• Journal of Korean Society of Water and Wastewater
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• v.18 no.5
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• pp.666-672
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• 2004

Granular media filtration is used almost universally as the last particle removal process in conventional water treatment plants. Therefore, superb particle removal efficiency is needed during this process to ensure a high quality of drinking water. However, every particle can not be removed during granular media filtration. Besides the pattern of particle attachment is different depending on physicochemical aspects of particles and suspension. Filtration experiments were performed in a laboratory-scale filter using spherical glass beads with a diameter of 0.55 mm as collectors. A single type of particle suspension (Min-U-Sil 5) and pH control was used to destabilize particles. The operating conditions were similar to those of standard media filtration practice: a filtration velocity of 5 m/h. More favorable particles, i.e., particles with smaller surface charge, were well attached to the collectors especially during the early stage of filtration. This selective attachment of the lower charged particles caused the zeta potential distribution (ZPD) of the effluent to move to a more negative range. On the other hand, the ZPD of the effluent did not keep moving from less negative to more negative during the later stages of filtration, and this result was thought to be caused by two reasons: ripening effects and the detachment of flocs.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.41 no.1
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• pp.24-29
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• 2009

The use of fluorescent whitening agents (FWAs) increases as the demand for the whiter and brighter printing papers increases. FWAs are used as internal and surface treatment chemicals. FWAs that are not used properly in the papermaking process, however, remain in the process water and may demage the paper quality and processes. In this study, a new idea to eliminate FWAs from the process water, consisted of the floc formation of FWAs with cationic chemicals, such as cationic polyelectrolytes and alum, and the removal of the floc by screening or sedimentation, was proposed. Flocculation of FWAs, that is the first step to remove FWAs from the process water, was investigated using turbidity and particle size measurement. Relationship between turbidity and particle size showed that the turbidity could reflect the particle size change of FWA flocs and was proper for the evaluation of flocculation phenomena. Poly-DADMAC was more efficient than PEI to induce the flocculation of FWAs. Alum was effective chemical for the flocculation and sedimentation of FWAs.

• Membrane and Water Treatment
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• v.11 no.2
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• pp.159-166
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• 2020

In this study, the performance and antifouling properties of polysulfone (PSf) and polyvinylidene fluoride/polyvinylpyrrolidone (PVDF/PVP) membranes in a membrane bioreactor (MBR) were investigated. The membranes were prepared via phase inversion method, and then characterized by a set of analyses including contact angle, porosity and water flux and applied in a lab-scale MBR system. Soluble microbial product (SMP), extracellular polymeric substance (EPS), FTIR, gel permission chromatography (GPC) and particle size distribution (PSD) analyses were also carried out for MBR system. The results showed that the MBR with PSf membrane had higher hydrophobic organic compounds which resulted in formation of larger flocs in MBR. However, in this MBR had high compressibility coefficient of cake layer was higher (n=0.91) compared to MBR with PVDF/PVP membrane (n=0.8); hence, the fouling was more profound. GPC analysis revealed that compounds with molecular weight lower than 2 kDa are more formed on PSf membrane more than PVDF/PVP membrane. The results of FTIR analysis confirmed the presence of polysaccharide and protein compounds on the cake layer of both membranes which was in good agreement with EPS analysis. In addition, the results showed that their concentration was higher for the cake on PSf membrane.

• Environmental Engineering Research
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• v.21 no.4
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• pp.365-372
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• 2016

The effects of hydrodynamics and alum dose on particle growth were investigated by monitoring particle counts in a rapid mixing process. Experiments were performed to measure the particle growth and breakup under various conditions. The rapid mixing scheme consisted of the following operating parameters: Velocity gradient (G) ($200-300s^{-1}$), alum dose (10-50 mg/L) and mixing time (30-180 s). The Poisson regression model was applied to assess the effects of the doses and velocity gradient with mixing time. The mechanism for the growth and breakup of particles was elucidated. An increase in alum dose was found to accelerate the particle count reduction. The particle count at a G value of $200s^{-1}$ decreased more rapidly than those at $300s^{-1}$. The growth and breakup of larger particles were more clearly observed at higher alum doses. Variations of particles due to aggregation and breakup of micro-flocs in rapid mixing step were interactively affected by G, mixing time and alum dose. Micro-flocculation played an important role in a rapid mixing process.

• Journal of the Korean Ceramic Society
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• v.39 no.5
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• pp.446-451
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• 2002

Zirconia/alumina mixture powder was spray-dried various degree of dispersion, type of dispersants and powder content in the slurry. The quality of the granule was determined by observation of the granule shapes after spray drying and fracture of intergranular boundaries during pressing. Defect-free granules were obtained from the powders that formed weak flocs in the slurry. The granules, spray-dried from the slurry containing 32.5 vol% powder mixture and PVP as binder, were fractured completely during shaping and the sintered specimens showed a density of 99.7% and a flexural strength of 850 MPa.

• Membrane and Water Treatment
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• v.8 no.6
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• pp.517-528
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• 2017

This study evaluates the performance of membrane bioreactor (MBR) coupled with a modified walnut shell granular activated carbon (WSGAC) for tannery wastewater treatment. For this purpose, a pilot with overall volume of 80L and 12 hours hydraulic retention time (HRT) is operated in three scenarios. Here, the chemical oxidation demand (COD) of wastewater is reduced more than 98% in both C:N ratios of 13 (S1) and 6.5 (S2). This performance also remains intact when alkalinity depletes and pH reduces below 6 (S3). The ammonium removal ranges between 99% (S2) and 70% (S3). The reliability of system in different operating conditions is due to high solids retention time and larger flocs formation in MBR. The average breakthrough periods of WSGAC are determined between 15 minutes (S2) and 25 minutes (S1). In this period, the overall nitrate removal of MBR-WSGAC exceeds 95%. It is also realized that adding no chemicals for alkalinity stabilization and consequently pH reduction of MBR effluent (S3) can slightly lengthen the breakthrough from 15 to 20 minutes. Consequently, MBR can successfully remove the organic content of tannery wastewater even in adverse operational conditions and provide proper influent for WSGAC.

• Journal of computational fluids engineering
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• v.21 no.3
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• pp.24-30
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• 2016

In the water purification plant, the mixture of water and chemical from the mixing basin enters the flocculation basin. The rotating flocculators are generally used for the efficient flocculation of dregs. In this paper, the performance of flocculators of a vertical paddle type, widely used in the typical flocculation basins, and a hydro-foil type, recently disseminated in the field, are compared with each other by use of the numerical method. Also the characteristics and the efficiency are analyzed with CFD techniques. The strain rate and the eddy viscosity are compared for two types to predict the mixing efficiency, and the maximum speed and its location are pursued from the computed data. The hydrofoil type shows that the eddy viscosity is enhanced 1.66 to 3.03 times larger than that of vertical paddle type, and also produced 1.87 to 1.95 times larger flocs for each stage. However, the rapid rotation of hydrofoil may chop the floc to small size due to the higher turbulence intensity. From the result of computation, the strong and weak points of each type have been analyzed for the decision making.

• Journal of Korean Society on Water Environment
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• v.25 no.6
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• pp.935-942
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• 2009

During period of the rainy season of spring tide Aug. 2005, the suspended sediment transport rate from Seomjin River increased ten times as high as neap tide of low river discharge. During ebb tide of high terrestrial input, the grain size of suspended particles of both surface and bottom layer of the water column, showed a uni-modal distribution with a dominant peak at coarse fraction, which suggests a characteristic development of floc-sized particles of low mean effective density. On the contrary, the particles supplied toward upstream of Seomjin river from Gwangyang Bay during flood tide showed a bi-modal distribution with a secondary peak at finer fraction, possibly due to the resuspension and the deflocculation associated with the increased shear velocity at near bottom. Break-up of large flocs is also suggested by the increased mean effective density. However, settling velocity was lower during flood tide because of smaller grain size. Thus, net deposition of suspended sediment is expected at within Gwangyang Bay instead of upstream of Seomjin River, even though suspended sediment transport rate at near bottom water was three times higher than that at surface water during flood tide.

• Journal of Korean Society on Water Environment
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• v.28 no.3
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• pp.367-374
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• 2012

A flotation process has a shorter processing time and needs less space than a sedimentation process. Dissolved air flotation process (DAF) is an efficient flotation method and used in a conventional wastewater treatment process. However, DAF requires the circulation of water containing compressed air and requires expensive installation and operation cost. Plasma Air Flotation (PAF) process is able to float flocs by micro bubbles generated from underwater plasma without the circulation of bubbly water and additional saturators. Therefore, PAF can be an alternative solution overcoming economic barriers. In this study, Humic acid removal efficiency by PAF process was compared with that of sedimentation process. 44.67% and 87.3% reduction rate based on UV 254 absorbance has been measured in sedimentation and PAF respectively. In particular, PAF in the flocculation zone can dramatically remove humic acid from water. In flocculation zone, PAF can separate organic matters but sedimentation cannot.

• Journal of Korean Society of Water and Wastewater
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• v.23 no.4
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• pp.397-406
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• 2009

This study was conducted to monitor the floc sizes forming in the mixing zone in the water treatment plant. The dosing amount of poly aluminium chloride(PAC) was determined by particle dispersion analyzer(iPDA) in the lab and field scale test. During a field test period, PAC coagulant was used and the raw water was taken from Nakdong river. PAC wad diluted to activate the coagulant, leading to bring the more homogeneous dispersion in the shorter time. To monitor the floc sizes, the unit of floc size index(FSI) was used. With increasing of raw water turbidity, FSI value was increased. Also, the increased dosing amount of PAC brought the increased FSI and with overdosing of coagulant was in turn decreased. When the PAC was fed into the raw water after dilution in a field scale test, the width of FSI was narrower compared with the feeding of the mother liquor of PAC, implying that the formed flocs are denser and more uniform sizes. The width of FSI in average was varied on depending on the basicity of coagulant. Also, dF value, fractal dimension was evalued with the different coagulants, showing from 2.01 to 2.03. On-line floc monitor was effective for the optimal dosing in the drinking water plant.