• Title/Summary/Keyword: fire retardant chemicals

Search Result 33, Processing Time 0.081 seconds

Field Treatments of Small Diameter Logs Using Sap Displacement Method (I) - Feasibility of Treatment Using Transpiration Method and Butt-end Method - (수액치환법을 이용한 소경재의 산지처리(I) - 증산법과 원구법을 이용한 처리 가능성 -)

  • Chun, Su-Kyoung;Kim, Jae-Jin;Ra, Jong-Bum;Kim, Gyu-Hyeok
    • Journal of the Korean Wood Science and Technology
    • /
    • v.30 no.4
    • /
    • pp.58-65
    • /
    • 2002
  • This research was carried out to develop field treatment techniques of thinned small diameter softwood logs and less utilized hardwood logs using sap displacement method. In this paper, we report the feasibility of using transpiration method and butt-end method for the treatment of three softwood species and three hardwood species with preservatives, fire-retardant chemicals, and dimensional stabilizer. Butt-end method was effective as a field treatment technique compared to transpiration method when considered the treatability, easiness of treatment, productivity of treated wood, and environmental aspects related to chemical treatment, regardless of the combination of wood species and chemicals.

Redrying Fire - Retardant - Treated Structural Plywood (구조용(構造用) 내화처리(耐火處理) 합판(合板)의 재건조(再乾燥)에 관(關)한 연구(硏究))

  • Lee, Phil-Woo;Schaffer, E.L.
    • Journal of the Korean Wood Science and Technology
    • /
    • v.9 no.4
    • /
    • pp.1-21
    • /
    • 1981
  • Exterior grades of Douglas-fir and aspen plywood were impregnated with interior fire-retardant chemicals and redried under low-, intermediate-, and high-temperature drying conditions. Fire-retardant treatments included borax-boric acid, chromated zinc chloride, minalith, pyresote, and a commercial formulation. Drying processes included kiln and press-drying. Evaluated were drying rates and defects generated. The borax-boric acid and the commercial treatments redried at rates similar to water-treated controls. Other salt treatments were significantly slower drying and more defect prone. Chromated zinc chloride treatment was consistently the slowest drying and most defect prone. Press drying was three times faster at an equivalent temperature level. However, thickness shrinkage doubled because of 50 1b/in. platen pressure.

  • PDF

Studies on Press Drying of Fire-Retardant Treated Plywood (내화처리합판(耐火處理合板)의 열판건조(熱板乾燥)에 관(關)한 연구(硏究))

  • Kim, Jong Man
    • Journal of Korean Society of Forest Science
    • /
    • v.56 no.1
    • /
    • pp.1-25
    • /
    • 1982
  • Plywood used for construction as a decorative inner material is inflammable and can cause fire accidents. causing destruction of human life and property. To diminish the fire disaster, fire retardant plywood is indeed required. In the methods of manufacturing the fire retardant plywood, a soaking method is occasionally used. However after soaking plywood into fire retardant chemical solutions redrying of soaked plywood is of the utmost importance. In this study 3.5mm and 5.0mm thickness plywoods were selected for fire retardant treatment. Treating solutions were prepared for 20% dilute solutions of ammonium sulfate, monoammonium phosphate, diammonium phosphate, borax-boric acid minalith, and water solution, 1-, 3-, 6-, and 9 hour-soaking treatments in borax-boric acid and minalith, and 6- and 9 hours in the other chemicals were applied and after the treatment hot drying was applied to treated plywoods at $90^{\circ}C$, $120^{\circ}C$ and $150^{\circ}C$ of press temperature. Drying rates, drying curves, water absorption rates of fire retardant chemicals, weight per volume and fire retardant degree of plywood were investigated. The results may be summarized as follows: 1) In the 9 hours-soaking treatment of fire retardants by hot and cold bath method, the chemical retentions of 3.5mm thickness plywood could be attained within the range ($1.125-2.25kg/(30cm)^3$) of minimum retention specification as follows: $1.353kg/(30cm)^3$ in monoammonium phosphate, $1.331kg/(30cm)^3$ in diammonium phosphate, $1.263kg/(30cm)^3$ in ammonium sulfate, $1.226kg/(30cm)^3$ in borax-boric acid. But the chemical retention, $0.906kg/(30cm)^3$, in minalith could not be attained within the range of minimum retention specification. And also in case of 5.0mm thickness plywood, chemical retentions, as $1.356kg/(30cm)^3$ and $1.166kg/(30cm)^3$ respectively, of ammonium sulfate and diammonium phosphate could be attained within the range minimum retention specification, but the other fire retardant chemicals could not. 2) In the 6- and - hours-soaking treatments of 3.5mm and 5.0mm thickness plywood, the drying curve sloped of chemical treated plywood was smaller than that of water treated. The drying rate related to thickness of treated plywood, was about three times as fast in 3.5mm thickness plywood compared with 5.0mm thickness plywood. 3) In the treatment at $120^{\circ}C$ of hot platen temperature, the drying rates of chemical-treated plywood showed the highest quantity in diammonium phosphate of 3.5mm and 5.0mm thickness plywood. But the drying rate of water treated plywood was highest during the 6- and 9 hours-soaking treatments. 4) The drying rate remarkably increased with proportion to increase of the platen temperature, and the values were respectively 1.23%/min., 6.54%/min., 25.75%/min. in hot platen temperature of $90^{\circ}C$, $120^{\circ}C$, $150^{\circ}C$ in 3.5mm thickness plywood and 0.55%.min., 2.49%/min., 8.19%/min. in hot platen temperature of $90^{\circ}C$, $120^{\circ}C$, $150^{\circ}C$ in 5.0mm thickness plywood. 5) In the fire retardant degree of chemical treated plywood, the loss in weight was the smallest in diammonium phosphate, next was in monoammonium phosphate and ammonium sulfate, and the greatest was in borax-boric acid and minalith. And the fire-retardant effect in burning time, flame-exhausted time and carbonized area were greatest in diammouniun phosphate, next were in monoammonium phosphate and ammonium sulfate, and the weakest were in borax-boric acid and minalith.

  • PDF

The Cause of Whitening by Flame Retardants Treatment on Korean Wooden Cultural Heritage

  • Kim, Jin Qyu;Chung, Yong Jae;Lee, Hwa Soo;Seo, Hyun Jeong;Son, Dong Won;Han, Gyu-Seong
    • Journal of the Korean Wood Science and Technology
    • /
    • v.44 no.4
    • /
    • pp.589-599
    • /
    • 2016
  • Korean wooden cultural heritages are treated by flame retardants to protect fire hazards. Two types of flame retardants are used to treat wooden cultural heritage. These flame retardants cause some problems such as surface whitening, discoloration, and cracks due to the chemical reaction caused by Korean traditional wood painting (Dancheong), flame retardant and wood humidity. The Korean government is trying to cut down on the amount of flame retardants for the wooden cultural heritage because of these problems. This study was carried out to find the cause of whitening by flame retardants treatment. The reaction between pigment and flame retardant chemicals was analyzed by infrared spectroscopy.

Effect of fire - retardant treatment and redrying on the mechanical properties of radiata pine (내화처리(耐火處理) 및 재건조(再乾操)가 라디에타소나무의 역학적(力學的) 성질(性質)에 미치는 영향(影響))

  • Chung, Doo-Jin;Jo, Jae-Sung;Yun, Ki-Eon;Kim, Jae-Jin;Kim, Gyu-Hyeok
    • Journal of the Korean Wood Science and Technology
    • /
    • v.27 no.1
    • /
    • pp.37-49
    • /
    • 1999
  • The effect of fire-retardant treatment and redrying on the mechanical properties of radiata pine sapwood were evaluated. Small, clear specimens were treated with three different fire-retardant(FR) chemicals, borax-boric acid(BRX), minalith(MIN), and pyresote(PYR), with target retentions of 30 and 60kg/$m^3$, and then redried at maximum dry-bulb temperature of $25^{\circ}C$, $60^{\circ}C$, $80^{\circ}C$ or $110^{\circ}C$. Each specimen, including untreated and water-treated controls, was tested in static bending and in compression parallel to grain. The extent of strength reduction was dependent on the type of FR chemicals, retention, and redrying temperature, and a highly significant interaction existed between FR treatment and redrying temperature. Modulus of rupture(MOR) and work to maximum load(WML) were significantly decreased by FR treatment and redrying. None of three FR chemicals adversely affect modulus of elasticity (MOE) and maximum crushing strength(MCS). MOE of BRX treatment and MCS of both BRX and PYR treatment increased significantly compared to untreated controls. No significant differences existed between retention levels except for MOE and MCS of some combinations of FR chemicals and redrying temperatures. Although MOE and MCS was not significantly affected by any of the redrying temperatures, these properties were generally decreased with the increase in redrying temperature. The significant reduction in MOR and WML was observed in BRX treatment when dried at temperatures of $60^{\circ}C$ and above, and in MIN and PYR treatment when dried at temperatures of $80^{\circ}C$ and above. Consequently, BRX-treated radiata pine should not be redried at temperatures >$60^{\circ}C$, and MIN- and PYR-treated radiata pine should not be redried at temperatures > $80^{\circ}C$ where bending strength and energy-related properties are important design considerations.

  • PDF

Micromorphological Characteristics of Buddhist Temple Woods Treated with Eire-retardant (방염 처리 고목재의 미생물 분해의 미시형태적 특징)

  • Wi, Seung Gon;Kim, Ik-Joo;Park, Young Man;Kim, Yoon Soo
    • 한국문화재보존과학회:학술대회논문집
    • /
    • 2001.11a
    • /
    • pp.27-34
    • /
    • 2001
  • Following the recommendations made by the cultural authorities the wooden cultural properties (WCP) had been treated with fire-retardants for fire protection. However, visual inspections of some of the WCPs treated with fire-retardants showed microbial decay. The work was extended to examine the micromorphological characteristics of the WCPs in a Buddhist temple which had been treated with fire-retardant. Microscopic examination showed the presence of typical soft rot cavities along the length of microfibrils in the secondary wall. Bacterial attack was also observed by scanning and transmission electron microscopy. It is interesting that the decay patterns observed in the Buddhist temple were very similar to those observed in the waterlogged woods. Presumably chemicals in the fire-retardants used rendered the wood susceptible to attack by soft-rot and bacterial decay by causing an increase in the moisture content of wood. Further studies are needed to investigate the effect of fire-retardants used currently on the hygroscopicity and the strength of wood materials in the WCPs. Microbial attacks caused degradation of the secondary cell walls and in some cases also of the middle lamella. In addition, the cell walls in the outer parts of wood were also degraded due to weathering, and cell separation occurred from total disintegration of the middle lamella.

  • PDF

Studies on Fire-Retardant-Treatment and Press Drying of Plywood (합판(合板)의 내화처리(耐火處理)와 열판건조(熱板乾燥)에 관(關)한 연구(硏究))

  • Lee, Phil-Woo;Kim, Jong-Man
    • Journal of the Korean Wood Science and Technology
    • /
    • v.10 no.1
    • /
    • pp.5-37
    • /
    • 1982
  • Plywood used for construction as a decorative inner material is inflammable to bring large fire accidents and burn out human life and their properties. To diminish the fire disaster, fire retardant plywood has been required indeed. In the methods of manufacturing the fire retardant plywood the soaking method is occasionally used. However after soaking plywood into fire retardant chemical solutions, redrying of soaked plywood is the most important. In this study, 3.5mm thin and 5.0mm thick plywoods were selected for fire retardant treatment. Treating solutions were prepared for 20% dilute solutions of ammonium sulfate, monoammonium phosphate, diammonium phosphate, borax-boric acid and minalith, and water solution. 1-, 3-, 6-, and 9 hour-soaking treatments were applied and after treatments hot plate drying was applied to those treated plywoods at $90^{\circ}C$, $120^{\circ}C$ and $150^{\circ}C$, of press temperature. Drying rates, drying curves, water absorption rates of fire retardant chemicals, weight per volume and fire retardant degree of plywood were investigated. The results may be summarized as follows: 1. The plywoods treated with ammonium sulfate, monoammonium phosphate and diammonium phosphate and diammonium phosphate showed increase of chemical absorption rate with proportion to increase of treating time, but not in case of the plywood treated with borax-boric acid and minalith. 2. In the treatment of definite time, the absorption rate per unit of volume of plywood showed higher in thin plywood (thickness of 3.5mm) than in thick plywood (thickness of 5.0mm). In both thin and thick plywoods, the highest absorption rate was observed in 9 hour-treatment of ammonium sulfate. The value was 1.353kg/$(30cm)^3$ in thin plywood and 1.356kg/$(30cm)^3$ in thick plywood. 3. The volume per weight of plywood after chemical treatment increased remarkably and. after hot plate drying, the values were to a little extent higher than before chemical treatment. 4. The swelling rates of thickness in chemical-treated plywoods increased similarly with that of water-treated plywood in 1- and 3 hour-treatment of both thin and thick plywoods. But in 6- and 9 hour-treatment, the greater increased value showed in water-treated ply wood than any other chemical, especially in thick plywood. 5. The shrinkage rates after hot plate drying showed the same tendency as the swelling rate, and the rate showed the increasing tendency with proportion to increase of treating time in thick plywood of both chemical and water treatments. 6. Among drying curves, the curves of water-treated plywood placed more highly than chemical-treated plywood without-relation to thickness in 6- and 9 hour-treatment except in 1- and 3 hour-treatment. 7. The drying rate related to thickness of treated plywood, was twice above in thin plywood compared with thick plywood. 8. The drying rate remarkably increased with proportion to increase of the plate temperature and, the values were respectively 1.226%/min., 6.540%/min., 25.752%/min. in hot plate temperature of $90^{\circ}C$, $120^{\circ}C$, $150^{\circ}C$ in thin plywood and 0.550%/min., 2.490%/min, 8.187%/min, in hot plate temperature of $90^{\circ}C$, $120^{\circ}C$, $150^{\circ}C$ in thick plywood. 9. In the treatment at $120^{\circ}C$ of hot plate temperature, the drying rates of chemical-treated plywood showed the highest value in monoammonium phosphate of thin plywood and in diammonium phosphate of thick plywood. But the drying rate of water-treated plywood was highest in 6- and 9 hour-treatment. 10. The fire retardant degree of chemical-treated plywood was higher than that of the untreated plywood as shown in loss of weight, burning time, flame-exhausted time and carbonized area. 11. The fire-retardant effect among fire retardant chemicals were the greatest in diammonium phosphate, the next were in monoammonium phosphate and ammonium sulfate, and the weakest were in borax-boric and minalith.

  • PDF

Combustive Properties of Medium Density Fibreboards (MDF) Treated with Bis-(Dimethylaminomethyl) Phosphinic Acid and Alkylenediaminoalkyl-Bis-Phosphonic Acids (비스-디메틸아미노메틸 포스핀산과 알킬렌디아미노알킬-비스-포스폰산 유도체에 의해 처리된 중밀도 섬유판의 연소특성)

  • Park, Myung-Ho;Chung, Yeong-Jin
    • Fire Science and Engineering
    • /
    • v.28 no.5
    • /
    • pp.71-79
    • /
    • 2014
  • This study was performed to test the combustive properties of Medium Density Fibreboards (MDFs) treated with chemicals of the bis-(dimethylaminomethyl) phosphinic acid (DMDAP), N,N-dimethylethylenediaminomethyl-bis-phosphonic acid (DMDEDAP), piperazinomethyl-bis-phosphonic acid (PIPEABP), and methylpiperazinomethyl-bis-phosphonic acid (MPIPEABP). MDFs were painted in three times with 15 wt% solution of the bis-(dimethylaminomethyl) phosphinic acid and alkylenediaminoalkyl-bis-phosphonic acids at the room temperature, respectively. After drying MDF treated with chemicals, combustive properties and volatile organic compounds (VOCs) contents were examined by the cone calorimeter (ISO 5660-1), test for flame retardant (NEMA Notice No. 2012034), and gas chromatography (KS M ISO 11890-2), respectively. It was indicated that the MDFs treated with chemicals showed the longer time to combustion time (CT) = (442~492) s than that of virgin plate by reducing the burning rate except for CT treated with DMDAP. In adition, the MDFs treated with chemicals showed both of the higher char area (44.33~61.33) kg/kg and char length (10.33~11.67) cm than those of virgin plate. Especially, the MDFs treated with chemicals showed the higher mean volatile organic compounds (VOCs) (0.188~0.333) g/L than that of virgin plate within the prescribed limits. Thus, It is supposed that the combustion- retardation properties were improved by the partial due to the treated chemicals in the virgin MDF.

Flame Retardancy of Zelkova Sarrata Treated with Ammonium Salts (암모늄염으로 처리된 느티나무의 난연성 시험)

  • Chung, Yeong-Jin
    • Journal of the Korean Applied Science and Technology
    • /
    • v.27 no.4
    • /
    • pp.399-406
    • /
    • 2010
  • This study was performed to test the flame retardancy of zelkova sarrata-based materials by the treatment of ammonium salts. Zelkova sarrata plate was soaked by the treatment with three 20 wt% ammonium salt solutions consisting ammonium chloride (AMSL), monoammonium phosphate (MAPP), and diammonium phosphate (DAPP), respectively, at the room temperature. After the drying specimen treated with chemicals, combustion properties were examined by the cone calorimeter (ISO 5660-1). When the ammonium salts were used as the retardant for zelkova sarrata, the flame retardancy improved due to the treated ammonium salts in the virgin zelkova sarrata. However the specimen shows increasing CO over virgin zelkova sarrata and It is supposed that toxicities depend on extents. Also, the specimen with ammonium salts showed the higher total smoke release (TSR) than that of virgin plate. Of specimens treated with ammonium salts the ammonium chloride handled the test side was considered a improved inhibitory effect of combustion.

A Comparative Study on the Mechanical Properties of Plywood treated with Several Fire Retardant Chemicals (I) - Effect of Soaking Time on the Static Bending Strength of Treated Plywood - (수종(數種) 내화약제(耐火藥劑)로 처리(處理)된 합판(處理)의 기술적(技術的) 성질(性質)에 관(關)한 비교연구(比較硏究)(I) - 처리합판(處理處理)의 휨강도(强度)에 미치는 침지시간(浸漬時間)의 영향(影響) -)

  • Kim, Jong-Man;Chung, Woo-Yang;Lee, Phil-Woo
    • Journal of the Korean Wood Science and Technology
    • /
    • v.12 no.2
    • /
    • pp.20-26
    • /
    • 1984
  • This study was carried out to investigate the influence of chemical type and its retention in the fire-retardant treated plywoods on the static bending strength, a property peculiar to plywood. Being soaked in 20% aqueous solution of $(NH_4)_2SO_4$, $NH_4H_2PO_4$, $(NH_4)_2HPO_4$. Borax-Boric acid and Minalith for 3 to 12 hours at three-hour intervals and redried at $120^{\circ}C$ in hot press, the treated plywoods were put to static bending test. The values of chemical treated plywoods in Stress at proportional limit, Modulus of elasticity, Modulus of rupture and Work per unit volume to proportional limit were widely higher than those of water treated plywoods(control) and Borax-Boric acid treatment showed the highest value in the four mechanical data. And the bending strength of fire-retardant treated plywoods increased with the extension of soaking time or the increase of chemical retention in themselves. Borix-Boric acid was the desirable fire-retardant for thin plywood in view of mechanical strength and soaking defects in this study.

  • PDF