• 제목/요약/키워드: fine silica

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Combined effect of fine aggregate and silica fume on properties of Portland cement pervious concrete

  • Zhang, Yuanbo;Zhang, Wuman;Zhang, Yingchen
    • Advances in concrete construction
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    • 제8권1호
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    • pp.47-54
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    • 2019
  • Portland cement pervious concrete has been expected to have good water permeability, mechanical properties and abrasion resistance at the same time when Portland cement pervious concrete is applied to the actual vehicle pavement. In this study, the coarse aggregate and cement were replaced by the fine aggregate and the silica fume to improve actual road performance Portland cement pervious concrete. The Mechanical properties, the water permeability and the abrasion resistance of Portland cement pervious concrete were investigated. The results show that the compressive strength, the flexural strength and the abrasion resistance are increased when the fine aggregate and the silica fume are added to Portland cement pervious concrete separately. However, the porosity and the water permeability are decreased simultaneously. With assistance of silica fume and fine aggregate simultaneously, Portland cement pervious concrete could achieve a higher strength. The compressive strength, the flexural strength and the abrasion resistance of Portland cement pervious concrete mixed with 5% fine aggregates and 8% silica fume are increased by 93.1%, 65% and 65.2%, respectively. The porosity and the water permeability are decreased by 22.4% and 85% when Portland cement pervious concrete is mixed with 5% fine aggregate and 8% silica fume. Therefore, the replacement ratio of the fine aggregates and the silica fume should be considered comprehensively and determined on the premise of ensuring the water permeability coefficient.

잔골재용 폐유리의 표면개질이 모르타르의 역학적 특성 및 알칼리 실리카 반응에 미치는 영향 (Effect of Surface Modification of Waste Glass for Fine Aggregate on the Mechanical Properties and Alkali Silica Reaction of Mortar)

  • 손민재;김규용;이상규;사수이;유하민;남정수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2020년도 가을 학술논문 발표대회
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    • pp.23-24
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    • 2020
  • In this study, effect of surface modification of waste glass for fine aggregates on the mechanical properties and alkali silica reaction of mortar was analyzed. As a result, it was confirmed that the incorporation of waste glass fine aggregate decreases the mechanical properties of the mortar and increase the alkali silica reaction expansion. On the other hand, the surface modification of the waste glass fine aggregate is effective in improving this problem. However, unlike green and brown waste glass, it is judged that an additional experiment to determine the cause is necessary for white waste glass where alkali silica reactive expansion occurs extremely.

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Titanized or Zirconized Porous Silica Modified with a Cellulose Derivative as New Chiral Stationary Phases

  • Seo, You-Jin;Kang, Gyoung-Won;Park, Seong-Tae;Moon, Myeong-Hee;Park, Jung-Hag;Cheong, Won-Jo
    • Bulletin of the Korean Chemical Society
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    • 제28권6호
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    • pp.999-1004
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    • 2007
  • Spherical porous silica supports modified with titanium or zirconium alkoxides were prepared, and allyl groups were chemically attached to the titanized or zirconized silica supports, and the product was cross-polymerized with a double bond containing cellulose derivative to yield new CSPs (chiral stationary phases). Magic angle spinning 13C solid state NMR and elemental analysis were used to characterize the CSPs. The performances of the chiral stationary phases were examined in comparison with a conventional chiral stationary phase. Spherical porous silica particles modified with 3,5-dimethylphenylcarbamate of cellulose were prepared and used as the conventional chiral stationary phase. Chromatographic data were collected for a few pairs of enantionmers in heptane/2-propanol mixed solvents of various compositions with the three chiral columns and the results were comparatively studied. The separation performance of the chrial phase made of the titanized silica was better than the others, and the separation performance of the chiral phase of the zirconized silica was comparable to that of the conventional chiral phase. The superiority of titanized silica over bare or zirconized silica in chiral separation seemed to be owing to the better yield of crosslinking (monitored by increase of carbon load) for titanized silica than for the others.

폐유리 잔골재가 고강도 모르타르의 역학적 특성 및 알칼리-실리카 반응(ASR), ASR 후, 잔류 역학적 특성에 미치는 영향 (Effect of Waste Glass Fine Aggregate on Mechanical Properites and Alkali-Silica Reaction(ASR), After ASR Residual Mechanical Properties of High Strength Mortar)

  • 유하민;김규용;손민재;사수이;이예찬;남정수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2020년도 가을 학술논문 발표대회
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    • pp.31-32
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    • 2020
  • This study measured the mechanical performance and residual strength of high strength/normal strength mortar mixed with waste glass fine aggregate after alkali-silica reaction and alkali-silica reaction. As a result, the effect of improving the slip phenomenon of the waste glass fine aggregate in the high-strength mortar was not significant, but rather the amount of ASR was increased.

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A New Stationary Phase Prepared from Ground Silica Monolith Particles by Reversible Addition-Fragmentation Chain Transfer Polymerization

  • Lee, Seung-Mi;Zaidi, Shabi Abbas;Cheong, Won-Jo
    • Bulletin of the Korean Chemical Society
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    • 제31권10호
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    • pp.2943-2948
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    • 2010
  • Silica monolith powders were prepared by a new procedure where ground powders of proper size distribution were obtained without sieving. An initiator was attached to this ground monolith and polystyrene was bound by reversible addition-fragmentation chain transfer polymerization to give a new stationary phase. The separation efficiency of this phase was found better than that of the polystyrene bound phase based on conventional silica particles and that of the C18 bound silica monolith powders.

폐유리 잔골재 대체율이 물시멘트비가 다른 모르타르의 역학적 특성 및 알칼리 -실리카 반응에 미치는 영향 - (Effect of the replacement rates of Waste Glass Fine Aggregate on the Mechanical Properties and Alkali - Silica Reaction of Mortars with different W/C Ratio -)

  • 유하민;김규용;남정수;손민재;사수이;이예찬
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2020년도 봄 학술논문 발표대회
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    • pp.195-196
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    • 2020
  • This study evaluated the mechanical properties and alkali silica reaction of mortar according to the mixing ratio of waste glass. As a result, as the mixing ratio of the waste glass increased, the compressive and flexible strength of the mortar decreased due to the slip of aggregate, and the alkali-silica reaction(ASR) increased. So, it is considered that research is needed to prevent slip and ASR of the waste glass aggregate in order to use the waste glass as a fine aggregate for concrete.

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그라프트 중합에 의해 만들어진 폴리아크릴아마이드-실리카 나노 입자의 특성 (The Characteristics of Poly(acrylamide)-SiOx Nanoparticles Prepared by Graft-polymerizaton)

  • 민준호;민성기
    • 공업화학
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    • 제21권1호
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    • pp.34-39
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    • 2010
  • ${\gamma}-Methacryloxypropyl$이 가진 기능성 그룹으로 silica nanoparticle의 유기변형은 silica의 표면개질로 성공적으로 준비했다. 또한 ethanol 용매에서 AAm을 사용하는 radical 침전중합을 통해서 polyacrylamide를 MPSN nanosphere에 'raft from'방법으로 microsphere가 성공적으로 graft중합되었다. FTIR과 XPS는 ultra-fine silica particle의 표면에서 실리카개질이 공유결합하는 것을 보여주며 SEM분석은 ultra-fine particle과 유기변형된 입자는 각각 25, 30, 35 nm의 크기로 응집작용을 효과적으로 막아주고 나누어줌을 증명할 수 있다는 것을 보여준다.

Preparation and Characterization of Spherical Silica-coated Ceria Nanoparticles by Sol-Gel Method

  • Ahn, Yang-Kyu;Jeoung, Hae-Chan
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
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    • pp.96-96
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    • 2010
  • Monodispersed spherical silica-coated ceria nanoparticles were prepared through a sol-gel process using tetraethylorthosilicate (TEOS) and ceria fine particles. In this process, ceria fine particles were also prepared from cerium nitrate. The mean size of ceria particles was 300nm. Silica nanoparticles with narrow particle size distribution were prepared by controlled hydrolysis of TEOS solution. The silica sols were obtained by peptization, the process of redispersing a coagulated colloid, and were coated on ceria particles by the control of the weight ratio of silica/ceria and the pH of the mixture in aqueous solution. The morphologies of particles were characterized with scaning electron microscopy(SEM), transmission electron microscopy(TEM) and atomic force microscopy(AFM). The coating thickness of silica particles obtained by using this method was controlled in the range of 30 - 70nm.

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