• Journal of the Korean Society of Safety
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• v.31 no.5
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• pp.42-48
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• 2016

The usage of the correct combustion properties of the treated substance for the safety of the process is critical. For the safe handling of n-nonane being used in various ways in the chemical industry, the flash point and the autoignition temperature(AIT) of n-nonane was experimented. And, the explosion limit of n-nonane was calculated by using the flash point obtained in the experiment. The flash points of n-nonane by using the Setaflash and Pensky-Martens closed-cup testers measured $31^{\circ}C$ and $34^{\circ}C$, respectively. The flash points of n-nonane by using the Tag and Cleveland open cup testers are measured $37^{\circ}C$ and $42^{\circ}C$. The AIT of n-nonane by ASTM 659E tester was measured as $210^{\circ}C$. The lower explosion limit by the measured flash point $31^{\circ}C$ was calculated as 0.87 vol%. And the upper explosion limit by the measured upper flash point $53^{\circ}C$ was calculated as 2.78 vol%. It was possible to predict lower explosion limit by using the experimental flash point or flash point in the literature.

• Journal of the Society of Disaster Information
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• v.15 no.4
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• pp.634-647
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• 2019

Purpose: Currently, many chemicals are used in industrial and real life, and many substances are used in the form of a single substance, but most of them are used in the form of a mixture, and there is a need for a criterion for judging the danger of these substances. Method: Therefore, this study aims to confirm the risk criteria of the mixture through experimental studies on flammable mixtures in order to secure the effectiveness of the details of the existing Dangerous Goods Safety Management Act angerous Goods Judgment Criteria and to ensure the reliability and reproducibility of the dangerous goods judgment. Result: Experimental results show that alcohol flash point is mixed with water, which is a non-flammable liquid. Similar flash point trends occurred around 60% on an alcohol basis. In addition, in the case of flammable-combustible mixtures, there was little change in flash point if the flash point difference of the two materials was not large, and if the flash point difference of the two materials was low, the flash point tended to increase with the increase of the high flash point material. Conclusion: In the future, the test results may provide reference data on the experimental criteria for the flammable liquids that are cracked at the fire site.

• Journal of the Korean Society of Safety
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• v.22 no.2 s.80
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• pp.47-52
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• 2007

The flash points and the fire points for the m-xylene+n-propionic acid and n-butanol+n-pentanol systems were measured by using Tag open-cup apparatus(AS1M D 1310-86). The experimental flash points of two binary systems were compared with the values calculated by the Raoult's law, Van Laar equation and Wilson equation. The calculated values based on the Raoult's law on m-xylene+n-propionic acid system were found to be better than those based on Van Laar and Wilson equations. The calculated values based on Van Laar equation on n-butanol+n-pentanol system were found to be better than those based on the Raoult's law and Wilson equation. The the fire points for the m-xylene+n-propionic acid system were about $7{\sim}8^{\circ}C$ above the flash points. In the case of n-butanol+n-pentanol system, the flash points and the fire points had been found to be identical.

• Fire Science and Engineering
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• v.11 no.4
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• pp.15-23
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• 1997

A series of measurements and visualization to investigate the extingushiment of water sprays with pool fires is presented. Fire source is a small-scale pool burner with methanol, ethanol and gasoline. Measurements of temperature, O2, CO2, and CO concentrations along the plume centerline are carried out to observe pool structures without water sprays. Visualization by the Ar-ion laser sheet flow pattern of droplets of the sprays above the pool fires. It is observed than in the case of methanol and ethanol, water sprays continuously penetrate into the center of fuel surfaces. The gasoline pool fire allows intermittent penetration of water sprays because of pulsating characteristics of the gasoline flame. To evaluate the cooling effect of the fuel surface by the sprays, the temperature was measured at the fuel surface. As soon as the mists reach the fuel surface of methanol and ethanol, the temperatures of the fuel surface decrease rapidly below the boiling point, and then the fires are extinguished. Due to the application of mist upon the gasoline fire, though the fuel temperature decrease abruptly at the time of the injection, such a repid decrease do not continue till the extinction point.

• Journal of the Korean Society of Safety
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• v.31 no.1
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• pp.61-65
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• 2016

In this study, we considered the ignition possibility for the shredded thermoplastic elastomer at the fire ground loaded the waste TPE. The average moisture content of the TPE sample was almost 0.33 wt.% at $110^{\circ}C$ and the range of ignition point was $461.9{\sim}491.9^{\circ}C$ approximately. In addition, we analyzed the change of weight and calorie the TPE sample according to temperature variations using the TG-DTA analyzer. As a result, the weight loss occurred twice in $250{\sim}420^{\circ}C$ and $420{\sim}473^{\circ}C$, and we found the second weight loss temperature range was the ignition point of TPE. Also, we conducted the spontaneous ignition tests of TPE for the wet and dry samples and we confirmed that the possibility of spontaneous ignition of TPE was very low. The elapsed time and humidity had little influence on the spontaneous ignition of TPE in this experimental conditions. In conclusion, the spontaneous of the shredded waste TPE in this study.

• Steel and Composite Structures
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• v.23 no.1
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• pp.53-66
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• 2017

Structures submitted to Fire-After-Earthquake loading situations, are first experiencing inelastic deformations due to the seismic action and are then submitted to the thermal loading. This means that in the case of steel framed structures, at the starting point of the fire, plastic hinges have already been formed at the ends of the beams. The basic objective of this paper is the evaluation of the rotational capacity of steel I-section beams damaged due to prior earthquake loading, at increased temperatures. The study is conducted numerically and three-dimensional models are used in order to capture accurately the nonlinear behaviour of the steel beams. Different levels of earthquake-induced damage are examined in order to study the effect of the initial state of damage to the temperature-evolution of the rotational capacity. The study starts with the reference case where the beam is undamaged and in the sequel cyclic loading patterns are taken into account, which represent earthquakes loads of increasing magnitude. Additionally, the study extends to the evaluation of the ultimate plastic rotation of the steel beams which corresponds to the point where the rotational capacity of the beam is exhausted. The aforementioned value of rotation can be used as a criterion for the determination of the fire-resistance time of the structure in case of Fire-After-Earthquake situations.

• Fire Science and Engineering
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• v.17 no.2
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• pp.50-55
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• 2003

The lower flash points for the binary system, n-butanol+n-decane, were measured by Pensky-Martens closed cup tester. The experimental results showed the minimum in the flash point versus composition curve. The experimental data were compared with the values calculated by the reduced model under an ideal solution assumption and the flash point-prediction models based on the Van Laar and Wilson equations. The predictive curve based upon the reduced model deviated form the experimental data for this system. The experimental results were in good agreement with the predictive curves, which use the Van Laar and Wilson equations to estimate activity coefficients. However, the predictive curve of the flash point prediction model based on the Willson equation described the experimentally-derived data more effectively than that of the flash point prediction model based on the Van Laar equation.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.6
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• pp.154-160
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• 2020

This study analyzed the fire intensity according to the zones classification between traditional market stores using FDS software. Modeling was conducted for the Seomoon traditional market district 4 at Daegu, which places combustibles, such as textiles and clothing near the passageway. The first ignition point assumed a short circuit fire situation at the fourth store combustible. The analysis was conducted under similar conditions as the fire situation in 2016. When there was no section wall, the fire spread rapidly through radiation in all directions from the fire-origin point. After 600 seconds, the mall was burnt to the ground. When section walls were present, however, the fire could be restricted inside the compartment. The first intensity of the two analysis conditions was predicted from the total heat energy from 200 seconds (X₁) to 600 seconds (X₂), where the heat generation rate began to increase rapidly. As a result of installing section walls near the fire point, heat energy generation of approximately 11.12 MW (55.68 %) was delayed. Further analysis of smoke control, according to the section wall arrangement and re-installation facilities, will be needed to study the characteristics of fire in traditional markets comprehensively.

• Journal of Korean Institute of Fire Investigation
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• v.11 no.1
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• pp.155-166
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• 2007

This study is to deduce problems and grope for its solution by investigating the general operation status about the present fire investigation in Korea. As for the problems, this study is to point out that they are application of diversion by the function of law for fire investigation, execution of individualized fire investigation by each institution, total lack of information sharing system for fire investigation, and weakness of cause investigation for arson. The reform measures are as follows: the unity of law for fire investigation, joint investigation by the related institutions, early introduction of civil fire investigation expert system, extension of special research institutes for fire investigation, introduction of system for sharing information of fire investigation, and operation of fire investigation team for cause investigation for arson.

• Proceedings of the SAREK Conference
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• 2007.11a
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• pp.352-357
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• 2007

The objective of this study is to find the optimal set-point of a hybrid Plant, which is combined by renewable energy plant of the GSHP(Ground Source Heat Pump) and the conventional plant(chiller, boiler). The work presented in this study was carried out by using the EnergyPlus(Version 2.0). In order to validate the simulation model, field data were measured from a building. The GSHP was used as a base plant and the conventional plant as the assistant plant. Various temperatures were controlled (zone summer set-point, zone winter set-point, chilled water temperature, hot water temperature) to find the optimal set-point temperature of the system. The influence of the various set-points were analyzed seasonally.