• Title/Summary/Keyword: flame stability

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Combustion Characteristics of Methane-Oxygen Diffusion Flame Formed by Swirl-coaxial Injector (스월 동축형 인젝터에 의해 형성되는 메탄-산소 확산화염의 연소특성)

  • Bae, Seong Hun;Hong, Joon Yeol;Kim, Heuy Dong;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.2
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    • pp.1-8
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    • 2017
  • In order to analyze combustion characteristics of methane-oxygen diffusion flame in a model combustor, combustion experiments were carried out under various spray conditions of propellant scrutinizing combustion stability limit and flame shapes. As the propellant approached the theoretical equivalence ratio condition, a stable detached flame was observed even under high oxygen Reynolds number. And the length of the visible flame increased and the lift-off distance of the flame exhibited a tendency toward decrease. Due to the swirl effect of the propellant by the swirl-coaxial injector, a wide and short flame was produced. Thus, it may be appropriate to employ the swirl-coaxial injector in thrusters having a limited physical dimension.

Effect of Phosphorous-Based Flame Retardants on the Weight, Diameter, and Thermal Stability after Stabilization Processes of Rayon Fibers for Carbon Fibers (탄소섬유용 레이온섬유의 안정화공정 후 중량, 직경 및 열안정성에 미치는 인계 난연제의 영향)

  • Yoon Sung Bong;Cho Donghwan;Park Jong Kyoo
    • Polymer(Korea)
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    • v.29 no.2
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    • pp.211-215
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    • 2005
  • Stabilization process is absolutely necessary to convert the precursor fibers into chemically, physically, thermally and structurally stable carbon fibers. Especially, it is critically important for rayon fibers experiencing severe weight loss and thermal shrinkage occurring at the stabilization stage below $400^{\circ}C$. The stabilization of rayon fibers strongly depends not only on stabilization temperature but also on heating rate, chemical pre-treatment, atmosphere, and so on. In the present study, the weight loss, fiber diameter change occurred in the furnace during the stabilization process for rayon fibers produced with various heating rates and in the absence and presence of phosphorous-based flame retardants and the thermal stability of the stabilized fibers were investigated. The result indicates that the weight, diameter and thermal stability of the rayon fibers are significantly affected by the type and amount of the flame retardant used. It is also suggested that the pre-treatment of rayon fibers with a concentration lower than $3\;vol\%$ of phosphoric acid is most desirable for further carbonization process of stabilized rayon fibers.

Assessment on the Flame Retardancy for Polyethylene/Montmorillonite Nanocomposite (Polyethylene/Montmorillonite Nanocomposite의 난연성 평가)

  • Song, Young-Ho;Chung, Kook-Sam
    • Fire Science and Engineering
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    • v.20 no.4 s.64
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    • pp.72-76
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    • 2006
  • Polymer/clay nanocomposites have generated considerable interests in the past decade because adding just tiny amount of clay to the polymer matrix could produce a dramatic enhancement in physical, thermal and mechanical properties. Smectite clays, such as montmorillonite (MMT), are of great industrial value because of their high aspect ratio, plate morphology, intercalative capacity, natural abundance and low cost. In this study, PE/MMT nanocomposites were directly prepared by melt intercalating PE and the modified clay. The nanostructure was verified by X-ray diffraction (XRD) and transmission electron microscopy (TEM), and their flame retardant properties were measured and discussed by limiting oxygen index (LOI), char yield and smoke mass concentration. And their thermal stabilities were measured by differential thermogravimetric (DTG) and thermogravimetric analysis (TGA). The PE/MMT nanocomposites proved more effective the conventional composites in reinforcement. Two functions in the thermal stability of the PE/MMT nanocomposite, one is the barrier effect to improve the thermal stability, and another is catalysis, leading to a decrease of the thermal stability. The flammability was greatly decreased due to the formation of the clay-enriched protective char during the combustion.

Changes of Dimensional Stability of Cotton Knitted Fabrics after Flame Resistant Treatment (면 편성물의 방염처리에 의한 형태안정성의 변화)

  • Jee Ju-Won
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.9_10 s.146
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    • pp.1274-1284
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    • 2005
  • Effect of fixation methods and relaxation treatment on the dimensional stability and physical properties of MDPPA/HMM treated cotton knitted fabrics were studied. Combination of four different fixation methods - relaxation, swelling agent treatment, pad dry cure fixation, and wet fixation - were applied to flame retardant finish of 4 kinds of cotton knitted fabric with MDPPA/HMM. Then these fabrics were washed 10 times. As a result, In swelling treatment on 10G showed relatively higher value of length shrinkage than 14G. Length and width shrinkage were increased by initial washing treatment and no further change was shown after 6 washing cycles. After 10 washing cycles, length and width shrinkage decreased. The KES standardized basic value of B/W, 2HB/W and bursting strength of interlock were relatively larger than those of single jersey. The values of B/W and 2HB/W of cotton knitted fabrics were increased by relaxation and washing treatment but were decreased by swelling treatment. In addition, the bursting strength of the cotton knitted fabrics was decreased after fusing, washing and relaxation treatment.

The Effects of Injector and Swirler on the Flame Stability in a Model Combustor (모델연소기에서의 화염 안정화에 대한 분사기와 선회기의 영향)

  • Park, Seung-Hun;Lee, Dong-Hun;Bae, Choong-Sik
    • Journal of the Korean Society of Combustion
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    • v.3 no.2
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    • pp.13-27
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    • 1998
  • The optimization of frontal device including fuel nozzle and swirler is required to secure the mixing of fuel and air and the combustion stability leading the reduction of pollutant emissions and the increase of combustion efficiency in gas turbine combustor. The effects of injection nozzle and swirler on the flow field, spray characteristics and consequently the combustion stability, were experimentally investigated by measuring the velocity field, droplet sizes of fuel spray, lean combustion limit and the temperature field in the main combustion region. Flow fields and spray characteristics were measured with APV(Adaptive Phase Doppler Velocimetry) under atmospheric condition using kerosine fuel. Temperatures were measured by Pt-Pt13%Rh, R-type thermocouple which was 0.2mm thick. Spray and flame was visualized by ICCD(Intensified Charge Coupled Device) camera. It was found that the dual swirler resulted in the biggest recirculation zone with the highest reverse flow velocity at the central region, which lead the most stable combustion. The various combustion characteristics were observed as a function of the geometries of injector and swirler, that gave a tip for the better design of gas turbine combustor.

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Study on Combustion Stability and Flame Structure of Injectors Through Subscale Combustion Tests (모델 연소시험을 통한 분사기 연소안정성과 화염구조에 대한 연구)

  • Song Ju-Young;Lee Kwang-Jin;Seo Seonghyeon;Han Yeoung-Min;Seol Woo-Seok
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.10a
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    • pp.245-250
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    • 2004
  • The objective of the present study is to conduct model combustion tests for various injectors to identify their combustion stability characteristics. Three different double swirl coaxial injectors with variation of a recess number have been tested for the comparative study of stability characteristic and flame structure. Gaseous oxygen and mixture of gaseous methane and propane have been employed for simulating actual propellants used for a fullscale thrust chamber. Upon test results, the direct comparison between various types of injectors can be realized for the selection of the best design among prospective injectors.

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A Study on the Influence Coaxial Parallel Magnetic Field upon Plasma Jet (II) (Plasma Jet의 동축평행자계에 의한 영향에 관한 연구 2)

  • Choon Saing Jhoun
    • 전기의세계
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    • v.22 no.5
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    • pp.19-32
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    • 1973
  • This paper treats with some of plasma jet behaviors under magnetic field for the purpose of controlling important characteristics of plasma jet in the practices of material manufacturings. Under the existence and non-existence of magnetic field, the pressure distribution, flame length, stability and noise of plasma jet are comparatively evaluated in respect of such parameters as are current, gap of electrode, quantity of argon flow, magnetic flux density, diameter and length of nozzle. The results are as follows: 1) the pressure, the length and the noise of plasma jet rise gradually with the increase of are current, and have high values under identical arc current as the diameter of nozzle increases, but reverse phenomenon tends to appear in the noise. 2) The pressure, the flame length and the noise increase with the increased quantity of argon flow, and the rising slope of noise is particularly steep. Under magnetic field, the quantity of argon flow in respect of flame length has the critical value of 80(cfh). 3) The pressure and length of flame decrease with small gradient value as the length of gap increases, but the noise tends to grow according to the increase of nozzle diameter. 4) The pressure and the length of jet flame decrease inversly with the increase of magnetic flux density, which have one critical value in the 100 amps of arc current and two values in 50 amps. The pressure of jet flame can be below atomospher pressure in strong magnetic field. 5) "The constriction length of nozzle has respectively the critical value of 6(mm) for pressure and 23(mm) for the length of flame. 6) Fluctuations in the wave form of voltage become greater with the increase of argon flow and magnetic flux density, but tends to decrease as arc current increases, having the frequency range of 3-8KHz. The wave form of noise changes almost in parallel with that of voltage and its changing value increases with argon flow, arc current and magnetic flux density, having the freuqency range of 6-8KHz. The fluctuation of jet presurre is reduced with the increase of argon flow and magnetic flux density and grows with arc current.rent.

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Effect of Coflow Air Velocity on Heat-loss-induced Self-excitation in Laminar Lifted Propane Coflow-Jet Flames Diluted with Nitrogen (질소로 희석된 프로판 동축류 층류 제트 부상화염에서 열손실에 의한 자기진동에 대한 동축류 속도 효과)

  • Lee, Won-June;Yoon, Sung-Hwan;Park, Jeong;Kwon, Oh-Boong;Park, Jong-Ho;Kim, Tae-Hyung
    • Journal of the Korean Society of Combustion
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    • v.17 no.1
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    • pp.48-57
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    • 2012
  • Laminar lifted propane coflow-jet flames diluted with nitrogen were experimentally investigated to determine heat-loss-related self-excitation regimes in the flame stability map and elucidate the individual flame characteristics. There exists a critical lift-off height over which flame-stabilizing effect becomes minor, thereby causing a normal heat-loss-induced self-excitation with O(0.01 Hz). Air-coflowing can suppress the normal heat-loss-induced self-excitation through increase of a Peclet number; meanwhile it can enhance the normal heat-lossinduced self-excitation through reducing fuel concentration gradient and thereby decreasing the reaction rate of trailing diffusion flame. Below the critical lift-off height. the effect of flame stabilization is superior, leading to a coflow-modulated heat-loss-induced self-excitation with O(0.001 Hz). Over the critical lift-off height, the effect of reducing fuel concentration gradient is pronounced, so that the normal heat-loss-induced self-excitation is restored. A newly found prompt self-excitation, observed prior to a heat-loss-induced flame blowout, is discussed. Heat-loss-related self-excitations, obtained laminar lifted propane coflow-jet flames diluted with nitrogen, were characterized by the functional dependency of Strouhal number on related parameters. The critical lift-off height was also reasonably characterized by Peclet number and fuel mole fraction.

The Characteristics of Unconfined Hydrogen Diffusion Flames in Supersonic Air Flows (초음속 공기 유동장에서의 수소 확산 화염 특성에 대한 연구)

  • 김제흥;심재헌;김지호;윤영빈
    • Journal of the Korean Society of Propulsion Engineers
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    • v.4 no.4
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    • pp.78-86
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    • 2000
  • The objective of this research is to understand the characteristics of a nonpremixed, turbulent, hydrogen jet flame which is stabilized in Mach 1.8 coflowing air flows. In order to investigate the flame structure, flame lengths and fuel trajectories were measured by using direct photography, acetone PLIF, Mie scattering techniques, and numerical simulation. Effect of increasing air velocity was investigated when fuel velocity is fixed. The subsonic flame length was decreased drastically, however the supersonic flame length was increased slowly Then the change of flame blow out characteristics was observed as varying fuel nozzle lip thickness. The flame stability can be increased when fuel nozzle lip thickness was increased, which indicates that the minimum fuel lip thickness ratio is required for the stable supersonic flames. Also, it is found that fuel jet is blocked by high pressure zone and low scattering zone is made. Then the fuel that was moving along the recirculation zone had longer residence time within the supersonic flames, which made partially premixed zone.

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Electrochemical Performance of Tricredyl Phosphate and Trispentafluorophenly Phosphine as Flame Retardant Additives for Lithium-ion Batteries (리튬이온전지용 난연성 첨가제(TCP, TFPP)의 전기화학적 특성)

  • Ahn, Se-Young;Kim, Ke-Tack;Kim, Hyun-Soo;Nam, Sang-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.9
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    • pp.756-760
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    • 2007
  • Flame retardant(FR) properties were investigated with tricredyl phosphate(TCP) and tris(pentafluorophenyl)phosphine(TFPP) as additives for lithium-ion batteries. Thermal stability was improved with additives in $Li/LiNi\frac{1}{3}Mn\frac{1}{3}Co\frac{1}{3}O_2$ cells comparing to non-additive electrolytes. Oxygen evolution reaction of the cathode material was delayed to up $55^{\circ}C$, from $275^{\circ}C\;to\;330^{\circ}C$. Electrolytes with the 1 wt.% additives provided good FR properties while the resonable battery performance is maintained.