• Title/Summary/Keyword: fine dispersion

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Synthesis of Gold Nanoparticles by Chemical Reduction Method for Direct Ink Writing

  • Cho, Young-Sang;Son, Soo-Jung;Kim, Young-Kuk;Chung, Kook-Chae;Choi, Chul-Jin
    • Journal of Powder Materials
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    • v.17 no.5
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    • pp.390-398
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    • 2010
  • Aqueous gold nanoparticle dispersion was synthesized by chemical reduction method using diethanolamine as reducing agent and polyethyleneimine as dispersion stabilizer. The synthesis conditions for the stable dispersion of the gold nanoparticle suspension were determined by changing the amount of the reducing agent and dispersant during the wet chemical synthesis procedures. The face centered cubic lattice structure of the gold nanoparticles was confirmed by using X-ray diffraction and the morphologies of the nanoparticles were observed by transmission electron microscope. The synthesized gold nanoparticle dispersion was concentrated by evaporating the dispersion medium at room temperature followed by the addition of ethyleneglycol as humectant for the increase of the elastic properties to obtain gold nanoparticle inks for direct ink writing process. The line patterns were obtained with the gold nanoparticle inks during the writing procedures and the morphologies of the fine patterns were observed by scanning electron microscope.

Numerical Investigation of an Unconditionally Stable Compact 2D FDTD Based on the Alternating-Direction Implicit Scheme

  • Saehoon Ju;Jeongnam Cheon;Kim, Hyung-Hoon;Kim, Hyeongdong
    • Journal of electromagnetic engineering and science
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    • v.3 no.1
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    • pp.39-44
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    • 2003
  • An unconditionally stable compact 2D Alternating-Direction Implicit (ADI) FDTD method for calculating dispersion characteristics of waveguide structures is proposed. The numerical stability and numerical dispersion relation of the proposed method are also presented and discussed. Numerical wavelengths for the dominant and higher order modes in a hollow waveguide are obtained from numerical simulations and compared with those from the analytical dispersion relation. The numerical results show that the proposed scheme has the potential to successfully analyze a class of waveguides having locally fine geometry with reduced numerical costs.

Fine Powder Preparation in the System of $(1-x)ZrO_2-xMgO$ ($(1-x)ZrO_2-xMgO$ 계의 미세입자 원료분말의 제조)

  • 안영필;김복희;성상현;정복환;이응상
    • Journal of the Korean Ceramic Society
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    • v.22 no.5
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    • pp.17-22
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    • 1985
  • This study was to make powder by coprecipitation method and spray dispersion precipitation method in $(1-x)ZrO_2-xMgO$ system to improve sinterability. As the result the specific surface area of powder prepared by spray dispersion precipitation method and coprecipitation method was above $110m^2/g$ and $10-20m^2/g$ respectively. Spray dispersion precipitation method was more effective than coprecipitation method in powder preparation.

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Influence of Fluoro-illite on Flame Retardant Property of Epoxy Complex (에폭시 복합체의 난연 특성에 미치는 불소화 일라이트의 영향)

  • Yu, Hye-Ryeon;Jeong, Eui-Gyung;Kim, Jin-Hoon;Lee, Young-Seak
    • Polymer(Korea)
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    • v.35 no.1
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    • pp.47-51
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    • 2011
  • In this study, illite, an environmental friendly, low cost, and high aspect ratio additive, was used to improve flame retardant property of epoxy and it was fluorinated to enhance dispersion of hydrophilic illite in hydrophobic epoxy by introducing hydrophobic functional groups. Fluorination of illite enhanced illite dispersion ill epoxy solution before curing and that in the complex after curing. These enhanced dispersions were attributed to the increased affinity of illite to hydrophobic epoxy solution induced by fluorination of illite and the increased intercalation of epoxy polymer or exfoliation of illite by epoxy curing. Hence, limited oxygen index(LOI) of fluorinated illite/epoxy complex increased by 24%, compared to that of epoxy, suggesting that the preparation of fluorinated illite/epoxy complex increased their flame retardant properties.

Microstructure and Mechanical Properties of Al2O3/Fe-Ni Nanocomposite Prepared by Rapid Sintering (급속소결에 의해 제조된 Al2O3/Fe-Ni 나노복합재료의 미세조직 및 기계적 특성)

  • Lee, Young-In;Lee, Kun-Jae;Jang, Dae-Hwan;Yang, Jae-Kyo;Cho, Yong-Ho
    • Journal of Powder Materials
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    • v.17 no.3
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    • pp.203-208
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    • 2010
  • A new High Frequency Induction Heating (HFIH) process has been developed to fabricate dense $Al_2O_3$ reinforced with Fe-Ni magnetic metal dispersion particles. The process is based on the reduction of metal oxide particles immediately prior to sintering. The synthesized $Al_2O_3$/Fe-Ni nanocomposite powders were formed directly from the selective reduction of metal oxide powders, such as NiO and $Fe_2O_3$. Dense $Al_2O_3$/Fe-Ni nanocomposite was fabricated using the HFIH method with an extremely high heating rate of $2000^{\circ}C/min$. Phase identification and microstructure of nanocomposite powders and sintered specimens were determined by X-ray diffraction and SEM and TEM, respectively. Vickers hardness experiment were performed to investigate the mechanical properties of the $Al_2O_3$/Fe-Ni nanocomposite.

Ultrasonic Spray Nozzle System with Piezoelectric Device for Chemicals Dispersion (압전체를 이용한 약품 분사용 초음파 분사 노즐 시스템)

  • 고재석;김용현;김형수;조순행;최승철
    • Journal of the Microelectronics and Packaging Society
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    • v.10 no.4
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    • pp.65-71
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    • 2003
  • A new type of ultrasonic spray nozzle was fabricated employing a piezoelectric device. The spray nozzle was designed to disperse chemicals in a water treatment mixing tank. The piezoelectric properties in ultrasonic spray nozzles were optimized to improve the dispersion of chemicals. The piezoelectrics were packaged in an aluminum case with silicone resin for the aqueous solution proof packaging. Chemicals were dispersed with high efficiency and the chemicals consumption was reduced by the ultrasonic fine particle spraying. The concentration of Escherichia coli in mixing tank was decreased remarkably using ultrasonic spray nozzle dispersion compared to the conventional methods.

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Modification of Water-borne Polyurethane Using Benzophenone Crosslinker (Benzophenone 가교제를 이용한 수분산 폴리우레탄 개질)

  • Kim, HyeokJin;Kim, Jin Chul;Chang, SangMok;Seo, BongKuk
    • Applied Chemistry for Engineering
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    • v.27 no.2
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    • pp.221-226
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    • 2016
  • Production of eco-friendly and biologically harmless materials is strongly required in all industries. In particular, reducing volatile organic compounds in coating processes is extremely important to secure worker's safety. During recent two decades, extensive research works on water-borne polyurethane dispersion (PUD) have been continuously developed as an alternative to solvent-borne polyurethane. However, PUD was shown inferior mechanical properties to the organic solvent-borne polyurethane due to a limit to the molecular weight increase, which resulted in the limit of applications. To overcome this drawback, several approaches have been examined such as polymer blends and thermal/radiation induced crosslinking. Among these methods, the radiation curing system was suitable for industrialization because of the high crosslinking density and fast curing speed. In this study, we overcame the drawback for PUD via introducing benzophenone radiation curable units to PUD. We synthesized PUD films which possessed good dispersion in water for 30 days, increased Tg and Td more than $5^{\circ}C$ after UV curing film as well as improved young's modulus more than double.

Effect of Ball milling Time on Graphite Dispersion and Mechanical Properties in Rapidly Solidified 6061 Al Composite (급속응고 6061Al/Graphite 복합재료의 볼밀링 시간에 따른 흑연 분산거동 및 기계적 특성)

  • Son, Hyeon-Taek;Lee, Jae-Seol;Hong, Soon-Jik;Chun, Byong-Sun
    • Journal of Powder Materials
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    • v.16 no.3
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    • pp.209-216
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    • 2009
  • A composite of rapidly solidified Al-6061 alloy powder with graphite particle reinforcements was prepared by ball milling and subsequent hot extrusion. The microstructure and mechanical properties of these composites were investigated as a function of milling time. With increasing milling time, the gas atomized initially and spherical powders became elongated with a maximum aspect ratio after milling for 30 h. Then, refinement and spheroidization were achieved by further milling to 70 h with a homogeneous and fine dispersion of graphite particles forming between the matrix alloy layers. The best compression and wear properties were obtained in the powder milled for 70 h, associated with the increased fine and homogeneous distribution of graphite particles in the aluminum alloy matrix.

The Fine Dust Reduction Effect and Operational Strategy of Vegetation Biofilters Based on Subway Station Passenger Volume (지하역사 내 승하차 인원에 따른 식생바이오필터의 미세먼지 저감효과와 운전전략)

  • Jae Young Lee;Ye Jin Kim;Mi Ju Kim
    • Journal of the Semiconductor & Display Technology
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    • v.22 no.4
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    • pp.13-18
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    • 2023
  • A subway station is a prominent multi-purpose facility where the quantitative management of fine dust, generated by various factors, is conducted. Recently, eco-friendly air purification methods using air-purifying plants are being discussed, with the focus on biofiltration through vegetation. Previous research in this field has confirmed the reduction effects of transition metals such as Fe, which have been identified as harmful to human health. This study aimed to identify the sources of fine dust dispersion within subway stations and derive an efficient operational strategy for air-purifying plants that takes into account the behavior characteristics of fine dust within multi-purpose facilities. The experiment monitored regional fine dust levels through IAQ stations established based on prior research. Also, the data was analyzed through time-series and correlation analyses by linking it with passenger counts at subway stations and the frequency of train stops. Furthermore, to consider energy efficiency, we conducted component-specific power consumption monitoring. Through this study, we were able to derive the optimal operational strategy for air-purifying plants based on time-series comprehensive analysis data and confirm significant energy efficiency.

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Tracer Experiment for the Investigation of Urban Scale Dispersion of Air Pollutants - Simulation by CALPUFF Dispersion Model and Diffusion Feature of Tracer Gases (추적자 확산 실험에 의한 서울 도심 확산 현상 연구 - 추적기체의 확산특징과 CALPUFF 모델에 의한 모사)

  • Lee, Chong-Bum;Kim, Jea-Chul;Lee, Gang-Woong;Ro, Chul-Un;Kim, Hye-Kyeong
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.4
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    • pp.405-419
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    • 2007
  • A series of tracer experiments for the evaluation of atmospheric dispersion was performed over the urban area of Seoul using two inert, non-deposition perfluorocarbon (PMCH and m-PDCH) gases during three years campaign on 2002, 2003 and 2005. 30 sampling sites for collecting these tracers were located along two arcs of 2.5 and 5 kilometers downwind from the release point. About ten measurements which each lasted for 2 hours or 4 hours were made over the two consecutive days during each campaign. CALPUFF and MM5 meteorological model were applied to evaluate the urban dispersion in detail. Size of Modeling domain was $27\;km{\times}23\;km$ and the fine nest in the modeling domain had a grid size of 0.5 km. The results showed that CALPUFF dispersion model had a tendency to estimate tracer concentrations about $2{\sim}5$ times less than those of ambient samples under many conditions. These consistent inaccuracy in urban dispersion was attributed to inherent inaccuracy and lack of details in terrain data at urban area.