• Membrane Journal
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• v.24 no.1
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• pp.10-19
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• 2014

Porous flat sheet membranes for separators in Zn air batteries were prepared with polyethersulfone (PES) solutions by immersion precipitation phase inversion method. PES/polyvinylpyrrolidone(PVP)/N-methylpyrrolidone(NMP) mixtures were used for casting solutions and water was used for coagulant. With the separators, Zn air batteries were fabricated. The separators were characterized by means of stress-strain test, impedance test and SEM. The Zn air batteries were tested by current interrupt method (CIM) and galvanostatic discharge method. The tensile strength increased with increasing PES content in the casting solution while the ionic conductivity decreased. On the other hand, the ionic conductivity increased while the tensile strength decreased with increasing PVP content. The effect of ionic conductivity trend of the separator in the Zn air battery was confirmed through current interrupt method and galvanostatic discharge method experiments. The battery with the separator from casting solution with higher PES content showed higher IR drop and lower discharge capacity. And the battery with the separator from casting solution with higher PVP content showed lower IR drop and higher discharge capacity.

• Polymer(Korea)
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• v.35 no.5
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• pp.438-443
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• 2011

In order to enhance water permeability through the improvement of fouling phenomena and wettability of hydrophobic porous membranes, various adsorption materials, i.e., poly(vinyl amine), poly (styrene sulfonic acid), poly(vinyl sulfonic acid), and poly(acrylamide-co-acrylic acid) were adsorbed onto the surface of polyethylene (PE) porous membrane. The concentration of adsorption solutions, adsorption time, the sort of salts and their ionic strength were varied, and the pure water permeability of their resulting adsorbed membranes was measured. In general, water permeability increased with an initial increase in the concentration of adsorption solution, adsorption time, and ionic strength and then decreased with a further increase. The pure water permeability of 375 $L/m^2h$(LMH), 35% enhancement, was obtained at a condition of poly(vinyl sulfonic acid) 1000 ppm, $Mg(NO_3)_2$ ionic strength(IS) 0.1, and adsorption time 150 sec, while the 50% (411 LMH) and 35% (374 LMH) enhancements were obtained at conditions of poly(styrene sulfonic acid) 1000 ppm, adsorption time 60 sec, and NaCl IS 0.1 and 0.2, respectively.