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Stepwise Production of Syngas and Hydrogen from Methane on Ferrite Based Media Added with YSZ  

Je, Han-Sol (Dept. of Fine Chemical Engineering and Applied Chemistry, Chungnam National Univ.)
Cha, Kwang-Seo (Dept. of Fine Chemical Engineering and Applied Chemistry, Chungnam National Univ.)
Kim, Hong-Soon (Dept. of Fine Chemical Engineering and Applied Chemistry, Chungnam National Univ.)
Lee, Young-Seak (Dept. of Fine Chemical Engineering and Applied Chemistry, Chungnam National Univ.)
Park, Chu-Sik (Hydrogen Energy Research Group, Korea Institute of Energy Research)
Kim, Young-Ho (Dept. of Fine Chemical Engineering and Applied Chemistry, Chungnam National Univ.)
Publication Information
Transactions of the Korean hydrogen and new energy society / v.21, no.1, 2010 , pp. 50-57 More about this Journal
Abstract
Stepwise production of syn-gas and hydrogen from methane on ferrite based media added with yttria-stabilized zirconia (YSZ) was carried out using a fixed bed infrared reactor. In this study, all M-ferrite (M=Co, Cu, Mn and Ni) media were prepared by co-precipitation method, and there the YSZ was added as a binder to improve thermal stability, reactivity, and resistance against carbon deposition. Most of the ferrite media containing YSZ showed the good redox property for temperature programmed reduction/oxidation (TPR/O) tests. Notably, the Cu-substituted ferrite medium with YSZ showed the great resistance against carbon deposition as well as the good reactivity for the stepwise production of syngas and hydrogen. Furthermore, it also showed the good durability without significant deactivation during five repeated cyclic tests.
Keywords
Synthesis gas; Hydrogen; Stepwise production; Ferrite; YSZ(Yttria-stabilized zirconia); Thermochemical;
Citations & Related Records
Times Cited By KSCI : 5  (Citation Analysis)
연도 인용수 순위
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