• Title/Summary/Keyword: fixed carbon

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Effects of Microwave Irradiation on the Composition of Swine Manure and Crystallization of MAP (극초단파 조사가 돈분뇨의 성상과 MAP 결정화 반응에 미치는 영향)

  • Cho, Joon-Hee;Ra, Chang-Six
    • Journal of Animal Science and Technology
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    • v.51 no.1
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    • pp.75-80
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    • 2009
  • Composition changes of swine manure and the effects on MAP ($MgNH_4PO_46H_2O$) crystallization by microwave irradiation were examined. The concentration of ${PO_4}^{3-}$ was increased within a fixed period of time and then decreased, but $NH_4$-N was reduced continuously during microwave irradiation. Concentration of ${PO_4}^{3-}$ was started to reduce just from the point of foam formation during microwave irradiation, and the temperature at that time was always $49^{\circ}C$ irrespectively to microwave irradiation rate. Inorganic carbon was reduced with microwave irradiation, but soluble organic carbon (TOCs) was increased proportionally. Crystallization rate under conditions of non-microwave irradiation, irradiation up to $93^{\circ}C$ and $48^{\circ}C$ was 87.8%, 87.3% and 98.5%, respectively, showing 10% enhancement when irradiated up to $48^{\circ}C$. However, removal efficiency of ammonia nitrogen was proportional to the microwave irradiation rate or duration, obtaining 2.5%, 4.5% and 10.2%, respectively. Based on these results, it would be a useful strategy to irradiate microwave up to $49^{\circ}C$ to enhance MAP crystallization rate by changing the ionic pattern of nutrients in the manure. Meanwhile, provision of enough microwave irradiation rate might be needed to achieve high $NH_4$-N removal.

Stepwise Production of Syngas and Hydrogen from Methane on Ferrite Based Media Added with YSZ (YSZ 첨가 페라이트 매체상에서 메탄으로부터 합성 가스 및 수소의 단계적 생산)

  • Je, Han-Sol;Cha, Kwang-Seo;Kim, Hong-Soon;Lee, Young-Seak;Park, Chu-Sik;Kim, Young-Ho
    • Journal of Hydrogen and New Energy
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    • v.21 no.1
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    • pp.50-57
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    • 2010
  • Stepwise production of syn-gas and hydrogen from methane on ferrite based media added with yttria-stabilized zirconia (YSZ) was carried out using a fixed bed infrared reactor. In this study, all M-ferrite (M=Co, Cu, Mn and Ni) media were prepared by co-precipitation method, and there the YSZ was added as a binder to improve thermal stability, reactivity, and resistance against carbon deposition. Most of the ferrite media containing YSZ showed the good redox property for temperature programmed reduction/oxidation (TPR/O) tests. Notably, the Cu-substituted ferrite medium with YSZ showed the great resistance against carbon deposition as well as the good reactivity for the stepwise production of syngas and hydrogen. Furthermore, it also showed the good durability without significant deactivation during five repeated cyclic tests.

Development and Evaluation of Smart Foundation with Heating Devices (발열장치를 이용한 보온 기능성 스마트 파운데이션의 개발 및 평가)

  • Hwang, Young-Mi;Lee, Jeong-Ran
    • Fashion & Textile Research Journal
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    • v.15 no.2
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    • pp.231-239
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    • 2013
  • This research developed a smart girdle for adult women in their 20's that has an inserted carbon weaving heater to help with relief from coldness and abdominal disease through the thermal insulation effect. A pocket of powernet fabric was attached to the inside of the girdle for the easy insertion and separation of the heating device, while the heating device was fixed to a mesh material by cotton yarn and was wrapped with elastic lining material to prevent the mechanical devices from being exposed. A set of 3 hooks was attached to the center of the back of the heating device in consideration of convenience and mobility. Whereas the switch was inserted into around the right waistband, and the battery into the inner pocket around the waist, to integrate the heating device with the girdle. The satisfaction and usability of the fabricated smart girdle was verified by having research participants wear it to evaluate the appearance change caused by the device, the inconvenience of wearing/unwearing, mobility, and the satisfactory functionality of the device. As a result, the grand mean was evaluated to be high, with appearance (4.19), mobility (4.17), and functionality (4.51) being higher than 4.00; which indicates that the heat generation function of the smart girdle is effective. It may be said that such collection and analysis of data that reflect users' opinions have value and significance in that they can be grafted onto future research on new technology as well as they contribute to taking a step forward in the rapidly increasing research of smart clothing, with the new-type clothing equipped with new function.

Recovery of manganese compounds from electric arc furnace dust by Aluminothermy Process (테르밋 반응을 이용한 페로망간 전기로 분진의 재활용에 관한 연구)

  • Ha, Tae-Young;Jo, Young-Min;Park, Young-Koo;Kim, Youn-Che
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.23-30
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    • 2015
  • The properties of dust collected from electric arc furnace of ferro manganese production units was investigated, and also the metallic manganese was recovered from the dust by aluminothermy process. The ferromanganese dust collected from electric arc furnace contained about 15% of manganese oxide ($Mn_3O_4$) and 9% of carbon as the contaminant, and have a 5um of 50% median diameter and irregular particle shape. The carbon contaminant in the dust could be reduced until about 0.1~0.5% level by roasting in the air at a temperature of 600~900C for 60minutes. The recovery of manganese could not be carried out using only ferromanganese dust from electric arc furnace by aluminothermy process, but the ferromanganese which contained manganese of about 92% and iron of about 5% could be obtained from the mixture of ferromanganese dusts from electric arc furnace and converter. The best mixing condition of dust fixed at electric arc furnace dust / converter dust ratio of 1:9 and 2:8, and the mixing rato of 3:7 or more could not separated the metal and slag from the reactant after aluminothermy reaction.

The Effect of Carrier in CO2 Reforming of CH4 to Syngas over Ni-based catalysts

  • Seo, Ho Joon;Kang, Ung Il;Yu, Eui Yeon
    • Clean Technology
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    • v.5 no.2
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    • pp.63-68
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    • 1999
  • The activities of Ni(20wt%)/$La_2O_3$, Ni(20wt%)/${\gamma}-Al_2O_3$, and Ni(20wt%)/$SiO_2$ catalyst for $CO_2$ reforming of $CH_4$ were investigated in a fixed bed flow reactor under atmospheric condition. Catalyst characterization using XRD, TEM, SEM, BET analysis were also conducted. The catalytic activity of Ni(20wt%)/$La_2O_3$ catalyst has relatively superior to that of Ni(20wt%)/${\gamma}-Al_2O_3$ and Ni(20wt%)/$SiO_2$ catalyst. The good activity of Ni(20wt%)/$La_2O_3$ catalyst seems to depend on reduced $Ni^{\circ}$ phases of NiO($\rightarrow$ Ni + O), $LaNiO_3$($\rightarrow$ $Ni+La_2O_3$), Ni crystalline phases, and decoration of Ni phases by lanthanum species is also an important factor. Ni(20wt%)/${\gamma}-Al_2O_3$ and Ni(20wt%)/$SiO_2$ catalyst due to surface acidity resulted in the deposition of wisker type and encapsulate carbon on the surface of catalyst, but Ni(20wt%)/$La_2O_3$ catalyst did not show carbon on the surface of catalyst up to 8.5hr reaction.

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The Technology for On-line Measurement of Coal Properties by using Near-Infrared (근적외선을 이용한 온라인 석탄 성상분석 방법)

  • Kim, Dong-Won;Lee, Jong-Min;Kim, Jae-Sung;Kim, Hak-Jong
    • Korean Chemical Engineering Research
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    • v.45 no.6
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    • pp.596-603
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    • 2007
  • Rapid or on-line coal analysis is of great interest in coal industry as it would allow efficient plant operation. Multivariate analysis has been applied to near-infrared(NIR) spectra coal for investigating the relationship between coal properties(%) (moisture, ash, volatile matter, fixed carbon, carbon, hydrogen, nitrogen, oxygen, sulfur), heating value(kcal/kg) and corresponding near-infrared spectral data. The quantitative analysis was carried out by applying PLS(partial least squares regression) to determine a methodology able to establish a relationship between coal properties and NIR spectral data being applied mathematical pre-treatments for minimizing the physical features of the samples. As a results of the analysis, this technique is able to classify the species of coals and to predict the all coal properties except ash, nitrogen and sulfur. The efficient operation of coal fired power plant is expected owing to real time on-line coal analysis of moisture and heating value.

Characterization of Fe-ACF/$TiO_2$ composite Photocatalysts Effect Via Degradation of MB Solution (Fe-ACF/$TiO_2$ 복합체의 특성과 MB용액의 분해에서 포토-펜톤 효과)

  • Zhang, Kan;Meng, Ze-Da;Ko, Weon-Bae;Oh, Won-Chun
    • Elastomers and Composites
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    • v.44 no.3
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    • pp.290-298
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    • 2009
  • In this paper, the Fe-activated carbon fiber (ACF)/$TiO_2$ composite catalysts were prepared by a sol-gel method. The synthesized photocatalysts were used for the photo degradation of Methylene blue solution under UV light. From Brunauer-Emmett-Teller measurements (BET) data, it was shown the blocking of the micropores on the surface of ACF by treatment of Fe and Ti compound. As shown in SEM images, the ferric compounds and titanium dioxides were fixed onto the ACF surfaces. The result of X-ray powder diffraction showed that the crystal phase contained a mixing anatase and rutile structure and the 'FeO+$TiO_2$' from the composites. The EDX spectra for the elemental analysis showed the presence of C, O, and Ti with Fe peaks. Degradation activity of MB could be attributed to +OH radicals derived from electron/hole pair's reactions due to photolysis of $TiO_2$ and photo-Fenton effect of Fe.

Steam Gasification Characteristics of Oil Sand Coke in a Lab-Scale Fixed Bed Gasifier (실험실 규모의 고정층 가스화기에서 오일샌드 코크스의 수증기 가스화 특성)

  • Yoon, Sang Jun;Choi, Young-Chan;Lee, See-Hoon;Lee, Jae Goo
    • Applied Chemistry for Engineering
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    • v.20 no.1
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    • pp.62-66
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    • 2009
  • Utilization and interest of unconventional fuel and process residue such as oil sand and its residue, oil sand coke, have been increased because of the continuous rise of fuel price and conventional fuel availability. In this study, the gasification of oil sand coke produced from coking process of oil sand was performed to utilize as an energy resource using lab-scale fixed bed gasification system. The combustion characteristics of oil sand bitumen and oil sand coke were investigated by using TGA and lab-scale gasification system was applied to reveal the characteristics of produced syngas composition with oxygen/fuel ratio, temperature and steam injection rate. Oil sand coke shows a high carbon content, heating value and sulfur content and low ash content and reactivity. In case of oil sand coke gasification, generally with increasing temperature, the amount of steam introduced and decreasing oxygen injection rate, $H_2$ content in product gas increased while the $CO_2$ content decreased. The calorific value of syngas shows about $2100kcal/Nm^3$ and this result indicates that the oil sand coke can be used as a resource of hydrogen and fuel.

Removal of a High Load of Ammonia by a Marine Bacterium, Vibrio alginolyticus in Biofilter

  • Kim, Nam-Jin;Shoda, Makoto
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.7 no.5
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    • pp.316-322
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    • 2002
  • A newly isolated heterotrophic marine bacterium, Vibrio alginolyticus, was used to remove a high load of ammonia gas under non-sterile condition. The cells were inoculated onto an inorganic packing material in a fixed-bed reactor (biofilter), and a high load of ammonia, in the range of ammonia gas concentration of 170 ppm to 880 ppm, was introduced continuously. Sucrose solution and 3% NaCl was supplied intermittently to supplement the carbon source and water to the biofilter. The average percentage of gas removed exceeded 85% for 107-day operation. The maximum removal capacity and the complete removal capacity were$19\;g-N\;kg^{-1}$ dry packing material $day^{-1}$ and $16\;g-N\;kg^{-1}$ dry packing material $day^{-1}$, respectively, which were about three times greater than those obtained in nitrifying sludge inoculated onto the same packing material. On day 82, the enhanced pressure drop was restored to the normal one by NaOH treatment, and efficient removal characteristics were later observed. During this operation, the non-sterile condition had no significantly adverse effect on the removability of ammonia by V. alginolyticus.

Effects of Filler Types and Compositions on the Physical Properties of Chloroprene Rubber (충전제 종류 및 배합비가 클로로프렌고무의 물성에 미치는 영향)

  • Kim, Duk-Joon;Lee, Young-Kwan;Choi, Sang-Soon;Kim, Tae-Ho
    • Elastomers and Composites
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    • v.32 no.5
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    • pp.295-301
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    • 1997
  • The effects of filler types and compositions on the final properties such as tensile strength, % elongation, hardness, and specific gravity of chloroprene rubber were investigated. The fillers involved in this investigation were HAF-type carbon black, Mistron, and white clay, For each filler, the variation of filler compositions gave almost the linear effects on the all properties investigated. For a fixed filler composition, different filler types gave different influential strength on rubber properties. After linearlization of experimental data with respect to each filler composition, the simple linear addition of each property with respect to filler compositions was applied to predict the final properties of the filler included rubber systems. For the chloroprene rubber system including the fillers composed of Mistron(25phr)/HAF(20phr)/clay(35phr), the predicted properties were well in accordance with the experimental results. Similar results were obtained for other additives such as processing oil and accelerator.

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