• Advances in concrete construction
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• v.8 no.1
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• pp.47-54
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• 2019

Portland cement pervious concrete has been expected to have good water permeability, mechanical properties and abrasion resistance at the same time when Portland cement pervious concrete is applied to the actual vehicle pavement. In this study, the coarse aggregate and cement were replaced by the fine aggregate and the silica fume to improve actual road performance Portland cement pervious concrete. The Mechanical properties, the water permeability and the abrasion resistance of Portland cement pervious concrete were investigated. The results show that the compressive strength, the flexural strength and the abrasion resistance are increased when the fine aggregate and the silica fume are added to Portland cement pervious concrete separately. However, the porosity and the water permeability are decreased simultaneously. With assistance of silica fume and fine aggregate simultaneously, Portland cement pervious concrete could achieve a higher strength. The compressive strength, the flexural strength and the abrasion resistance of Portland cement pervious concrete mixed with 5% fine aggregates and 8% silica fume are increased by 93.1%, 65% and 65.2%, respectively. The porosity and the water permeability are decreased by 22.4% and 85% when Portland cement pervious concrete is mixed with 5% fine aggregate and 8% silica fume. Therefore, the replacement ratio of the fine aggregates and the silica fume should be considered comprehensively and determined on the premise of ensuring the water permeability coefficient.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2020.11a
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• pp.23-24
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• 2020

In this study, effect of surface modification of waste glass for fine aggregates on the mechanical properties and alkali silica reaction of mortar was analyzed. As a result, it was confirmed that the incorporation of waste glass fine aggregate decreases the mechanical properties of the mortar and increase the alkali silica reaction expansion. On the other hand, the surface modification of the waste glass fine aggregate is effective in improving this problem. However, unlike green and brown waste glass, it is judged that an additional experiment to determine the cause is necessary for white waste glass where alkali silica reactive expansion occurs extremely.

• Bulletin of the Korean Chemical Society
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• v.30 no.3
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• pp.722-725
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• 2009

• Bulletin of the Korean Chemical Society
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• v.28 no.6
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• pp.999-1004
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• 2007

Spherical porous silica supports modified with titanium or zirconium alkoxides were prepared, and allyl groups were chemically attached to the titanized or zirconized silica supports, and the product was cross-polymerized with a double bond containing cellulose derivative to yield new CSPs (chiral stationary phases). Magic angle spinning 13C solid state NMR and elemental analysis were used to characterize the CSPs. The performances of the chiral stationary phases were examined in comparison with a conventional chiral stationary phase. Spherical porous silica particles modified with 3,5-dimethylphenylcarbamate of cellulose were prepared and used as the conventional chiral stationary phase. Chromatographic data were collected for a few pairs of enantionmers in heptane/2-propanol mixed solvents of various compositions with the three chiral columns and the results were comparatively studied. The separation performance of the chrial phase made of the titanized silica was better than the others, and the separation performance of the chiral phase of the zirconized silica was comparable to that of the conventional chiral phase. The superiority of titanized silica over bare or zirconized silica in chiral separation seemed to be owing to the better yield of crosslinking (monitored by increase of carbon load) for titanized silica than for the others.

• Bulletin of the Korean Chemical Society
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• v.30 no.12
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• pp.3127-3130
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• 2009

• Proceedings of the Korean Institute of Building Construction Conference
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• 2020.11a
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• pp.31-32
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• 2020

This study measured the mechanical performance and residual strength of high strength/normal strength mortar mixed with waste glass fine aggregate after alkali-silica reaction and alkali-silica reaction. As a result, the effect of improving the slip phenomenon of the waste glass fine aggregate in the high-strength mortar was not significant, but rather the amount of ASR was increased.

• Bulletin of the Korean Chemical Society
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• v.31 no.10
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• pp.2943-2948
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• 2010

Silica monolith powders were prepared by a new procedure where ground powders of proper size distribution were obtained without sieving. An initiator was attached to this ground monolith and polystyrene was bound by reversible addition-fragmentation chain transfer polymerization to give a new stationary phase. The separation efficiency of this phase was found better than that of the polystyrene bound phase based on conventional silica particles and that of the C18 bound silica monolith powders.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2020.06a
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• pp.195-196
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• 2020

This study evaluated the mechanical properties and alkali silica reaction of mortar according to the mixing ratio of waste glass. As a result, as the mixing ratio of the waste glass increased, the compressive and flexible strength of the mortar decreased due to the slip of aggregate, and the alkali-silica reaction(ASR) increased. So, it is considered that research is needed to prevent slip and ASR of the waste glass aggregate in order to use the waste glass as a fine aggregate for concrete.

• Applied Chemistry for Engineering
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• v.21 no.1
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• pp.34-39
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• 2010

Methacryloxypropyltrimethoxysilane (MPTMS) was used for the surface modification of silica nanoparticles in the toluene dispersion system for 8 h (MPSN). Then, methacryloxypropyl-modified silica nanoparticles were successfully prepared by solutioun polymerization in the ethanol solution at $60^{\circ}C$ for 14 h with adding AIBN initiator. The modification of ultra-fine particles (SiOx-PAA nanospheres) was investigated via EA, XPS, FTIR, TGA, SEM and TEM. The mean diameter of the bare silica nanoparticles, MPSN and SiOx-PAA monodisperse nanoparticles was about 25, 30 and 35 nm, respectively.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.96-96
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• 2010

Monodispersed spherical silica-coated ceria nanoparticles were prepared through a sol-gel process using tetraethylorthosilicate (TEOS) and ceria fine particles. In this process, ceria fine particles were also prepared from cerium nitrate. The mean size of ceria particles was 300nm. Silica nanoparticles with narrow particle size distribution were prepared by controlled hydrolysis of TEOS solution. The silica sols were obtained by peptization, the process of redispersing a coagulated colloid, and were coated on ceria particles by the control of the weight ratio of silica/ceria and the pH of the mixture in aqueous solution. The morphologies of particles were characterized with scaning electron microscopy(SEM), transmission electron microscopy(TEM) and atomic force microscopy(AFM). The coating thickness of silica particles obtained by using this method was controlled in the range of 30 - 70nm.