• Title/Summary/Keyword: flat membrane

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Membrane Fouling Models for Activated Sludge Cakes (활성슬러지 케이크의 분리막 오염 모델)

  • Kim, Dae Chun;Chung, Kun Yong
    • Membrane Journal
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    • v.24 no.3
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    • pp.249-257
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    • 2014
  • This experiment was carried out for a laboratory scale activated sludge bioreactor equipped with submerged flat sheet membrane using the synthetic wastewater. The membrane system for the activated sludge solution of MLSS 5,000 mg/L was operated with constant permeate flux by continuously permeating and periodically 10 minute-permeating/2 minute-resting modes, respectively. The transmembrane pressure was measured as the permeate flux increased from 10 to $25L/m^2{\cdot}hr$ under the constant air flowrate 0.25 L/min. Also, the complete blocking, standard blocking, intermediate blocking, incompressible cake and linear compressible cake fouling models were retrofitted for the experimental data in order to determine the state of the membrane fouling. Because the transmembrane pressure fluctuated as a pulse shape for every period of 10 minute-permeating/2-minute resting mode, the membrane fouling models were separately applied for the maximum and minimum connecting lines. The linear compressible cake fouling model for the activated sludge cakes was the best fitted with the experimental results from the above five models.

Modification of ultrafiltration membranes with carbon nanotube buckypaper for fouling alleviation

  • Guo, Jin;Liu, Jian-Hong;Wang, Li-Ying;Liu, Hong
    • Membrane and Water Treatment
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    • v.6 no.1
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    • pp.1-13
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    • 2015
  • The modification of ultrafiltration membranes with carbon nanotube (CNT) buckypaper on fouling control was investigated. Two types of commercially available flat-sheet membranes were used: PS35 and PES900C/D (PES) (the PS35 membranes were hydrophilic with a molecular weight cutoff of 20 kDa, and the PES membranes were hydrophobic with a molecular weight cutoff of 20 kDa). The CNT buckypaper modified ultrafiltration membranes were prepared by filtering a CNT suspension through the flat-sheet membrane in a dead-end ultrafiltration unit. After modification, the pure water flux of PES was significantly increased, while the pure water flux of PS35 was decreased. The properties of the CNT modified membranes were also investigated. Considering the antifouling properties, pure water flux of the modified membrane, and the stability of CNT buckypaper layer on the membrane surface, ethanol solution with a concentration of 50 wt.%, multi-walled carbon nanotubes (MWCNTs) with a larger diameter (30-50 nm), and the CNT loading with $7.5g/m^2$ was selected. The CNT buckypaper on the surface of ultrafiltration membranes can trap the pollutants in sewage effluent and prevent them reaching the surface of virgin membranes. Water quality analysis showed that the effluent quality of the modified membrane was obviously improved. The removal efficiency of humic acid and protein-like matters by the modified membrane was significant. These results indicate the potential application of the CNT buckypaper layer modified membranes in the field of wastewater reclaim.

Structural Performance of Reinforced Concrete Flat Plate Buildings Subjected to Fire

  • George, Sara J.;Tian, Ying
    • International Journal of Concrete Structures and Materials
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    • v.6 no.2
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    • pp.111-121
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    • 2012
  • The research presented in this paper analytically examines the fire performance of flat plate buildings. The modeling parameters for the mechanical and thermal properties of materials are calibrated from relevant test data to minimize the uncertainties involved in analysis. The calibrated models are then adopted to perform a nonlinear finite element simulation on a flat plate building subjected to fire. The analysis examines the characteristics of slab deflection, in-plane deformation, membrane force, bending moment redistribution, and slab rotational deformation near the supporting columns. The numerical simulation enables the understanding of structural performance of flat plate under elevated temperature and, more importantly, identifies the high risk of punching failure at slab-column connections that may trigger large-scale failure in flat plate structures.

LLE and SLM studies for Pd(II) separation using a thiodiglycolamide-based ligand

  • Kumbhaj, Shweta;Prabhu, Vandana;Patwardhan, Anand V.
    • Membrane and Water Treatment
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    • v.9 no.6
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    • pp.463-471
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    • 2018
  • The present paper deals with the liquid-liquid extraction and flat sheet supported liquid membrane studies of Pd(II) separation from nitric acid medium using a novel synthesized ligand, namely, N,N,N',N'-tetraethyl-2,2-thiodiethanthiodiglycolamide (TETEDGA). The effect of various diluents and stripping reagents on the extraction of Pd(II) was studied. The liquid-liquid extraction studies showed complete extraction of Pd(II) in ~ 5 min. The influence of nitric acid and TETEDGA concentration on the distribution of Pd(II) has been investigated. The increase in nitric acid concentration resulted in increase in extraction of Pd(II). Stoichiometry of the extracted species was found to be $Pd(NO_3)_2{\cdot}TETEDGA$ by slope analysis method. Extraction studies with SSCD solution showed negligible uptake of Pt, Cr, Ni, and Fe, thus showing very high selectivity and extractability of TETEDGA for Pd(II). The flat sheet supported liquid membrane studies showed quantitative transport of Pd(II), ~99%, from the feed ($3M\;HNO_3$) to the strippant (0.02 M thiourea diluted in $0.4M\;HNO_3$) using 0.01 M TETEDGA as a carrier diluted in n-dodecane. Extraction time was ~160 min. Parameters such as feed acidity, TETEDGA concentration in membrane phase, membrane porosity etc. were optimized to achieve maximum transport rate. Permeability coefficient value of $2.66{\times}10^{-3}cm/s$ was observed using TETEDGA (0.01 M) as carrier, at 3 M, $HNO_3$ feed acidity across $0.2{\mu}m$ PTFE as membrane. The membrane was found to be stable over five runs of the operation.

Structural and Thermal Properties of Polysulfone Membrane Including Graphene (그래핀을 포함하는 폴리설폰 멤브레인의 구조 및 열 특성)

  • Choi, Hyunmyeong;Choi, Yong-Jin;Sung, Choonghyun;Oh, Weontae
    • Membrane Journal
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    • v.28 no.1
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    • pp.37-44
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    • 2018
  • Polysulfone composites including graphene were prepared, and their thermal characteristics in membrane states were analyzed by using a custome-made residual stress analyzer and a thermal diffusivity analyzer based on laser flash method. The residual stress analysis was carried out on the polysulfone composite films deposited on Si (100) substrates for 1 cycle of heating and cooling runs. The flat membrane of graphene-embedded polysulfone composites were prepared by the phase transfer method in distilled water and the thermal conductivity was separately measured in the out-of-plane and the in-plane directions. The residual stress of the graphene-embedded polysulfone film was gradually decreased with increasing graphene loading and the out-of-plane thermal conductivity was distinguished from the in-plane thermal conductivity in the flat membranes. These thermal characteristics are caused by the structural uniqueness of graphene and the micro-void structures formed during membrane fabrication.

Chemical Resistance Characteristics of the Chlorinated Polyvinyl Chloride Microfiltration Flat-sheet Membrane with respect to Immersion Time (침지시간에 따른 Chlorinated Polyvinyl Chloride 정밀여과용 평막의 내화학적 특성)

  • Ryu, Jae-Sang;Son, Jae-Ik;Kim, Hee-Jun;Chung, Kun-Yong
    • Membrane Journal
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    • v.19 no.4
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    • pp.324-332
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    • 2009
  • This study aimed to measure chemical resistance properties of the microfiltration flat-sheet membrane made by Chlorinated Polyvinyl Chloride (CPVC) with respect to the immersed time. The solutions of effective chlorine 0.5 wt% NaClO, HCl 1 wt% and pH 4 buffer under acidic condition, NaOH 4 wt% and pH 10 buffer under alkine condition were used as widely applied chemicals for membrane washing. The CPVC membrane samples were immersed in the above chemical solutions during 1, 3, 5 and 10 days at 5, 25 and $50^{\circ}C$, respectively. After then, the tensile strength and elongation at break as the chemical durability for the samples were measured and evaluated. The tensile strength decreased within 5% at $5^{\circ}C$, but decreased up to 17% at 25 and $50^{\circ}C$ for 0.5 wt% NaClO solution mainly used for membrane cleaning. The chemical resistance of CPVC membrane was good enough for HCl 1 wt% and pH 4 buffer acid solutions, but the most vulnerable for NaOH 4 wt% solution.

Non-conforming modes for improvement of finite element performance

  • Choi, Chang-Koon;Lee, Tae-Yeol
    • Structural Engineering and Mechanics
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    • v.14 no.5
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    • pp.595-610
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    • 2002
  • This paper presents an efficiency of various non-conforming (NC) modes in development of a series of new finite elements with the special emphasis on 4-node quadrilateral elements. The NC modes have been used as a key scheme to improve the behaviors of various types of new finite elements, i.e., Mindlin plate bending elements, membrane elements with drilling degrees of freedom, flat shell elements. The NC modes are classified into three groups according to the 'correction constants' of 'Direct Modification Method'. The first group is 'basic NC modes', which have been widely used by a number of researchers in the finite element communities. The basic NC modes are effective to improve the behaviors of regular shaped elements. The second group is 'hierarchical NC modes' which improve the behaviors of distorted elements effectively. The last group is 'higher order NC modes' which improve the behaviors of plate-bending elements. When the basic NC modes are combined with hierarchical or higher order NC modes, the elements become insensitive to mesh distortions. When the membrane component of a flat shell has 'hierarchical NC modes', the membrane locking can be suppressed. A number of numerical tests are carried out to show the positive effect of aforementioned various NC modes incorporated into various types of finite elements.

Experimental Study of Impact Behaviors of the Membrane for LNG Storage Tank (LNG 저장탱크용 멤브레인의 충격거동에 관한 실험적 연구)

  • Kim, Young-Gyu;Kim, Chung-Kyun
    • Journal of the Korean Society of Safety
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    • v.10 no.4
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    • pp.68-74
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    • 1995
  • This paper analyzes the behaviors of the membrane under drop impact loadings using the acoustic emission technique. The analysis is useful for evaluating the strength of the membrane as well as for studying its damping characterisics due to the corrugation and the ring knot. The membrane for LNG storage tank is basically composed linear and circular elements. Two membrane specimens have approximately same drop impact mass and same drop speed. Locan 320 system with piezoelectric sensor is used in the experimental measurement. Experimental results for the membranes indicated that AE siganls having higher energies were generated with increasing drop impact loadings. It was confirmed that the ring knot. membrane has high absorption of drop impact loadings in comparison with the flat membrane. These results are very important to reliable design and to improve the safey of the membrane components.

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Characteristics of Protein Chromatography by Affinity Membrane Mudule (친화성 막모듈에 의한 단백질 크로마토그래픽 특성)

  • 이광진;염경호
    • KSBB Journal
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    • v.13 no.2
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    • pp.125-132
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    • 1998
  • Protein affinity membrane was prepared via the coating of chitosan gel on the porous flat polysulfone membrane surface, followed by the immobilization f the reactive dye (Cibacron Blue 3GA) to the chitonsan gel. The maximum protein binding capacity of affinity membrane was about 70${\mu}g/cm^2$ determined by the batch adsorption experiments of human serum albumin (HSA). Using module of this membrane, the characteristics of protein chromatography were investigated through the experiments of elution and frontal chromatography of HSA. This membrane module promises as a chromatography column, since it represented a lower pressure drop and a greater reproducibility. The protein separation ratio was significantly influenced by the flow rate of mobile phase and the injection quantity of HSA. The dynamic protein binding capacity of module decreased from the equilibrium binding capacity with increasing flow rate and approached the value of 15 - 20 ${\mu}g/cm^2$ for flow rates above 6 mL/min.

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Moisture Permeation Characteristics of Hollow Fiber Membrane Tube for Humidification According to Input Conditions of Wet Steam (습증기 투입 조건에 따른 가습용 중공사막 튜브 수분 투과 특성)

  • CHAE, JONGMIN;YU, SANGSEOK
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.6
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    • pp.620-626
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    • 2018
  • Recently, fuel cell field is receiving much attention as an environmentally friendly energy in the world. Among the various types of fuel cells, in the case of PEMFC, ions move through the membrane in the middle of the unit cell. Therefore, proper moisture is required inside the PEMFC. In the case of membrane type humidifier, flat membrane or hollow fiber membrane is mainly used. Since various parameters can change the performance, the performance investigation has to be carried out with parameters. In this study, water transport of hollow fiber membrane was investigated in terms of principle operating conditions such as temperature and flow rate.