• 제목/요약/키워드: flame retardant finishing

검색결과 49건 처리시간 0.024초

제조공정제어에 의한 친환경 고성능 산업용 PET 난연시트 제조기술의 개발 (Development of PET Flame Retardant Sheets for Industrial Materials by Control of Manufacturing Process)

  • 김혜인;홍요한;박수민
    • 한국염색가공학회지
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    • 제21권4호
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    • pp.46-56
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    • 2009
  • In order to establish the standard manufacturing condition of PET flame retardant sheets, physicochetnical properties of the samples made by the conventional flame-retardant finishing were systematically investigated, including compatibility among flame retardant agent and finishing auxiliaries, surface property, and wicking property. From this results, the addition of washing and renapping process after the shearing process was required for the more effective in producing PET flame-retardant sheet by the standard finishing. The effect of the modification of the regular flame retardant finishing process was studied by FTIR, TGA, and flame retardancy test.

자동차 내장용 직물의 난연 및 발수가공 (Flame-Retardant and Water-Repellent Finishing of Automobile Indoor Fabrics)

  • 박병기;이방원;김환철;김학용
    • 한국염색가공학회지
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    • 제11권5호
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    • pp.7-12
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    • 1999
  • The objective of this study is to apply water repellent and flame retardant finishes simultaneously to the fabric used for automobile. Both two step and one step methods were tried to apply the finishing agent to the fabric. In the two step method, water repellent agent was treated first, and flame retardant agent was applied next. The reverse finishing process was also attempted. In the one step method, flame retardant agent and water repellent agent treated to the fabric in one bath. The results of two step method revealed that the finishing effect was better when the water repellent agent was treated first than when flame retardant agent was treated first. In one step method, fluoro water repellent agent was superior to silicon water repellent agent.

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수용성 Cyclcophosphazene 유도체를 이용한 견섬유의 이중경화형 방염가공 (Dual-curable Flame-Retardant Finish of Silk Fabrics Using a Water-soluble Cyclophosphazene Derivative)

  • 김정환;백지윤;장진호
    • 한국염색가공학회지
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    • 제34권4호
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    • pp.217-223
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    • 2022
  • Flame-retardant finished silk fabrics could release carcinogenic formaldehyde resulting from the conventional finishing agents. New water-soluble cyclophosphazene derivative can be used as a formaldehyde-free flame retardant for the silk protein. Dichloro tetrakis{N-[3-dimethylamino)propyl]methacrylamido}cyclophosphazene(DCTDCP) can be cured by heat or UV irradiation as a durable flame retardant for the silk fabrics. Treatment conditions were optimized including curing temperature and time, finishing formulations, and UV energy. At the 30% DCTDCP application, peak HRR and THR decreased by 42.6% and 49.6% respectively compared to the pristine silk fabrics. Also char residue increased up to 48% from 11% indicating solid-phase retarding mechanism. The flame-retardant silk fabrics showed a LOI of 31.1 and the washed sample maintained a LOI of 26.8 even after ten laundering cycles.

인 화합물에 의한 나일론 직물의 방염가공 (Flame Retardant Finishing for Nylon Fabric with Phosphate Compound)

  • 김수창
    • 한국염색가공학회지
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    • 제10권4호
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    • pp.30-36
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    • 1998
  • The need for the effective flame retardant finishing for synthetic fiber Is required. This paper is focussed on the analysis of physical properties of nylon 6 fabric treated with tris(2-chloroethyl) phosphate(TCEP) in comparision with the untreated fabric. In order to evaluate the flame retardance effect, limiting oxygen index and burn rate were determined. Above 20% add-on of TCEP on nylon 6 fabric, reasonable flame retardancy was observed. Thermal stability of the treated nylon 6 fabric was evaluated by TGA. It seems that TCEP acts via a condensed phase mechanism. Tenacity and moisture regain of the treated fabrics were not changed and washfastness of those was excellent.

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현장방염처리제도의 실효성 확보 방안에 관한 연구 (A Study on the Ways of Securing the Effectiveness of Field Flame Retardant Coating Process)

  • 박성현;백은선
    • 한국화재소방학회논문지
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    • 제25권2호
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    • pp.95-100
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    • 2011
  • 본 연구는 현장방염처리 물품에 대한 성능검사와 관련하여 불합리한 제도를 개선하고, 합리적인 방염성능검사 방법을 통하여 현장방염처리 물품에 대한 방염의 신뢰성을 확보하는데 궁극적인 목적이 있다. 이를 위해 최근 2년 동안 일선 소방관서에서 실시한 현장방염처리 물품에 대한 방염성능검사 실적을 토대로 최근에 사용되는 인테리어 마감자재 및 현장방염처리 경향에 대한 분석을 하였다. 또한 현장방염처리물품에 대한 성능검사 방법 및 절차, 방염처리업 등록제도의 문제점 등을 분석하여 현 실정에 적합한 방염성능검사 방법 및 성능검사의 신뢰성 확보를 위한 개선방안을 제시하고자 하였다.

침장용 난연 자카드직물의 제직설계 (Weaving design of flame retardant jacquard fabrics for bedding)

  • 안영무
    • 패션비즈니스
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    • 제14권5호
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    • pp.102-111
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    • 2010
  • The pegging board planning for jacquard weaves was carried out to express a big enough design in 60 inch width. 20 Kinds of fabrics were fabricated by a jacquard loom with a warp density of 168 yarns/inch, a weft density of 100T, and a weight of 180-220g/$m^2$ or 250-300g/$m^2$. The result of sanitary test about Escherichia coli, Staphilococcus aureus, Klebsiella pneumoniae and Salmonella typhimurium showed a sterilizing power of over 90% after cultivating for 30, 60, 120 minutes. And also its property was sustained after laundrying 20 times. The flame retardant properties showed a good result and complied with the flame retardant criteria of KOFEI 1001. Abrasion, laundry and light fastnesses of flame retardant fabrics showed 4-5 grades. The fabrics manufactured from 30's fiber appeared a little fluff and pill on the fabric. Therefore, they need a shearing process after finishing all processes to decrease the fluff or pill on the fabric. The flame retardant fabric manufactured from 30's and 40's fiber showed increased strength and elongation after soaping and dyeing finishing because the fabrics were shrunk.

분산염료 염색공정이 PET직물의 UV경화형 방염가공에 미치는 영향 (Effect of Disperse Dyeing on UV-curable Flame-retardant Finish of PET Fabrics)

  • 정용균;장진호
    • 한국염색가공학회지
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    • 제20권2호
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    • pp.66-74
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    • 2008
  • Effect of disperse dyeing on flame retardant finishing of PET fabrics via UV curing using three UV curable phosphorous-containing methacrylates and ammonium polyphosphate(APP) was investigated. The dye fixation and flame retardancy of PET fabrics did not change significantly with excellent durability to five laundering cycles irrespective of the dyeing and finishing sequence. However, the flame retardancy of Pekoflam-treated fabrics was lower than that of the UV treated and decreased substantially when heat treatment was carried out before the dyeing. The dyeability of the flame-retardant PET fabrics was not affected in the case of UV curing of the methacrylates alone. However, UV finishing after the dyeing caused significant decrease in K/S and ${\Delta}E$ due to changed refraction and inherent color of surface coating of the UV curable monomers and APP. Whereas the heat treatment with Pekoflam decreased both color fastness to laundering and sublimation, surprisingly the UV finish of PET fabrics before and after the dyeing increased the color fastness probably resulting from the presence of photopolymerized surface layer on the fabrics.

졸-겔법으로 제조된 방염제졸의 연기밀도 특성에 관한 연구 (Study on the Smoke Density Characteristics of Flame Retardant Sol Manufactured by a Sol-gel Method)

  • 조경래;이춘하;김시국
    • 한국화재소방학회논문지
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    • 제31권3호
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    • pp.11-18
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    • 2017
  • 본 연구에서는 건축물 내에 사용되는 실내장식물의 가연성으로 인해 화재 시 발생하는 연기로 인한 인명피해를 사전에 예방하기 위해 무기물의 실리케이트와 유기물의 실란커플링제를 졸-겔법으로 합성하여 방염성을 부여할 수 있는 비할로겐 방식의 유-무기 하이브리드 방염제졸을 새롭게 제조하였다. 제조된 방염제졸의 성능확인을 위해 방염성능기준에 의거한 연기밀도 측정기준인 ASTM E 662의 시험장치 및 절차에 따라 훈소모드 실험 및 불꽃모드 실험을 진행하여 성능을 확인하였다. 결과적으로 제조된 방염제졸은 기존의 방염제의 물성과 내열성능을 높여 화재 시 연기발생량을 감소시킬 수 있기 때문에 향후 다양한 실내장식물에서도 확대적용 함으로써 연기에 의한 피해에 있어 긍정적인 효과를 발휘할 것으로 생각된다.

방염제의 상쇄효과(相殺效果)의 연구현황 (The Research State for Offset Effect of Flame Retardant)

  • 영남대학교 방염기술연구회
    • 한국염색가공학회지
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    • 제8권5호
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    • pp.90-93
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    • 1996
  • 섬유공업에서 방염가공의 필요성은 여기서 제언할 필요조차 없고, 방염제와 타종가공약제간의 상승효과에 관한 연구논문은 많으나, 방염제의 상쇄효과에 관한 연구논문은 드물다. 여기에서 소개코저하는 내용은 보기드문 연구내용으로서 현업에 종사하시는 우리 회원들에게는 많은 도움이 되리라 생각하여 소개한다.

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인산/구연산 복합 산촉매 및 이산화티타늄을 적용한 면섬유의 난연 특성 (Flame Retardant Properties of Cotton Fiber with Phosphoric/citric Acid Catalysts and TiO2)

  • 양희진;김삼수;이상오;이재웅
    • 한국염색가공학회지
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    • 제33권4호
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    • pp.238-249
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    • 2021
  • In this study, the effect on flame retardancy and various physical properties when TiO2 was added with a citric acid/phosphate complex acid catalyst together with Pyrovatex CP new (N-methylol dimethylphosphonopropionamide), a phosphorus-based flame retardant, was studied on cotton fibers. SEM-EDS analysis was performed to confirm the surface characteristics and surface element analysis of the flame-retardant treated cotton fibers, and a vertical carbonization test was performed to confirm the char formation capability and flame retardancy according to the phosphoric acid ratio. By comparing the LOI index before and after washing 10 times, the washing durability of the flame retardant solution containing the phosphoric acid catalyst and TiO2 was tested by LOI index after ten washing cycles. In addition, the influence of the flame-retardant processing on the physical properties were compared including thermogravimetric analysis (TGA), tear strength and whiteness.