (I type), gas-rich inclusion (II type) and solid-bearing inclusions (III-A, III-B). The solid-bearing inclusions (III-A, B) represent the earliest trapped fluids. They have salinities between 63 and 67.5 wt.% equivalent NaCl. These are high saline inclusions containing NaCl and KCl daughter crystals. Homogenization temperature inferred from the fluid inclusion study ranges from 620 to $700^{\circ}C$. Type I and II inclusions were observed within the same fracture. This cause for these differences in degree of filling is evidence of boiling. Salinities of type I and II inclusions range from 10.24 wt.% to 13.44 wt.%, from 8.4 wt.% to 11.48 wt.% NaCl equivalent, respectively.

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Fluid Inclusions of Granitoids and their Bearing on Mineralization in South Korea

  • Tetsuya, Shoji;Than, Zaw
    • Economic and Environmental Geology
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    • v.23 no.2
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    • pp.127-133
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    • 1990
  • Relation between fluid inclusions and mineralization has been studied for 30 granitoid specimens from 19 localities in South Korea. Polyphase inclusions are found in granitoid specimens of 9 localities. In the vicinities of 6 localities among them occurs any of W, Cu or Fe deposits of the vein-, stockwork-, skarn-or pegmatite-type. On the contrary, no ore deposit is reported near the granitoids characterized by no polyphase inclusion except only one locality. This fact implies that the occurrence of polyphase inclusions is a good indicator for such kinds of mineralization. Ores and country rocks of some of the deposits contain polyphase inclusions in their quartz crystals. The fact that many polyphase inclusions occur in granitoids and ore constituents suggests that highly saline hydrothermal solution played an important role for the formation of such kinds of deposits. On the contrary, the granite and the ore of the Mugug gold deposit have many fluid inclusions, but are free from the polyphase type.

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Solid Phases in Polyphase Inclusions from North Ore Deposits, Dunjeon Gold Mine (둔전금광산 북광상에서 산출되는 다상포유물내의 고상)

  • Park, Hee-In;Lee, Chan Hee
    • Economic and Environmental Geology
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    • v.24 no.1
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    • pp.1-8
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    • 1991
  • North ore deposits of the Dunjeon gold mine is disseminated-stockworks deposits emplaced in Ordovician Dongjeom quartzite. Six types of fluid inclusions are recongnized in the stage I quartz. Among them polyphase inclusions(type-IV-A, B) are predominent in the lower part of stage I quartz crystals whereas liquid and gas inclusions(type I, II) are abundant in the upper part of the same quartz crystals. Liquid $CO_2$-bearing inclusions(type III-A, B)occur as pseudosecondary inclusions. Solid phases in polyphase inclusions are identified by using scanning electron microscopy combined with energy dispersive x-ray spectroscopy. The solid phases are as follows; halite, sylvite, hydrophyllite, quartz, muscovite, calcite, ankerite, K-Mg-Fe-Al-Si mineral, Ca-Fe-Si mineral, Mg-Al-Si mineral, two kinds of Fe-mineral and Cu-Fe mineral. Results of freezing and heating experiments of fluid inclusions and identification of daughter minerals in polyphase inclusions in the stage I quartz reveal that ore fluids were high saline system NaCl-KCl-$CaCl_2$-$H_2O$ in the earier stage and then evolved to rather simple system NaCl-$H_2O$ in the later stage, and temporally fluid mixing occured with system $CO_2$-$H_2O$. Homogenization temperatures and salinity of fluid inclusions in the stage I range from 290 to $454^{\circ}C$ and from 0.2 to 54.2 wt. % equivalent to NaCl.

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Petrochemical and Fluid Inclusion Study on the Porphyritic Granite in the Yonghwa-Seolcheon Area (용화(龍化)-설천(雪川) 지역(地域)에 분포하는 백악기 반상화강암(斑狀花崗岩)의 암석화학(岩石化學) 및 유체포유물(流體包有物)에 관한 연구(硏究))

  • Youn, Seok-Tai;Park, Hee-In
    • Economic and Environmental Geology
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    • v.28 no.5
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    • pp.445-454
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    • 1995
  • The petrochemical data of the porphyritic granites of Cretaceous age in the Yonghwa-Seolcheon area show the trend of subalkaline magma, calc-alkaline magma, I-type granitoid and magnetite series. This granite is the relevant igneous rock of gold-silver mineralization in this mining district Fluid inclusions have been studied in phenocryst quartz from the Cretaceous porphyritic granite. Three main types of fluid inclusion were found : liquid-rich inclusion(I type), gas-rich inclusion(II type) and solid-bearing inclusions(III-A, III-B). The solid-bearing inclusions(III-A,B) represent the earliest trapped fluids. They have salinities between 41.0 and 67.5 wt% equivalent to NaCl. These are high saline inclusions containing NaCl and KCl daughter crystals. Homogenization temperature inferred from the fluid inclusion study ranges from 650 to $75^{\circ}C$ Type I and II inclusions were observed within the same fracture. This cause for these differences in degree of filling is evidence of boiling. Salinities of type I and II inclusions range from 9.87 wt% to 15.29 wt%, from 8.40 wt% to 14.64 wt% NaCl equivalent, respectively.

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Gas and Solute Compositions of Fluid Inclusions in Quartz from Some Base-metal ore Deposits, South Korea (남한의 주용 금속광상산 석영내의 유체포유물의 가스성분과 용존성분의 화학조성)

  • Kim, Gyu-Han;Jeong, Hae-Ran
    • Economic and Environmental Geology
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    • v.32 no.5
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    • pp.421-434
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    • 1999
  • Gas and chemical compositions of fluid inclusions in quartz some of Au-Ag, Pb-Zn-Cu and W-Mo mineral deposits in South Kores were analyzed to interpret the sources of ore fluid and the depositional condition of ore minerals in base-metal ore deposits. Fluid inclusions in quartz from the gold and silver mines are characterized by $CO_2$ rich fluids which have a wide range in $CH_4 \;and\; CO_2$ contents ($CH_4/CO_2$=0.001-0.225). The $CO_2$ rich but $CH_4$-poor nature of the fluid reflects the high fo2 condition during the mineral precipitation. The C2H6 is detected in hydrothermal quartz vines in metasedimentary rocks from the Jeonjoo-il, Youngbokari and Taechang mines. The $CH_4 /CO_2$ rations in W-Mo bearing quartz veins range from 0.005 to 0.214, which is similar with those in Au-Ag mines. However, skarn formation stage. Fluid inclusions, A relatively good correlation between Na and Cl contentrations reflects varible salinity in the fluid inclusion, it is suggested that the chemistry of promary magmatic hydrothermal fluids has changed during post-magmatic alteration and/or wall rock alteration processes. The content of gas compositions also depends on the kinds of country rocks, supporting above conclusion.

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CFD aided design of the continuous casting tundish (전산유체기법을 이용한 연속주조 Tundish 의 형상 설계)

  • Cho J. R.;Ha M. Y.;Lee S. W.
    • Journal of computational fluids engineering
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    • v.2 no.1
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    • pp.117-128
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    • 1997
  • Effects of dam and weir on the fluid flow and behavior of inclusions in the continuous casting tundish have been studied using the CFD (Computational Fluid Dynamics) technique. Inclusions affecting the quality of steel products have been considered to be passive: the fluid flow has been obtained for unstaggered grid points defined on body-fitted generalized cuvilinear coordinates with no attention on inclusions, and the spatial propagation of inclusions has been determined by using the flow field data. The result show that the dam and weir direct the flow to the free surface and increase the residence time of inclusions significantly, and thereby that inclusions have much more chance to be floated to the free surface of the tundish where it is eliminated. It is also found that they offer more margin on the geometric design of exit nozzles connected to moulds. This finding is particularly important for twin casting operations where the quality of steel products from the two moulds be kept uniformly.

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Fluid Inclusions of Daehwa and Donsan Tungsten-Molybdenum Deposits (대화(大華) 및 돈산(敦山) 중석(重石)·모리브덴 광상(鑛床)의 유체포유물(流體包有物))

  • Park, Hee-In;Choi, Suck-Won;Kim, Deog-Lae
    • Economic and Environmental Geology
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    • v.18 no.3
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    • pp.225-237
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    • 1985
  • Mineralization of Daehwa and Donsan W-Mo deposits can be devided into three distinct depositional stages on the basis of mineral paragenesis and flnid inclusion studies; stage I, deposition of oxides and silicates ; stage II, deposition of base-metal sulfides and sulfosalts with carbonates; stage III, deposition of barren calcite and fluorite. Tungsten, molybdenum and tin mineralization occurred in stage I. Fluid inclusion studies reveal that ore fluid of stage I were homogeneous $H_2O-CO_2$ fluids containing 3.5~14.6 mol % $CO_2$. Minimum temperature and pressure of stage I ore fluids were $240^{\circ}C$ and 500 bars respectively. Salinities of aqueous type I inclusions in minerals of stage I range from 3.7 to 7.6 wt. % equi. NaCl. whereas those of $CO_2$-containing type III inclusions range from 0.3 to 4.4 wt. %. Temperatures of stage II ore fluids range from 200 to $305^{\circ}C$ on the whole and salinities were in the range of 3.2~7.2 wt. %. Homogenization temperatures of fluid inclusions in calcite and fluorite of stage III range from 114 to $186^{\circ}C$ and salinities were in the range of 0.9~4.3 wt. %. Sulfur fugacities during stage II deduced from mineral assemblages and tamperature data from fluid inclusions declined from earlier to later in the range of $10^{-11}{\sim}10^{-18}atm$. Fluid inclusion evidences suggest that the dominance of $CO_2$ in ore fluid during W-Mo mineralization is the characteristic features of Cretaceous W-Mo deposits of central district of Korea compared to those of Kyeongsang basin district.

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The use of fluid inclusions to constrain P-T-X conditions of formation of Eonyang amethyst (언양 자수정 형성 환경의 압력-온도-성분에 대한 유체포유물의 이용)

  • K. H. Yang
    • The Journal of the Petrological Society of Korea
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    • v.5 no.1
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    • pp.1-9
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    • 1996
  • Eonyang amethyst deposits are thought to be spatially and temporally associated with the biotite granite of the Kyeongsang Basin. The examined euhedral quartz crystals in cavities in the aplite intruded biotite granite are colored-zoned from white at the base to amethystine at the tops. Three types of primary Inclusions were observed and three is representing each types are constructed to constrain the trapping conditions and fluid evolution involved during the formation of the amethyst. The intersection of the isochore representing the early fluid inclusions with solidus temperature of the host granite indicates initial quartz formation at about $600^{\circ}C$ and 1.0-1.5 kbars . Intermediate quartz formation, associated with the high-salinity inclusions, occurred at somewhat lower temperatures ($400^{circ}c$) and pressures of about 1 kbar. The amethystine quartz formed from $H_2O$-$CO_2$-NaCl fluids at temperatures between 280-$400^{circ}c$ and pressures of about 1 kbar. Early quartz is interpreted to have formed from fluids that either exsolved from or were in equilibrium with the granite at near solidus conditions, whereas the amethystine quartz apparently grew from fluids of at least partial sedimentary origin.

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