• Title/Summary/Keyword: fine and coarse particles

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Electrical and Mechanical Characteristics of Ni-YSZ Tubular Support Fabricated by Extrusion (압출공정에 의해 제조된 Ni-YSZ 원통형 음극 지지체의 특성)

  • Yu, Ji-Haeng;Kim, Young-Woon;Park, Gun-Woo;Seo, Doo-Won;Lee, Shi-Woo;Woo, Sang-Kuk
    • Journal of the Korean Ceramic Society
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    • v.43 no.12 s.295
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    • pp.768-774
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    • 2006
  • The microstructure of Ni-YSZ cermets was controlled with fine and coarse starting powders (NiO and YSZ) to obtain a optimum strong and conductive tubular anode support for SOFCs. Three types of cermets with different microstructures, i.e., coarse Ni-fine YSZ, fine Ni-coarse YSZ, and fine Ni-fine YSZ, were fabricated to investigate their electrical and mechanical properties. The cermets from fine NiO powder showed high electrical conductivity due to the enhanced percolation of Ni particles. The cermet by foe Ni and coarse YSZ showed excellent electrical conductivity (>1000 S/cm) despite its high porosity $(\sim40%)$ but it showed poor mechanical strength due to the lack of percolation by YSZ particles and due to large pores. Thus fine NiO and YSZ powders were used to make strong and conductive Ni-YSZ support tube by extrusion. The microstructure of the anode tube was modified by the amount of polymeric additives and carbon black, a pore former. Ni-YSZ tube (porosity $\sim34%$) with the finer microstructure showed better performance both in electrical conductivity (>1000 S/cm) and fracture strength $(\sim140\;MPa)$. Either flat or circular NiO-YSZ tubes with the length from 20 to 40cm were successfully fabricated with the optimized composition of materials and polymeric additives.

Source Identification and Quantification of Coarse and Fine Particles by TTFA and PMF

  • Hwang, In-Jo;Bong, Choon-Keun;Lee, Tae-Jung;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.E4
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    • pp.203-213
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    • 2002
  • Receptor modeling is one of statistical methods to achieve reasonable air pollution strategies. In order to maintain and manage ambient air quality, it is necessary to identify sources and to apportion its sources for ambient particulate matters. The main purpose of the study was to survey seasonal trends of inorganic elements in the coarse and fine particles. Second, this study has attempted emission sources qualitatively by a receptor method, the PMF mo-del. After that. both PMF (positive matrix factorization) model and TTFA (target transformation factor analysis) model were applied to compare and to estimate mass contribution of coarse and fine particle sources at the receptor. A total of 138 sets of samples was collected from 1989 to 1996 by a low volume cascade impactor with 9 size fraction stages at Kyung Hee University in Korea. Sixteen chemical species (Si, Ca, Fe, K, Pb, Na, Zn, Mg, Ba, Ni, V, Mn, Cr, Br, Cu. Co) were characterized by XRF. The study result showed that the weighted arithmetic mean of coarse and fine particles were 51.3 and 54.4 $\mu\textrm{g}$/㎥, respectively. Contribution of both particle fractions were esti-mated using TTFA and PMF models. The number of estimated sources was seven according to TTFA model and 8 according to PMF model. Comparison of TTFA and PMF revealed that both methodologies exhibited similar trends in their contribution pattern. However, large differences between contributions were observed in some sour-ces. The results of this study may help to suggest control strategies in local countries where known source profiles do not exist.

Cowpea Starch Extraction Process using Microparticulation/Air classification Technology (미분쇄/공기분급을 이용한 동부전분의 추출)

  • Ku, Kyung-Hyung;Park, Dong-June
    • Korean Journal of Food Science and Technology
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    • v.30 no.1
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    • pp.118-124
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    • 1998
  • Dehulled cowpea was microparticulated and coarse fractions and fine fractions were collected by air classification at air classifying wheel speed (ACWS) of 15,000 rpm, 12,000 rpm and 9,000 rpm, respectively. Protein content in fine fraction after air classification was 2 times higher than that of microparticulated cowpea, emulsion capacity was about 3 times than coarse fraction. The coarse fraction of the highest viscosity on the gelatinization properties were detected by amylograph, was C-3 (9,000 rpm coarse)fraction. The majority of microparticulated cowpea particles were oval shaped starch and the rest of them were indeterminate minute particles which had some sharp corners. As an application test, microparticulated cowpea and coarse fraction (C-3) were used for mook (Korea traditional starch jelly) preparation and the wet milled cowpea starch was compared as a control. Some impurities induced discoloring was detected by sensory evaluation but after washing, it made no difference in sensory scores between washed starch and the control cowpea mook. And also syneresis of washed cowpea was less than control. At the above result, it can be to recovery about 85% of cowpea starch using microparticulation/air classification technology.

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Elemental Analysis of Road Aerosols using by a PIXE Method (PIXE 분석법에 의한 도로변 분진의 원소분석)

  • 최금찬;임경택;조정구;김태형
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.5
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    • pp.523-528
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    • 1996
  • Aerosol Particles were collected in a heaby traffic region in pusan. Samples were collected in two size fractions with a two-stage sampler during the day and the night. Elemental concentrations of these aerosol particles were determined by a PIXE(Proton Induced X-ray Emission) analysis method. The results suggest that the elements originating mainly from natural sources such as Si, Ca, Fe, Cl, and K are dominent in the coarse fraction, but the elements such as S, Pb, Br, and Zn are dominent in the fine fraction. Br/Pb ratio are evaluated in both coarse and fine size fraction, and which are mainly emitted automobile sources. The study further also discussed other Br/Pb ratio related works described elsewhere. Sulfur in the fine fraction was continuously increased during the sampling period without time variation.

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Analysis of Physical and Chemical Properties of Perlite Substrate (펄라이트 배지의 물리성과 화학성 분석)

  • 조영렬;손정익
    • Journal of Bio-Environment Control
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    • v.9 no.1
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    • pp.20-26
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    • 2000
  • This study aims at analyzing physical and chemical properties of perlite substrate. Particles of substrate were divided into five categories In size: gravel, very-coarse, coarse, medium and fine grade. Particles of very-coarse and greater grades in perlite substrate occupied 98.5% of total particles. The air phase of total particles was distributed between 76.8% and 87.7% with especially showing that of very-coarse grade was lower than that of coarse or smaller one. However, the liquid and solid phases were vice versa. The cation exchange capacity (CEC) measured was highest in the fine grade. In drainage experiments, the water being drained from the substrate increased with the ratio of drain area, and the 65~70% of total water reduced within five minutes after irrigation. The drained volume was proportional to the depth of the substrate, which contained about 2mL.cm$^2$:by depth (cm). Due to quick reduction of the water in the substrate, the pF value increased in four minutes after irrigation and showed the highest negative correlation ($R^2$=0.997) with the moisture content of the substrate. The physical and chemical properties including drainage characteristics analyzed in this study can be, therefore, utilized to control the moisture content of perlite substrate, efficiently.

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Effect of Reinforcing Materials on Properties of Molten Carbonate Fuel Cell Matrices

  • Moon, Young-Joon;Lee, Dokyol
    • The Korean Journal of Ceramics
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    • v.2 no.3
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    • pp.142-146
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    • 1996
  • The molten carbonate fuel cell matrices, which are usually made of high surface, fine particle size ${\gamma}-LiAlO_2$ are reinforced with coarse particles of the same material and alumina fibers. An the effects of reinforcing materials on pore characteristics, sintering properties and mechanical properties of the matrices are examined.Among the matrices examined, the highest mechanical reinforcement has been achieved in the one containing 10 wt.% coarse particles and 20 wt.% alumina fibers.

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Characteristics of the Reduction of Fine Particles in an Indoor Air Cleaner Using Electrostatic Precipitation Technique (전기집진기형 공기청정기의 미세 먼지 저감 특성에 관한 연구)

  • Mok, Young-Sun;Lee, Ho-Won
    • Journal of the Korean Society of Industry Convergence
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    • v.7 no.1
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    • pp.115-120
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    • 2004
  • An indoor air cleaner consisting of a dielectric barrier discharge system and an electrostatic precipitator (ESP) was experimentally investigated. The function of the dielectric barrier discharge is to precharge particles by producing nonthermal plasma before indoor air enters ESP, leading to an enhancement in dust collection efficiency. The dependence of particle size distribution on the plasma discharge was examined to understand the mechanism of the particle precharging. The plasma discharge was found to increase the electrical force of the particles, rather than agglomerate them. Coarse particles in the range of 0.5 to $5.0{\mu}m$ were observed to be easily collected by this indoor air cleaner, and the present study laid emphasis on the removal of fine particles of $0.3{\mu}m$. The collection efficiency of the fine particles was largely enhanced by the plasma discharge.

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Organic Carbon, Calcium Carbonate, and Clay Mineral Distributions in the Korea Strait Region, the Southern Part of the East Sea

  • Khim, Boo-Keun;Shin, Dong-Hyeok;Han, Sang-Joon
    • Journal of the korean society of oceanography
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    • v.32 no.3
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    • pp.128-137
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    • 1997
  • This study presents results from a detailed sedimentological investigation of surface sediments obtained from the Korea Strait region, the southern part of the East Sea (Sea of Japan). The distribution of different types of bottom sediments is controlled by the recent fine-grained sediment transport and deposition combined with the lowerings of sea level during the last glacial period, forming a diverse mixture of organic-rich fine-grained and shelly coarse-grained sediments. In comparison to high organic concentration of fine-grained sediments in the inner continental shelf and slope areas, the shell-rich coarse-grained sediments on the outer shelf are discernible being further modified. These coarse-grained sediments are confirmed as relict resulting from the sediment dynamics during the lower sea levels of the last glacial period. Clay mineral distribution of the fine-grained sediments gives information about the transport mechanism. Presence of present-day current system (the Tsushima Warm Current) is most probable source for the fine-grained particles into the open East Sea from the East China Sea, indicating that Holocene sediment dynamics may be used to explain the observed distribution of surface coarse-grained shell-rich sediments.

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Vertical Change in Extinction and Atmospheric Particle Size in the Boundary Layers over Beijing: Balloon-borne Measurement

  • Chen, Bin;Shi, Guang-Yu;Yamada, Maromu;Zhang, Dai-Zhou;Hayashi, Masahiko;Iwasaka, Yasunobu
    • Asian Journal of Atmospheric Environment
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    • v.4 no.3
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    • pp.141-149
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    • 2010
  • Aerosol size and number concentration were observed in the atmospheric boundary layer over Beijing (from near the ground to 1,200 m) on March 15 (a clear day) and 16 (a dusty day), 2005. The results were further compared with lidar measurements in order to understand the dependency of extinction on the particle size distribution and their vertical changes. The boundary layer atmosphere was composed of several sub-layers, and a dry air layer appeared between 400 and 1,000 m under the influence of dust event. In this dry air layer, the concentration of the fine-mode particles (diameter smaller than $1.0\;{\mu}m$) was slightly lower than the value on the clear day, while the concentration of coarse-mode particles (diameter larger than $1.0\;{\mu}m$) was remarkably higher than that on the clear day. This situation was attributed to the inflow of an air mass containing large amounts of Asian dust particles and a smaller amount of fine-mode particles. The results strongly suggest that the fine-mode particles affect light extinction even in the dusty atmosphere. However, quantitatively the relation between extinction and particle concentration is not satisfied under the dusty atmospheric conditions since laser beam attenuates in the atmosphere with high concentration of particles. Laser beam attenuation effect becomes larger in the relation between extinction and coarse particle content comparing the relation between extinction and fine particle content. To clarify this problem technically, future in situ measurements such as balloon-borne lidar are suggested. Here extinction was measured at 532 nm wavelength. Measurements of extinction at other wavelengths are desired in the future.

Chemical Composition of the Size-resolved Particles in Buk-Ak Tunnel

  • Ma, Chang-Jin;Hwang, Kyung-Chul;Kang, Gong-Unn;Tohno, Susumu
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.E2
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    • pp.53-59
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    • 2004
  • The roadway tunnels in urban areas give rise to problems such as a localized air pollution. Here, we report the results of a case study of an urban roadway tunnel measurement. The size-resolved particle sampling was carried out with a two 2-stage filter pack samplers and an Andersen impactor sampler at the center of Buk-Ak tunnel in November 2001. Particle Induced X-ray Emission (PIXE) was applied to determine the elemental composition of size-resolved particles divided into soluble and insoluble fractions. The Thermal/Optical Reflectance (TOR$^{(R)}$) method was also employed in analyzing of elemental carbon (EC) and organic carbon (OC). Mass concentrations of fine (< 1.2 ${\mu}{\textrm}{m}$) and coarse (> 1.2 ${\mu}{\textrm}{m}$) particles are 165 and 48 $\mu\textrm{g}$ m$^{-3}$ , respectively. Total elemental mass concentration (the sum of insoluble coarse, soluble coarse, insoluble fine, and soluble fine) is found to be 24$\mu\textrm{g}$ m$^{-3}$ and comprises only 11 % of total particle mass concentration. The concentrations of EC, OC, and mass show the clear dependency on particle size with the maximum between 0.1 and 0.43 ${\mu}{\textrm}{m}$ aerodynamic diameters. Total carbon (sum of EC and OC) accounts for approximately 70% of mass concentration.n.