• Fire Science and Engineering
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• v.29 no.6
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• pp.20-25
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• 2015

In order to examine the explosion risk of 2-ethylhexanoic acid, we experimentally studied the explosion limit, explosion pressure, and rate of increase of the explosion pressure at different oxygen concentrations. The lower explosion limit was 3.2% at a temperature of $100^{\circ}C$, and the oxygen concentration was 40 to 70%. The upper explosion limit was 4.5% and the lower explosion limit was 4.0% at an oxygen concentration of 21%.The maximum explosion pressure of 2-ethylhexanoic acid was 1.4161 MPa at an oxygen concentration of 70%, and the rate of increase of the explosion pressure was 62.692 MPa/s at this concentration.

• Journal of the Korean Society of Safety
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• v.39 no.2
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• pp.9-21
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• 2024

Static-electricity-induced fires and explosions persistently occur every year, averaging approximately 80 and 20 cases annually according to fire statistics provided by the National Fire Agency and industrial accident statistics provided by the Ministry of Employment and Labor, respectively. Despite the relatively low probabilities of these accidents, their potential risks are high. Consequently, effective risk assessment methodologies and accident investigation strategies are essential for efficiently managing static-electricity hazards in fire- and explosion-prone areas. Accordingly, this study aimed to identify the causal variables essential for accident investigations, thereby facilitating risk assessments and the implementation of effective recurrence prevention measures to mitigate static-electricity hazards in fire-and explosion-prone regions. To this end, industrial accident statistics recorded over the past decade (2012 to 2021) by the Ministry of Employment and Labor were analyzed to identify major fire and explosion incidents and related industrial accidents wherein static electricity was identified as a potential ignition source. Subsequently, relevant investigation reports (63 cases) were thoroughly analyzed. Based on the results of this analysis, existing electrostatic fire and explosion risk assessment techniques were refined and augmented. Moreover, factors essential for investigating electrostatic fire and explosion disasters were delineated, and the primary causal variables necessary for effective risk assessments and scientific investigations were derived.

• Journal of the Korean Society of Safety
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• v.19 no.4 s.68
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• pp.150-154
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• 2004

Gas explosion characteristics of hydrogen and liquefied petroleum gas(LPG) were measured in 6L cylindrical vessel, and experiment for explosion to fire transition phenomena of the gases were carried out using the 270L vessel. Explosion characteristics were measured using the stain type pressure transducer and explosion to fire transition phenomena was analyzed with the hish-speed camera. Base on the experiment, it was found that explosion pressure was most high slightly above the stoichiometric concentration, and explosion pressure rise rate and flame propagation velocity were proportional to the combustion velocity. And we find that those kind of explosion characteristics affect the explosion-to-fire transition, in addition, explosion flame temperature, flame residence time, are important parameters in explosion-to-fire transition.

• Fire Science and Engineering
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• v.24 no.3
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• pp.66-71
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• 2010

In order to evaluate the fire and explosion involved and to ensure the safe and optimized operation of chemical processes, it is necessary to know combustion properties. Explosion limit is one of the major combustion properties used to determine the fire and explosion hazards of the flammable substances. In this study, the lower explosion and upper explosion limits of esters were predicted by using the heat of combustion. The values calculated by the proposed equations agreed with literature data within a few percent. From the given results, using the proposed methodology, it is possible to predict the explosion limits of the other ester flammable substances.

• Fire Science and Engineering
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• v.31 no.4
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• pp.119-127
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• 2017

This study analyzed the cause of car explosion that occurred in the riverside park. The car carrying a male driver and a female passenger was parked in the park and explosion occurred inside the car. After the explosion, the driver and the passenger got burned. When they went to the hospital by the 119 Rescue Service, they stated that the car was sprayed with thinner before they had a quarrel and the explosion occurred during their quarrel. However, after several days, they changed their statement. They said that gasoline in the plastic bottle was poured and ran into the cigarette lighter. They tried to pull the cigarette lighter but pushed it by mistake. Then explosion occurred. Because only the explosion by mistake could receive car insurance, whether the cause of explosion was intentional or not became an issue. The car exploded was carefully investigated and analyzed. The statement of the driver and passenger was analyzed in the aspect of fire science. As a result, it was demonstrated that this car explosion occurred by driver's intention.

• Journal of Ocean Engineering and Technology
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• v.37 no.3
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• pp.99-110
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• 2023

When a fire accident accompanied by an explosion occurs, the surrounding firewalls are affected by impact and thermal loads. Damaged firewalls due to accidental loads may not fully perform their essential function. Therefore, this paper proposes an advanced methodology for evaluating the fire resistance performance of firewalls damaged by explosions. The fragments were assumed to be scattered, and fire occurred as a vehicle exploded in a large compartment of a roll-on/roll-off (RO-RO) vessel. The impact velocity of the fragments was calculated based on the TNT equivalent mass corresponding to the explosion pressure. Damage and thermal-structural response analyses of the firewall were performed using Ansys LS-DYNA code. The fire resistance reduction was analyzed in terms of the temperature difference between fire-exposed and unexposed surfaces, temperature increase rate, and reference temperature arrival time. The degree of damage and the fire resistance performance of the firewalls varied significantly depending on impact loads. When naval ships and RO-RO vessels that carry various explosive substances are designed, it is reasonable to predict that the fire resistance performance will be degraded according to the explosion characteristics of the cargo.

• Journal of the Korean Society of Safety
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• v.8 no.4
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• pp.107-113
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• 1993

Small rectangular explosion chamber of its size 25cmX25cmX32cm with a circular bursting diaphram at the top was used to study the mechanism of gas explosion to fire transition phenomena, the process of ignition of solid combustibles during a gas explosion. To visulize the explosion to fire transition phenomena, transparent acryl window and high speed camera system were used. The test piece of solid combustible in this experiments was a 5cm$\times$5cm square sheet of newspaper which was placed in the explosion chamber filled with a LPG-air mixture. The mixture was ignited by an electric spark at the center of the chamber. Explosion to fire transition phenomena and the behavior of out flow and in flow of gas through the opening yielded by bursting the diaphram was visualized with shlieren system and without shlieren system. Diameter of a bursting dlaphram at the top of the explosion chamber was varied 5cm, 10cm, and 15cm, and the position of test piece were varied with 6 point. Explosion pressure was measured with strain type pressure transducer, and the weight difference of the test piece before and after each experimental run was measured. By comparing the weight difference of solid combustibles before and after the experiment and the behavior of out flow and inflow of gas after explosion, it was found that the possibility of ignition was depends on the LPG-air mixture concentration and the exposure period of test piece to the burnt gas. Test result of this experiments it was found that the main factor of this phenomena are that heat transfer to the test piece, and the pyrolysis reaction of test piece. Based on the results, the mechanism of the explosion to fire transition phenomena were inferred ; gas explosion- heat transfer to solid combustibiles ; pyrolysis reaction of solid combutibles : air inflow ; mixing of the pyroly gas with air ignition.

• Fire Science and Engineering
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• v.19 no.4 s.60
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• pp.26-31
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• 2005

In order to evaluate the fire and explosion involved and to ensure the safe and optimized operation of chemical processes, it is necessary to know combustion properties. Explosion limit is one of the major combustion properties used to determine the fire and explosion hazards of the flammable substances. In this study, the explosion limits of alcohols were predicted by using the normal boiling points and the flash points based on a solution theory. The values calculated by the proposed equations agreed with literature data within a few percent. From the given results, using the proposed methodology; it is Possible to Predict the explosion limits of the other flammable substances.

• Journal of the Korean Society of Combustion
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• v.20 no.1
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• pp.1-5
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• 2015

Fire and explosion analysis are performed for the quantitative risk assessment on the LNG test plant. From the analysis for a case of fire due to large leakage of LNG from the tank, it is obtained that loss of lives can be occurred within the radius of 60 m from the fire origin. Specially, wind can extend the extent of damage. Because the LNG test plant is not enclosed, the explosion overpressure is less than 6 kPa and the explosion has little effect on the integrity of the LNG test plant.

• Journal of the Korean Society of Safety
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• v.8 no.2
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• pp.58-63
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• 1993

Recently, a large amount of flammable or explosive materials have been handled or stored in chemical industries. H the equipments fail or the materials release in consequence of operation errors, fire and explosion could occur to them. Thus, risk assessment using quantification of risks is very important when design of processes and modifications of installed processes are performed. The purpose of this study is to develop the program for fire and explosion index in order to quantify the expected damage of fire and explosion incidents in chemical plants, to identify equipment that would be likely to contribute to the creation or escalation of an incident, to comunicate the potential fire and explosion risk to management and to account of damage cost.