• Title/Summary/Keyword: film

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The Effect of Extraction Conditions and Film Side on the Molecular Conformation of Silk Sericin Film

  • Jo, Yoon Nam;Bae, Do Gyu;Um, In Chul
    • International Journal of Industrial Entomology and Biomaterials
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    • v.26 no.2
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    • pp.113-118
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    • 2013
  • In this study, silk sericin films were prepared using different extraction methods, and the molecular conformation of sericin was examined using Fourier-transform infrared spectroscopy with attenuated total reflection geometry. Additionally, the effect of the film side (air-facing side or plate-facing side) on the molecular conformation of the sericin films was investigated. Interestingly, the molecular conformation of the sericin film depended on the film side. The molecular conformation of air-facing side of the sericin film was significantly influenced by extraction solution and time. The ${\beta}$-sheet crystallization and the crystallinity index of the sericin film markedly increased with an increase in the extraction time in hot water. The order of the crystallinity indices for the sericin films obtained with different extraction solutions was as follows: citric acid solution > urea solution >> hot water. In contrast, no remarkable differences were observed in the molecular conformation of the plate-facing side of the sericin film after extraction in hot water for different time periods. Urea and citric acid solution extractions showed remarkably higher crystallinity indices for sericin than those obtained after hot water extraction. However, no significant differences were observed in the crystallinity index of sericin between urea and citric acid solution extraction in plate-facing side of the film.

Protection Effect of ZrO2 Coating Layer on LiCoO2 Thin Film

  • Lee, Hye-Jin;Nam, Sang-Cheol;Park, Yong-Joon
    • Bulletin of the Korean Chemical Society
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    • v.32 no.5
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    • pp.1483-1490
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    • 2011
  • The protection effect of a $ZrO_2$ coating layer on a $LiCoO_2$ thin film was characterized. A wide and smooth $LiCoO_2$ thin film offers sufficient opportunity for careful observation of the reaction at the interface between cathode (coated and uncoated) and electrolyte. The formation of a $ZrO_2$ coating on a $LiCoO_2$ thin film was confirmed by secondary ion mass spectrometry. Scanning electron and atomic force microscopy were used to characterize the surface morphologies of coated and uncoated films before and after cycling. A $ZrO_2$-coated $LiCoO_2$ film showed a higher discharge capacity and rate capability than an uncoated film. This may be associated with a surface protection effect of the coating. The surface of a pristine film was damaged during cycling, whereas the coated film maintained a relatively clear surface under the same measurement conditions. This result clearly demonstrates the protection effect of a $ZrO_2$ coating on a $LiCoO_2$ thin film.

The Effect of Surrounding Gas Flow on the Heat Transfer of the Falling Film Flowing Down the Outside of a Vertical Tube (수직원관 외부 유하액막 열전달에 주변 기체유동이 미치는 영향)

  • 권경민;정시영;김병주
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.12
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    • pp.996-1003
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    • 2002
  • Heat transfer characteristics were investigated for the falling film flowing down the outside of an electrically heated vertical tube. Water was used for the falling film, and its Reynolds number was varied in the range of 70~500. Because water is heated and evaporated as it flows down, both sensible and latent heat transfer should be considered. The effect of the surrounding air movement was investigated by changing the direction of the air injection; without air injection, parallel-flow, and counter-flow. For all cases, sensible teat transfer rate was almost linearly increased with the increasing film flow rate. It was found that the film heat transfer coefficient was hardly influenced by the parallel air flow. However, the counter-flow of air reduced the heat transfer coefficient, which might be caused by the uneven distribution or flooding of the film. At high heat flux, a sudden change of the film heat transfer coefficient was detected as the film flow rate reached the transition value. It is supposed that this phenomenon was caused by the change in the film flow pattern.

Estimation of Interfacial Adhesion through the Micromechanical Analysis of Failure Mechanisms in DLC Film

  • Jeong, Jeung-Hyun;Park, Hae-Seok;Ahn, Jeong-Hoon;Dongil Kwon
    • The Korean Journal of Ceramics
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    • v.3 no.2
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    • pp.73-81
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    • 1997
  • In this paper, it is intended to present more reproducible and quantitative method for adhesion assemssement. In scratch test, micromechanical analysis on the stress state beneath the indenter was carried out considering the additional blister field. The interface adhesion was quantified as work of adhesion through Griffith energy approach on the basis of the analyzed stress state. The work of adhesion for DLC film/WC-Co substrate calculated through the proposed analysis shows the identical value regardless of distinctly different critical loads measured with the change of film thickness and scratching speed. On the other hand, uniaxial loading was imposed on DCL film/Al substrate, developing the transverse film cracks perpendicular to loading direction. Since this film cracking behavior depends on the relative magnitude of adhesion strength to film fracture strength, the quantification of adhesion strength was given a trial through the micromechanical analysis of adhesion-dependence of film cracking patterns. The interface shear strength can be quantified from the measurement of strain $\varepsilon$s and crack spacing $\lambda$ at the cessation of film cracking.

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Surface Characteristics of TiN and ZrN Film Coated STD 61 by Sputtering (스퍼터링법으로 TiN 및 ZrN 피막 코팅된 STD 61의 표면특성)

  • Eun, Sang-Won;Choe, Han-Cheol
    • Journal of the Korean institute of surface engineering
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    • v.43 no.6
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    • pp.260-265
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    • 2010
  • STD 61 steel has been widely used for tools, metallic mold and die for press working because of its favorable mechanical properties such as high toughness, and creep strength as well as excellent oxidation resistance. The STD 61 tool steel coated with TiN and ZrN by sputtering results in improvement of wear and corrosion resistance. In this study, surface characteristics of TiN and ZrN film coated STD 61 by sputtering were studied by using FE-SEM, EDS, XRD, and XRR and nanoindentation tests. From the results of surface characteristics of coated specimen, the ZrN coated surface showed finer granular than that of TiN coated surface. The coated layer structures of ZrN and TiN were grown to (111) and (200) preferred orientation. From the results of XRR test for surface roughness, density and growth rate of coating film, surface roughness and growth rate of ZrN coated film revealed lower values those of TiN coated film, whereas density of ZrN coated film showed higher values than that of TiN coated film. From the nanohardness and elastic modulus test, nanohardness value and elastic modulus of ZrN coated film became higher than those of TiN coated film.

A Study on the Oil Film Behaviors of Pin Bush Bearings for Diesel Engines with Various Engine Oil Viscosities (오일점도에 따른 디젤엔진용 핀부시 베어링의 유막거동에 관한 연구)

  • Kim, Chung-Kyun;Lee, Byoung-Kwan
    • Tribology and Lubricants
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    • v.24 no.1
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    • pp.21-26
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    • 2008
  • A pin bush bearing is one of the most important element in the piston engine which is joined a piston to a connecting rod. A pin bush is suffered by heat and changeable repeat loads, which are come from the explosive gas heat and pressures during a reciprocating stroke. Therefore, a tribological behavior of pin bush bearings is very severe compared to other parts of a piston assembly. To keep a stable operation of pin bush bearings effectively, it would be satisfied with proper oil film strength for severe operating conditions and durability, which are strongly related to the oil film thickness, oil film pressure, and a friction loss power. The computed results show that the viscosity of engine oils slightly affects to the minimum oil film thickness and oil film pressure distribution, but is an influential parameter on a total friction loss power. Thus the low viscosity engine oils for an increased operation condition should select a high level of base oil and add a viscosity index improver as an oil film additive.

Anisotropic, non-uniform misfit strain in a thin film bonded on a plate substrate

  • Huang, Y.;Ngo, D.;Feng, X.;Rosakis, A.J.
    • Interaction and multiscale mechanics
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    • v.1 no.1
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    • pp.123-142
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    • 2008
  • Current methodologies used for the inference of thin film stresses through curvature measurements are strictly restricted to stress and curvature states which are assumed to remain uniform over the entire film/substrate system. These methodologies have recently been extended to non-uniform stress and curvature states for the thin film subject to non-uniform, isotropic misfit strains. In this paper we study the same thin film/substrate system but subject to non-uniform, anisotropic misfit strains. The film stresses and system curvatures are both obtained in terms of the non-uniform, anisotropic misfit strains. For arbitrarily non-uniform, anisotropic misfit strains, it is shown that a direct relation between film stresses and system curvatures cannot be established. However, such a relation exists for uniform or linear anisotropic misfit strains, or for the average film stresses and average system curvatures when the anisotropic misfit strains are arbitrarily non-uniform.

Study for the Director's Purpose and Film Style of (<사울의 아들>의 연출의도와 형식에 관한 연구)

  • Lee, Choong-jik;Kim, Jihyun
    • The Journal of the Korea Contents Association
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    • v.18 no.8
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    • pp.227-239
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    • 2018
  • The style of a film is the element that makes audience realize director's purpose directly. As the film's spectacular background have became important it's hard to find non-wide screen film, and audience and theaters are very familiar to 1.85:1 film ratio and even wider. Nevertheless, did not follow this trend but to chose narrow film ratio and shallow focus. This film, of which the background is Nazi's concentration camp, does not allow audience to catch more information than main character Saul. It's because the director aims to make audience Saul's position in the film. This paper discuss how the style of reflects the director's intention.

Magnetic Properties of Co-Cr(-Ta)/Si Bilayered Thin Film (Co-Cr(-Ta)/Si 이층막의 자기적 특성)

  • 김용진;박원효;금민종;최형욱;김경환;손인환
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.3
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    • pp.281-286
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    • 2002
  • In odder to investigate the magnetic properties of CoCr-based bilayered thin films on kind of underlayer, we introduced amorphous Si layer to Co-Cr(-Ta) magnetic layer as underlayer. First, we prepared CoCr and CoCrTa single layer using the Facing Targets Sputtering system to investigate theirs properties. It was revealed that with increasing the film thickness of CoCr, CoCrTa single layer, crystalline orientation and perpendicular coercivity was improved. The CoCrTa thin film showed bettor crystalline and magnetic characteristics than CoCr thin film. As a result of investigating magnetic properties of CoCr and CoCrTa magnetic layer on introducing the Si underlayer, perpendicular coercivity and saturation magnetization of CoCr/Si and CoCrTa/Si bilayered thin film were decreased due to the increased grain size and diffusion of Si atoms to magnetic layer. And they showed constant with increasing the film thickness of Si thin film. However, in case of CoCrTa/Si bilayered thin film, in-plane coercivity was controlled low at about 250Oe. The c-axis orientations of CoCr/si and CoCrTa/Si bilayered thin film showed a good crystalline characteristics as about $2^{\circ}$.

A Study on the Characteristics of Computerized Tomographic X-Ray Film (CT X선용(線用)필름의 특성(特性) 연구(硏究))

  • Lee, Man-Koo;Kang, Se-Sik;Lee, Jae-Wan
    • Journal of radiological science and technology
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    • v.10 no.1
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    • pp.49-53
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    • 1987
  • This thesis compared and analyzed the characteristics, centered on a characteristic curve, about X-ray computerized tomographic film generally used in Korea recently. The results were as follows: 1. Maximum gradient (gamma) was film A-2.19, film B-2.00, film C-1.92. 2. Latitude was confined within the limits of density 0.6-2.0 in all. 3. When we changed window center from 0 to 40, the difference of density, which was in 1.0, was film A-0.12, film B-0.16, fil m C-0.14. 4. When we changed window width from 0 to 500, the difference of density, which was in 1.0, was film A-0.06, film B-0.08, film C-0.05. 5. In the case of window width 50 and window center 20, latitude was 0.5-2.0, 0.5-2.2, 0.5-1.9 and gamma value was 1.74, 1.82, 1.72 respectively, 6. In the case of window width 80 and window center 30, latitude was 0.6-2.2, 0.6-2.3, 0.8-2.2 and gamma value was 2.0, 2.13, 1.95 respectively.

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