• Journal of the Korean Ceramic Society
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• v.37 no.8
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• pp.751-759
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• 2000

Effects of the dosage change, from 0 to 2.0 wt% based on cement weight, of naphthalenic (NSF) and polycarboxylic(NT-2) superplasticizers, on the fluidity of cement paste substituted by 10 wt% II-anhydrite and fly ash respectively as well as II-anhydrite and fly ash itself were investigated. Dispersion properties between particles in suspension were investigated by zeta potential test. Initial fluidity and slump loss in the paste system were observed through mini-slump and apparent viscosity changes with elapsed time. Zeta potential on the particle surface was a tendency to increase according to increasing of NSF dosage. Especially, zeta potential of fly ash has the highest value among all particles equivalent to NSF dosage. In the fluidity of cement paste substituted by inorganic particles, the specimen with substitution of 10 wt% II-anhydrite and fly ash for cement was more effective than cement itself to improve initial fluidity and retain stable fluidity of cement paste. In addition, effect of NT-2 and NSF to improve the fluidity of cement paste, addition of 1.0 wt% NT-2 was more effective than 1.5wt% NSF.

• Journal of Powder Materials
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• v.28 no.5
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• pp.375-380
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• 2021

In this study, we investigate the effect of the duration of mechanical alloying on the microstructures and mechanical properties of ODS ferritic/martensitic steel. The Fe(bal.)-10Cr-1Mo pre-alloyed powder and Y₂O₃ powder are mechanically alloyed for the different mechanical alloying duration (0 to 40 h) and then constantly fabricated using a uniaxial hot pressing process. Upon increasing the mechanical alloying time, the average powder diameter and crystallite size increased dramatically. In the initial stages within 5 h of mechanical alloying, inhomogeneous grain morphology is observed along with coarsened carbide and oxide distributions; thus, precipitate phases are temporarily observed between the two powders because of insufficient collision energy to get fragmented. After 40 h of the MA process, however, fine martensitic grains and uniformly distributed oxide particles are observed. This led to a favorable tensile strength and elongation at room temperature and 650℃.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.19 no.11
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• pp.64-69
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• 2020

To determine the effective factors for microparticle blasting with precise sequence position control in the x-axis and y-axis directions, we conducted a statistical experimental analysis of blasted square shapes by considering five condition factors. The control input and output were operated simultaneously by rotation-linear motion conversion and fine particles were blasted onto the aluminum specimen by precise position control driving using multiple execution codes. The micro-driving device used for processing was capable of microparticle blasting and of controlling the system through contact with a limit sensor at high speed and a two-degree-of-freedom driving mechanism. Our experiments were conducted on 1,050 specimens of pure aluminum (containing <1% of other elements). The effects of several factors (e.g., particle and nozzle diameters, blasting pressure, and federate and blasting cycle numbers) on the surface roughness and blasted surface's depth were verified through a statistical experimental analysis by applying the dispersion analysis method. This statistical analysis revealed that the nozzle diameter, the blasting pressure, and the blasting cycle number were the dominant factors.

• Applied Chemistry for Engineering
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• v.32 no.4
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• pp.483-486
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• 2021

Catalytic ozonation of methyl ethyl ketone (MEK) has been examined over mesoporous MnO_x/Al₂O₃ (MA) catalysts developed by a solvent deficient method using two different manganese precursors including manganese chloride (C) and manganese sulfate (S) at room temperature. The maximum catalytic activities of MA with C (MEK removal efficiency and ozone decomposition of 98.4 and 93.7%, respectively) were higher than those of MA with S (MEK removal efficiency and ozone decomposition of 96 and 68%, respectively). Also the catalytic stability of MA with C was much higher than that of MA with S. The physico-chemical properties of catalysts are well correlated with the activity results, which confirmed that fine dispersion of MnO_x species with high ratios of Mn³⁺/Mn⁴⁺ and more acid sites are attributed to the higher catalyst stability for the MA-C catalyst.

• Progress in Superconductivity and Cryogenics
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• v.10 no.1
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• pp.1-5
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• 2008

The effect of $BaCeO_3$ doping on the critical current density of YBCO film by TFA-MOD method was studied. $BaCeO_3$ doping was made by two method; one is direct addition of $BaCeO_3$ nano-sized powder prepared by citrate process followed by grinding with planetary ball mill for 10 hours. Another is addition of Ba-Ce precursor solution prepared with Ba-acetate and Ce acetate dissolved in TFA to the YBCO-TFA precursor solution. The film was made by standard dip coating and heat treatment process with conversion temperature of $790^{\circ}C$ in 1000 ppm oxygen containing moisturized Ar gas atmosphere. The direct addition of $BaCeO_3$ powder resulted in YBCO film with good epitaxial growth and no evidence of second phase formation. The addition through precursor solution resulted in the increase of critical current density upto 30 at% doping and uniform dispersion of $BaCeO_3$ fine inclusion was confirmed by SEM-EDX.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.4
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• pp.388-395
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• 2016

This paper explores the photocatalytic sensitivity of cement mortar incorporated with recycled $TiO_2$ from waste water sludge. Basically, $TiO_2$ cluster sank down slowly to the bottom of cement mortar specimen before setting and hardening process. This leads the mismatch of $TiO_2$ concentration on the top and the bottom faces of a specimen. This poorly dispersed $TiO_2$-cement mortar naturally exhibits poor NOx removal efficiency especially on the top of cementitious structure. In architectural engineering application such as building or housing structures, one can simply filp over from the bottom so that more $TiO_2$ concentrated surface can be placed outward into the air. However, in highway pavement case, this could not be applicable due to in-situ installation of concrete pavement. Hence, the dispersion of $TiO_2$ cluster inside the cementitous material is getting important issue onto road construction application. To elaborate this issue, according to our results, silica fume, high-ranged water reducer, viscosity agent, blast furnace slag were not enhanced much of dispersion characteristics of $TiO_2$ cluster. The combination of foaming agent and accelerator of hardening with viscosity agent and small grain size of fine aggregate may help the dispersion of $TiO_2$ inside cementitious materials. Even though the enhanced dispersion were applied to the specimen, NOx removal efficiency doest not change much for the top surface of the specimen. This concurrently affected by the presence of tiny air voids and the dispersion of $TiO_2$ in that these voids could easily adsorbed NOx gas with the aid of large surface area.

• Journal of Soil and Groundwater Environment
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• v.13 no.4
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• pp.1-7
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• 2008

This study analyzed for hydrodynamic dispersion characteristics of multi-soil layer (Silt and clay, Find sand, Coarse sand), data of a field tracer test on the multi-soil layer and data of laboratory column experiments on the samples on each soil layers. Through the analysis of permeability and flow, MS (Silt and clay) and FS (Fine sand), which were low effective porosity, were higher average linear velocity while CS (Coarse sand), which was high effective porosity, was higher hydraulic conductivity. Hydraulic conductivity function based on average soil particle diameter was assumed Y=$3.49{\times}10^{-8}e^{15320x}$ and coefficient of determination was 0.90. Average linear velocity function based on average soil particle diameter was assumed Y=$1.88{\times}10^{-7}e^{11459x}$ and coefficient of determination was 0.81. Longitudinal dispersivity function based on average soil particle diameter was Y = 0.00256$e^{5971x}$ and coefficient of determination was 0.98. According to the linear regression analysis of average linear velocity and longitudinal dispersivity, assumed function was Y = 21.7527x + 0.0063, and coefficient of determination was 0.9979. The ratio of field scale/laboratory scale was 54.09, it exhibited scale-dependent effect of hydrodynamic dispersion. Field longitudinal dispersivity (1.39m) was 7.47 times as higher than longitudinal dispersivity estimated by the methods of Xu and Eckstein (1995). Hydrodynamic dispersion on CS layer was occurred mainly by diffusion flow in the test aquifer.

• Journal of the Korea Institute of Building Construction
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• v.9 no.5
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• pp.127-133
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• 2009

It is important to increase the strength of binders in order to enhance the strength of concrete. However, when the mineral admixture used for high strength concrete is incorporated individually, its dispersibility decreases due to the phenomenon of compaction, which reduces its fluidity and results in insufficient strength being created. To solve this problem, we can pre-mix each binder in advance to disperse a mineral admixture among binders, which will strengthen the fluidity and strength of concrete. Therefore, this study analyzed the properties of high strength concrete depending on the mix method used, to determine the effect of pre-mix cements ranging from W/B 15 to 35%. It was found that the fluidity of pre-mix increased to a level higher than that of individual mix due to its dispersion and ball bearing effect. The air content was slightly decreased from the result of individual mix due to the micro filler effect, which causes fine particles of silica-fume to fill the voids among cement particles, while the setting time of pre-mix was shorter than that of individual mix, because enhanced dispersion of pre-mix affects hydration heat time. The compressive strength of pre-mix increased due to the phenomenon of compaction of gap structure, and the variation of coefficient decreased by 1.69% on average in strength variation.

• Journal of Korea Water Resources Association
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• v.37 no.12
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• pp.979-991
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• 2004

In this study, RMA2 and RMA4, the 2-D depth-averaged models, were employed to simulate the two-dimensional mixing characteristics of the pollutants in the natural streams. The velocity and depth were first calculated using RMA2, 2-D hydrodynamic model, and then the resulting flow field was inputted to RMA4, 2-D water quality model, to compute the concentration field. RMA models were verified using the velocity and concentration data measured in S-curved meandering channel. The results showed that the RMA2 model simulated well the phenomenon that the maximum velocity line is located at the Inner bank of meandering channel, and the RMA4 model was well adapted to reproduce the general mixing behavior and the separation of tracer clouds. Comparing model simulations with measured data in the field experiments, RMA2 model simulated well general flow field and tendency that the maximum velocity line skewed toward the outer bank which were found in field experiments. The simulations of RMA4 model showed that the center of the tracer cloud tends to follow the path in which the maximum velocity occurs. In this study, the dispersion coefficients are fine-tuned based on the measured coefficients calculated using field concentration data, and the results show reasonable agreement with predictive equations.

• Journal of Adhesion and Interface
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• v.13 no.2
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• pp.58-63
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• 2012

CFRP chip is the byproduct from carbon fiber reinforced plastic (CFRP) processing. CFRP chip is not simply a waste mainly composed of fine carbon fiber and epoxy resin. CFRP chip keeps matrix to maximize their reinforcing effect. To obtain a uniform length of carbon fiber in CFRP chip, chip was chopped ina mortar. CFRP chip should be purified to get better interface adhesion. Epoxy resin on the carbon fiber was removed by $H_2O_2$ surface etching treatment. Optimal dispersion and fabrication conditions of CFRP chip embedded in phenolic resin were determined by thermal stability for fire retardant applications. CFRP chip-phenolic composite exhibits better mechanical and thermal properties than neat phenolic resin. Surface condition of CFRP chip-phenolic composite was evaluated by static contact angle measurement. Contact angle of CFRP chip-phenolic composite was greater than neat phenolic due to heterogeneous condition of fine carbon fibers. From the evaluation for fire retardant (ASTM D635-06) test, thermal stability of CFRP chip-phenolic composite was found to be improved with higher concentration of CFRP chip.