• Title/Summary/Keyword: fixed carbon

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Photocatalytic activity of Fe treated AC/TiO2 composites between visible light and UV light irradiation (가시광선과 UV광선에 의한 Fe 처리된 AC/TiO2 복합체의 광분해활성)

  • Meng, Ze-Da;Zhang, Kan;Oh, Won-Chun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.5
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    • pp.1760-1767
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    • 2010
  • FAT compounds photocatalysts were prepared with $TiOSO_4{\cdot}xH_2O$ (TOS) by a sol-gel method. The samples were characterized by scanning electron microscopy (SEM), BET specific surface area, X-ray diffraction analysis (XRD) and energy dispersive X-ray spectroscopy (EDX). The SEM results showed that ferric compounds and titanium dioxide were fixed onto the AC surfaces. The XRD results showed that Fe-AC/$TiO_2$ composites mostly contained anatase phase. EDX showed the presence of C, O, and Ti with Fe peaks in all samples. The photocatalytic activities were evaluated by the photocatalytic oxidation of methylene blue (MB) solution, via compare photodegradation of MB solution under visible light and UV light separately. Fe-AC/$TiO_2$ composites had an excellent photocatalytic under strong visible light irradiation. A small amount of Fe ions in AC/$TiO_2$ particles could obviously enhance their photocatalytic activity.

Whole Mount Preparation of Primary Cultured Neuron for HVEM Observation (배양된 시경세포 관찰을 위한 초고압전자현미경 홀마운트 시료제작기법)

  • Kim, Hyun-Wook;Hong, Soon-Taek;Oh, Seung-Hak;Park, Chang-Hyun;Kim, Hyun;Rhyu, Im-Joo
    • Applied Microscopy
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    • v.41 no.1
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    • pp.69-73
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    • 2011
  • High-voltage electron microscope (HVEM) has higher resolution and penetration power than conventional transmission electron microscope that could be load thick specimen. Some researchers have taken this advantage of HVEM to explore 3-dimensional configuration of the biological structures including tissue and cells. Whole mount preparations has been employed to study some cell lines and primary culture cells. In this study, we would like to introduce useful whole mount preparation method for neuronal studies. The plastic coverslips were punched, covered by formvar membrane and coated with carbon. The neurons obtained embryonic 18 rat hippocampus were seeded on the prepared cover slip. The coverslips were fixed, dried in freeze drier and kept in a descicator until HVEM observation. We could observe detailed neuronal structures such as soma, dendrite and spine under HVEM without conventional thin section and heavy metal stain. The anaglyphic image based on stereo paired image ($-8^{\circ},+8^{\circ}$) provides three dimensional perception of the neuronal dendrites and their spines. This method could be applied to sophisticated analysis of dendritic spine under the various experimental conditions.

A Study on the Methane Hydrate Formation Using Natural Zeolite (천연제올라이트를 이용한 메탄 하이드레이트 생성에 대한 연구)

  • Park, Sung-Seek;An, Eoung-Jin;Kim, Dae-Jin;Jeon, Yong-Han;Kim, Nam-Jin
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.23 no.4
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    • pp.259-264
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    • 2011
  • Gas hydrate is formed by physical binding between water molecule and gas such as methane, ethane, propane, or carbon dioxide, etc., which is captured in the cavities of water molecule under the specific temperature and pressure. $1\;m^3$ hydrate of pure methane can be decomposed to the methane gas of $172\;m^3$ and water of $0.8\;m^3$ at standard condition. If this characteristic of hydrate is reversely utilized, natural gas is fixed into water in the form of hydrate solid. Therefore, the hydrate is considered to be a great way to transport and store of natural gas in large quantity. Especially the transportation cost is known to be 18~25% less than the liquefied transportation. However, when methane gas hydrate is artificially formed, its reaction time may be too long and the gas consumption in water becomes relatively low, because the reaction rate between water and gas is low. Therefore, for the practical purpose in the application, the present investigation focuses on the rapid production of hydrates and the increment of the amount of captured gas by adding zeolite into pure water. The results show that when the zeolite of 0.01 wt% was added to distilled water, the amount of captured gas during the formation of methane hydrate was about 4.5 times higher than that in distilled water, and the methane hydrate formation time decreased at the same subcooling temperature.

Analytic Study of the Level of Introducing Bimodal TRAM System (신교통 바이모달트램 시스템 도입수준 분석 연구)

  • Eom, Jin-Ki;Choi, Myoung-Hun;Sung, Myoung-Joon;Lee, Jun;Park, Sang-Min
    • Journal of the Korean Society for Railway
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    • v.13 no.6
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    • pp.595-600
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    • 2010
  • The Bimodal Tram being developed in Korea is a new transit system that provides both benefits of rail and bus systems in terms of accessibility and fixed time schedule. The Bimodal Tram is expected to take an important role of transit system in Korea under the national strategy of transportation system such as 'Low Carbon and Green Growth' for the next generation. This study does define the key indices considered for a decision of introducing the Bimodal Tram system and develop a finalized index, BSI(Bimodal Score for Introduction), showing the level of Bimodal Tram system introduced at a city level. The transport/transit system varies depending on cities with respect to demographic characteristics, travel patterns, financial capabilities, etc. This study will help any cities where transport agencies are trying to introduce the Bimodal Tram as a new transit system.

A study for its Characteristics with Electric Variation in an Electrical Discharge Machining (방전가공에서 전기적 변화가 갖는 방전 특성에 관한 연구)

  • 신근하
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 1996.03a
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    • pp.132-136
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    • 1996
  • A Study is a experiment which is figure out to aptimum discharge cutting condition of the surfaceroughness, electric discharging speed and electro wear ratio with Ton Toff and V(voltage) as an input condition according to the current(Ip) in an electric spark machine ; 1)Electrode is utilized Cu(coper) and Graphite. 2)Work piece is used the material of carbon steel. The condition of experiment is; 1)Current is varied 0.7(A) to 50(A). 2)Pulse time(Ton) is varied 3($\mu$s) to 240($\mu$s) and also Toff is varied 7($\mu$s) to 20($\mu$s). 3)The time of electric discharging to work piece in each time is 30(min) to 60(min) 4)After the upper side of work piece was measured in radius (5${\mu}{\textrm}{m}$) of syulus analyzed the surface roughness to made the table and graph of Rmax by yielding data. 5)Electro wear ratio is; \circled1Coper was measured cx-machining and post machining but the electronic baiance. \circled2The ex-machining of graphite measured by it, the post-machining was found the data from volume specific gravity and analyzed to made its table and graph on ground the data 6)In order to keep the accuracy of voltage affected to the work piece was equipped with the A.V.R(Automatic Voltage Regulator). 7)The memory scope was sticked to the electric spark machine. 8)In order to preserve the precision of current, to get rid of the noise occured by internal resistance of electric spark machine and to force injecting for the discharge fluid, it made the fixed table for a work piece to minimize the work error by means of one's failure during the electric discharging According to above results, the surface roughness by the variation of electrodw and current was analyzed to compare KS(Korea Standards) It was decided the optimum condition of electric discharge cutting through analyzing the effect of electric discharge speed and electro wear ratio.

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Comparisons of Low Temperature Combustion Characteristics between Diesel and Biodiesel According to EGR control (EGR 제어를 통한 디젤 및 바이오디젤의 저온연소 특성 비교)

  • Lee, Yong-Gyu;Jang, Jae-Hoon;Lee, Sun-Youp;Oh, Seung-Mook
    • Journal of ILASS-Korea
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    • v.16 no.3
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    • pp.119-125
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    • 2011
  • Due to the oxygen contents in biodiesel, application of the fuel to compression ignition engines has significant advantages in terms of lowering PM formation in the combustion chamber. In recent days, considerable studies have been performed to extend the low temperature combustion regime in diesel engines by applying biodiesel fuel. In this work, low temperature combustion characteristics of biodiesel blends in dilution controlled regime were investigated at a fixed engine operating condition in a single cylinder diesel engine, and the comparisons of engine performances and emission characteristics between biodiesel and conventional diesel fuel were carried out. Results show that low temperature combustion can be achieved at $O_2$ concentration of around 7~8% for both biodiesel and diesel fuels. Especially, by use of biodiesel, noticeable reduction (maximum 50% of smoke was observed at low and middle loads compared to conventional diesel fuel. In addition, THC(total hydrocarbon) and CO(Carbon monoxide) emissions decreased by substantial amounts for biodiesel fuel. Results also indicate that even though about 10% loss of engine power as well as 14% increase of fuel consumption rate was observed due to lower LHV(lower heating value) of biodiesel, thermal efficiencies for biodiesel fuel were slightly elevated because of power recovery phenomenon.

HI concentration by EED for the HI decomposition in IS process (IS 프로세스의 HI 분해반응공정을 위한 전해 - 전기투석(EED) HI 농축)

  • Hong, Seong-Dae;Kim, Jeong-Geun;Lee, Sang-Ho;Choi, Sang-Il;Bae, Ki-Kwang;Hwang, Gab-Jin
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.2
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    • pp.212-217
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    • 2006
  • An experimental study on Electro-electrodialysis (EED) for IS (Iodine-Sulfur) process which is well known as hydrogen production system was carried out for the HI concentration from HIx (HI: $H_2O$ : $I_2$ = 1 : 5 : 1) solution. The polymer electrolyte membrane and the activated carbon cloth were adopted as a cation exchange membrane and electrode, respectively. In order to evaluate the temperature effect about HI concentration in fixed molar ratio, three case of temperature were selected to $60^{\circ}C$, $90^{\circ}C$ and $120^{\circ}C$. The electro-osmosis coefficient and transport number of proton have been changed from 1.95 to 1.21 (mol/Faraday) and 0.91 to 0.76, respectively as temperature increase from $60^{\circ}C$ to $120^{\circ}C$. It can be realized that the HI mole fraction in final stage of EED experiments already over the quasi-azeotrope composition.

Decomposition of Aromatic Organic Solvents with Catalytic Oxidation in SC-CO2 (초임계 이산화탄소내 촉매산화분해에 의한 방향족 유기용매의 분해특성)

  • Lee, Seung Bum;Hong, In Kwon
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.624-628
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    • 1998
  • The aromatic organic solvents(BTX) were decomposed in the fixed bed reactor packed with a 0.5% $Pt/{\gamma}-Al_2O_3$ catalyst, then, supercritical carbon dioxide(SC-$CO_2$) was used as the reaction media. And the conversion was dependent on the inlet concentration of BTX and the molar density of SC-$CO_2$. The conversion of BTX was decreased with increasing of inlet concentration, and was increased with temperature and pressure. The maximum conversion of benzene was 98.5% at $300^{\circ}C$ and 204.1 atm, and that of toluene and xylene were 82.0 and 76.5%, respectively, at $350^{\circ}C$ and 204.1 atm. The intermediate products of partial oxidation were identified as benzaldehyde, phenol, benzenemethanol, and so on. The BTX can be effectively converted into harmless $CO_2$ and $H_2O$ at appropriate operating condition. Thus, the nontoxic recovery process was suggested as the removal method of BTX.

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Characterisation and Co-pyrolytic Degradation of the Sawdust and Waste Tyre Blends to Study the Effect of Temperature on the Yield of the Products

  • Shazali, Erna Rashidah Hj;Morni, Nurul Afiqah Haji;Bakar, Muhammad Saifullah Abu;Ahmed, Ashfaq;Azad, Abul K;Phusunti, Neeranuch;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.32 no.2
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    • pp.205-213
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    • 2021
  • The present study aimed to determine the effect of co-pyrolysis of sawdust biomass and scrap tyre waste employing different blending ratios of sawdust to waste tyre such as 100:0, 75:25, 50:50, 25:75, and 0:100. The thermochemical characterization of feedstocks was carried out by employing the proximate, ultimate analysis, and thermogravimetric (TGA) analyses, calorific values, and scanning electron microscope coupled with energy dispersive x-ray analysis (SEM-EDX) to select the blending ratio having better bioenergy potential amongst the studied ratios. The blending ratio of 25:75 (sawdust to waste tyre) was selected for the co-pyrolysis study in a fixed-bed pyrolysis reactor system based on its solid biofuels properties such as heating value (30.18 MJ/kg), and carbon (71.81 wt%) and volatile matter (63.82 wt%) contents. The pyrolysis temperatures were varied as 500, 600 and 700 ℃ while the other parameters such as heating rate and nitrogen flowrate were maintained at 30 ℃/min and 0.5 L/min respectively. The bio-oil yields as 31.9, 47.1 and 61.2 wt%, bio-char yields as 34.5, 34.2 and 31.4 wt% and gaseous product yields as 33.6, 18.60 and 7.3 wt% at the pyrolysis temperatures of 500, 600 and 700 ℃ respectively were obtained. The blends of sawdust and waste tyres showed the improved energy characteristics which could provide the solution for the beneficial management of sawdust and scrape tyre wastes via co-pyrolysis processing.

Combustion Characteristics and the Modeling of Ionized Methane for Battery Fires (배터리화재를 모사한 이온화 메탄의 연소특성 및 모델링)

  • Ko, Hyuk-Ju;Lee, Eui-Ju
    • Fire Science and Engineering
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    • v.33 no.1
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    • pp.23-29
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    • 2019
  • Rechargeable battery such as lithium-ion battery has been noticed as a kinds of the energy storage system in the recent energy utilization and widely used actually in various small electronic equipment and electric vehicles. However, many thermal runaway caused battery accidents occurred recently, which still is obstacle for advanced application of lithium ion battery. One of the main differences to general fires is the existence of ionized electrolyte with electron during combustion. Therefore, we simply simulated the ion addition effects of battery fires by introducing an ionized fuel in jet diffusion flames. When the ionized methane through a corona discharge was used as fuel, the overall flame stability and shape such as flame length showed no significant difference from normal methane flame, but NOx and CO emissions measured at the post flame region decreased. The ion addition effect of methane oxidation was also numerically simulated with the modeling of hydrogen addition in the mixture. It was confirmed that the hydrogen addition at a fixed temperature had a similar effects on ionization of methane and hence could be modeled successfully.