• Title/Summary/Keyword: field investigation

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Investigation of Solvent Effect on the Electrical Properties of Triisopropylsilylethynyl(TIPS) Pentacene Organic Thin-film Transistors (용제에 따른 TIPS(triisopropylsilyl) Pentacene을 이용한 유기박막 트렌지스터의 전기적 특성에 관한 연구)

  • Kim, K.S.;Kim, Y.H.;Han, J.-In;Choi, K.N.;Kwak, S.K.;Kim, D.S.;Chung, K.S.
    • Journal of the Korean Vacuum Society
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    • v.17 no.5
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    • pp.435-441
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    • 2008
  • In this paper, we investigated the electrical properties of triisopropylsilyl (TIPS) pentacene organic thin-film transistor (OTFT) depending on solvent type. We spin coated TIPS pentacene by using chlorobenzene, p-xylene, chloroform, and toluene as solvents. Fabricated OTFT with chlorobenzene shows field-effect mobility of $1.0{\times}10^{-2}cm^2/V{\cdot}s$, on/off ratio of $4.3{\times}10^3$ and threshold voltage of 5.5 V. In contrast, with chloroform, the mobility is $5.8{\times}10^{-7}cm^2/V{\cdot}s$, on/off ratio of $1.1{\times}10^2$ and threshold voltage of 1.7 V. Moreover we measured the grain size of each TIPS pentacene solvent by atomic force microscopy (AFM). From these results, it can be concluded that a solvent with higher boiling point results in better electrical characteristics due to large grain size and high crystallinity of TIPS pentacene layer. In this paper TIPS pentacene with chlorobenzene shows the best electrical properties.

Characteristics and Drug Release Profiles of Multilamellar Vesicle(MLV) and Microemulsified Liposome(MEL) Entrapped 5-Fluorouracil and Its derivatives (5-Fluorouracil과 그 유도체를 봉입한 Multilamellar Vesicle(MLV)과 Microemulsified Liposome(MEL)의 특성 및 약물방출 거동)

  • Jee, Ung-Kil;Park, Mok-Soon;Lee, Gye-Won;Lyu, Yeon-Geun
    • Journal of Pharmaceutical Investigation
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    • v.25 no.3
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    • pp.249-264
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    • 1995
  • Although liposome has many advantages as a pharmaceutical dosage form, its application in the industrial field has been limited because of some problems such as preparation method, reproducibility, scale-up, stability and sterilization etc. Liposomes prepared by microemulsification method had defined size, narrow size distribution, reproducibility and high entrapment efficiency. For enhancing the stability, the dry form of liposome was recommended. These types of liposome are proliposome and freeze-dried liposome. The liposome must have some properties for preparing of freeze-dried liposome; small size $(50{\sim}200\;nm)$, narrow size distribution and cryoprotectant. In this experiment, the liposomes containing 5-Fluorouracil(5-FU) and its prodrug(pentyl-5-FU-1-acetate; PFA, hexyl-5-FU-1-acetate; HFA) were made with soybean phosphatidylcholine, cholesterol, stearylamine(SA) and dicetyl phosphate(DCP) employing hydration method or microemulsification method using $Microfluidizer^{TM}$. Both or liposome types were MLV and MEL. After preparation, freeze drying and rehydration were performed. In the process of freezing, trehalose(Tr) was added as a cryoprotectant. Their evaluation methods were as follows; entrapment efficiency, mean particle size and size distribution, dissolution test, retain of entrapment efficiency and turbidity after freeze-drying. The results are summarized as belows. The entrapment efficiency of 5-FU was dependent on total lipid concentration and cholesterol content but that of PFA and HFA was decreased when cholesterol was added. When DCP and SA were added, entrapment efficiency was decreased. As the partition coefficient of drug was increased, entrapment efficiency was increased. Under the same condition, entrapment efficiency of MEL is similar to that of MLV. The mean particle size and size distribution of MEL were smaller than those of MLV. Dissolution rates of drug from both liposome types were comparatively similar. Dissolution rates of drugs with serum and liver homogenate were faster than without these material. After preparation of liposome, free drug was removed efficiency by Dowex 50W-X4. When liposome was freeze-dried and then rehydrated in the presence of Tr, characteristics of liposome were maintained well in MEL than MLV. Tr Was used successfully as a cryoprotectant in the process of freeze drying and the optimal ratio of Tr:Lipid was 4:1(g/g).

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Studies on Geology and Mineral Resources of the Okchŏn Belts -Geological Structure of the Areas between Pyŏngchang, Yŏngwŏl and Jechŏn- (옥천대(沃川帶)의 지질(地質) 및 광물자원(鑛物資源)에 관(關)한 연구(硏究) -평창(平昌)~영월(寧越)~제천지역(堤川地域)의 지질구조(地質構造)-)

  • Kim, Ok Joon;Park, Pong Soon;Min, Kyung Duck
    • Economic and Environmental Geology
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    • v.18 no.4
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    • pp.369-379
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    • 1985
  • The geological structures and some of the stratigraphy in the area studied are being thought to be ambiguous and controvertible. The present study intended to clarify these ambiguities by correct interpretation of the geological structures and lithostratigraphy of the area concerned. The so-called "Sambangsan formation", which was designated as an unknown age by the Taebaksan Geological Investigation Corps (1962) and as the mid Cambrian age by T. Kobayashi (1966) and I.S. Kim (1983), has been determined by the present study as the $Hongj{\breve{o}}m$ series of Carbo-Permian age resting unconformably on the Cambro-Ordovician limestone formations. This determination was supported by conodont study concurrently carried out by I.S.Kim. The so-called "Daehari formation", which was renamed by the later study group after the original "Sambangsan formation" distributed in the area from southwest of Sambangsan toward southwest to $Juch{\breve{o}}n$, possesses more or less the same lithlogy as "Sambangsan formation" of the old designation in the eastern of the area, but different lithology in the western localities where Sadong formation, the basal sandstone member of the Kobangsan formation and the green shale member of the Nokam formation are cropped out. The narrow belt of the complex mixture of the $Py{\breve{o}}ngan$ group in-between limestone formations extending over 16km with a width of 500m to 1000m was formed by the faults: the northern boundary with the limestone formations is a fault contact all the way through entire area and the southern boundary is either fault contact in most of the area and unconformity in some other area. The $Hongj{\breve{o}}m$ formation on the Mt. Sambangsan shows rather steeply dipping nearly isoclinal folds which plunges $10^{\circ}$ to $20^{\circ}$ southward. There are also field evidences that the limestone formations distributed in both north and south of the Hongjom formation (erstwhile "Sambangsan formation") along the Sambangsan ridge are the same formations and show the same folding as the $Hongj{\breve{o}}m$ formation. Therefore, these limestone formations should be rezoned in the light of the new structural interpretation although they were differently designated in the previous studies as $Py{\breve{o}}ngchang$ and $Y{\breve{o}}ngw{\breve{o}}l$-type of the Joson Group. The structures developed in the area mostly faults, which acted as one of the guides for the new interpretation of the geology and structure of the area are described and shown on the geologic map.

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Stress factors by personality type of students department of dental hygiene who will take national examination soon and countermeasures (국가시험을 앞둔 치위생과 학생들의 성격유형에 따른 스트레스 요인 및 대처방안)

  • Heo, Nam-Suk;Park, Jeong-Hee;Kim, Eun-Hee
    • Journal of Korean society of Dental Hygiene
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    • v.9 no.2
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    • pp.57-71
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    • 2009
  • This study aims to investigate the stress factors of students in Dental Hygiene Department who will soon take the national examination, corresponding countermeasures and relationship of internal and external personality. On the basis of the results from investigation, this study will identify the methods to effectively cope with stress and to take the national examination with more positive thinking for the students and faculty members in Dental Hygiene Department, who have to pass the difficult test, the national examination. The structured questionnaires were given to junior students in Dental Hygiene Department in three colleges, to identify the stress factors, methods to deal with stress and A/B personality types. For the stress factor by field, the M college showed significantly higher stress about curriculum and assignment than the C college. In the stress factor analysis by item, the lack of information on national examination in the test area, all items in learning environment, a quantity of assignment that doesn't help the preparation of national examination in the assignment area, and lack of information on employment in job area demonstrated the significant difference(p<0.05). For the methods of subjects to deal with stress, several subcategories of long-term and short-term adaptation had significance. In case of the methods to deal with stress by personality type, B type in the short-term adaptation method in M college and A type in the long-term adaptation method in C college were significantly higher(p<0.05). As for the correlation between the population sociological features and stress factors by personality type, health status had the high correlation with test in the test area. In other areas, the travel hours to school showed the significant correlation. The higher the records were, the longer the travel hours were and the better the health status was, the higher the long-term adaptation method scores were. Moreover, the personality of A type showed the higher scores in the long-term adaptation method than that of B type. The health status and personality type showed the significant correlation(p<0.05). In conclusion, it is required to prevent any situations b identify the personality type and stress reasons of the students in Dental Hygiene Department who will take the national examination soon. The additional requirement is the continuing interest and counseling of faculty members to help students to cope with stress with positive attitude.

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Residue Levels of Chlorpyrifos and Chlorothalonil in Apples at Harvest (Chlorpyrifos 및 Chlorothalonil의 사과 생산단계별 잔류특성)

  • Kim, Young-Sook;Park, Ju-Hwang;Park, Jong-Woo;Lee, Young-Deuk;Lee, Kyu-Seung;Kim, Jang-Eok
    • Korean Journal of Environmental Agriculture
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    • v.22 no.2
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    • pp.130-136
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    • 2003
  • An organophosphorus insecticide, chlorpyrifos and an arylnitrile fungicide, chlorothalonil commonly used far apple were subjected to a residual investigation under field conditions to ensure safety of terminal residues at harvest. After pesticides were applied at standard rate in apple tree fer 15 days for chlorpyrifos and 30 days far chlorothalonil, persistence of their residues in apple was investigated by several interval. At harvest, residual concentrations of chlorpyrifos and chlorothalonil in apple were 1.3 and 2.4mg/kg, respectively, and the residue levels were higher than MRL 1.0 mg/kg in Korea. As well fitted by the first-oder kinetics, biological half-lives of the pesticide residues in apple were 9.3 days for chlorpyrifos and 32.2 days for chlorothalonil. During the storage, half-lives of chlorpyrifos and chlorothalonil were 35.0 and 56.3days at room temperature, and 120.7 and 182.8 days at 412, respectively. Distribution of chlorpyrifos residue in flesh, fruit skin and stalk cavity of each apple corresponded to 0.1% 22.8% and 77.1%, respectively. In case of chlorothalonil, residue in flesh, fruit skin and stalk cavity was 4.4%, 10.4% and 85.2%, respectively.

Analysis of the Secondary Chemistry Materials at 5 Centers for the University Affiliated Science-Gifted Education and Investigation of the Gifted Students' Perception (대학부설 5개 과학영재교육원의 중등화학 교재 분석과 영재학생들의 인식 조사)

  • Lee, Sang Kwon;Mo, Ran
    • Journal of Science Education
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    • v.36 no.1
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    • pp.106-119
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    • 2012
  • In order to promote national competition on knowledge based-society in 21centuries, it is important for us to train talented people who have much creativity. Comparing curriculums and contents studied in SECG (Science Education Center for the Gifted) and other organizations is object of this thesis. Finding implications of proper GATE(gifted and talented education) by understanding the present conditions is also a part of this thesis. We select 5 Science Education Centers for the Gifted and devise framework for analysis in order to analyze chemical textbooks in GATE programs. The framework consists of 6 categories including the contents, the level of activities, the opening extent of experiments, and the ability to think creatively. In our study of textbooks, we have found that the contents of chapters are divided properly but lacked the field of frontier and convergence science. Their activity types will have to develop programs which consist of various activities such as lectures and experiments. Precedent studies and study activities to promote scientific thinking were rated highly in general ratio. The level of studies that we analyzed lacked creative activities very much. In the opening extent of experiments, activities in the level 2 and the level 3 were low-rate. And in our study of thinking creatively, activities of promotion for expanded and related-ability to think seemed to lack. In order to achieve specific education for the gifted children, developments of GATE program is required. In the in-depth analysis from the questionnaires of Likert's method's descriptions, narrations, and interviews, it is divided into two answers in depth: contents of program, management of program. These also divided into two answers by attitude: positive answer or negative answer. According to the responses of the contents of program, the result of analysis shows that most respondents have positive reactions to not only contents and the managing method of SECG programs, but also to individual enhancing-abilities overall.

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Oak Forests of the Daegok-cheon Petroglyphs Area in Ulsan, South Korea (울산 대곡천 암각화 유적지 일대의 참나무림 다양성과 분포 특성)

  • Lee, Gyeong-Yeon;Kim, Jong-Won
    • Korean Journal of Ecology and Environment
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    • v.50 no.1
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    • pp.126-136
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    • 2017
  • We describe characteristics of diversity and distribution of oak forests on the Daegok-cheon gorge of the Southeastern Korean Peninsula, the oldest prehistoric site, in view of a sort of food resources of acorns. The $Z{\ddot{u}}rich$-Montpellier School's method was adopted for field investigation on the oak dominant stands. A total of 20 phytosociological $relev\acute{e}s$ composed of 193 taxa were analyzed by syntaxonomy and ecological flora. The Daegok-cheon's oak forests occupied 36.9% ($513,374m^2$) of the surveyed area, and its 99% ($507,677m^2$) was Quercus variabilis and Q. serrata stands. Oak forests of the Daegok-cheon gorge are a kind of regional vegetation type characterizing by the high relative net contribution degree (r-NCD) of Platycarya strobilacea and Sapium japonicum, which are an edaphic type of the xerophilous and thermophilic oak forests. The region of the Daegok-cheon petroglyphs is defined as an ecoregion with rich acorn supply and abundant water resources, and the warmer environment, which attracts prehistoric man.

A Study on the Printed Books of Ch'un-ch'iu(春秋) Commentary in Chosun Dynasty Period (조선시대에 간인(刊印)된 "춘추(春秋)" 판본(板本)에 관한 서지적(書誌的) 연구)

  • Yeom, Chong-Il;Song, Il-Gie
    • Journal of the Korean Society for Library and Information Science
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    • v.41 no.4
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    • pp.331-346
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    • 2007
  • The purpose of this study is to research into the characteristics of the printed hooks of ${\ulcorner}$Ch'un-ch'iu(春秋)${\lrcorner}$ commentary in Chosun dynasty by analyzing the types and forms of the existing printed books through the investigation of the bibliographic records of the books. To achieve this purpose, this study selected some of the 'Chak-pan' catalog(冊板目錄) printed in Chosun dynasty which has relatively clear and accurate history and investigated the block printing's condition of the printed books of ${\ulcorner}$Ch'un-ch'iu(春秋)${\lrcorner}$ commentary. In addition. a comprehensive book catalog of ${\ulcorner}$Ch'un-ch'iu(春秋)${\lrcorner}$ commentary was created by retrieving old book catalog from databases by several authoritative information centers and university libraries. Based on this catalog, this research created a new 'Union Catalog(綜合書目)' which contains bibliographies of the ${\ulcorner}$Ch'un-ch'iu(春秋)${\lrcorner}$ commentary through field investigations by identifying, picture-taking. and copying the real books. The new union catalog functions as the basis of the bibliographic analysis of this research.

Application of Laser-Induced Breakdown Spectroscopy (LIBS) for In-situ Detection of Heavy Metals in Soil (토양내 중금속 실시간 탐지를 위한 레이저 유도붕괴 분광법의 활용에 대한 소개)

  • Ko, Eun-Joung;Hamm, Se-Yeong;Kim, Kyoung-Woong
    • Economic and Environmental Geology
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    • v.40 no.5
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    • pp.563-574
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    • 2007
  • Laser induced breakdown spectroscopy (LIBS) is a recently developed analytical technique that is based upon the measurement of emission lines generated by atomic species close to the surface of the sample, thus allowing their chemical detection, identification and quantification. With powerful advantages of LIBS compared to the conventional analytical methodology, this technique can be applied in the detection of heavy metals in the field. LIBS allows the rapid analysis by avoiding laborious chemical steps. LES have already been applied for the determination of element concentration in a wide range of materials in the solid, liquid and gaseous phase with simplicity of the instrument and diversity of the analytical application. These feasibility of rapid multi elemental analysis are appealing proprieties for the in-situ analytical technique in geochemical investigation, exploration and environmental analysis. There remain still some limitations to be solved for LIBS to be applied in soil environment as an in-situ analytical technology. We would like to provide the basic principle related to the plasma formation and laser-induced breakdown of sample materials. In addition, the matrix effect, laser properties and the various factors affecting on the analytical signal of LIBS was dealt with to enhance understanding of LIBS through literature review. Ultimately, it was investigated the feasibility of LIBS application in soil environment monitoring by considering the basic idea to enhance the data quality of LIBS including the calibration method for the various effects on the analytical signal of LIBS.

Development of artificial bait for octopus drift line (문어 흘림낚시용 인공미끼 개발)

  • An, Young-Il;Arimoto, Takafumi
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.43 no.4
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    • pp.291-300
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    • 2007
  • The crayfish-shaped artificial bait for octopus drift line is manufactured, into which is made to insert ordinary bait. The effects of the artificial bait are confirmed through the analysis of octopus' behavior in the laboratory in comparison with the existing bait of pig-fat skin, and the investigation of the octopus catch on the sea, and in addition, the examination of the water quality in relation to the bait to be inserted into the artificial bait is done together. The artificial bait is red in color, 10.5cm in the length of the body, and 29g in weight. The octopus behavior in relation to the bait in the laboratory has shown a good result in which more than 30% of the octopuses rushed to the artificial bait. In the analysis of the octopus sitting time by the bait, the octopus stayed longer with the artificial bait(63.7%) than the pig-fat skin(25.1%). The octopus sitting time at the artificial bait inserted with frozen squid(48.8%, 44.6%) is shown to be longer than that of the pig-fat skin(36.9%) or boiled fish paste(21.2%). In the analysis of sitting frequency to the bait, the case of the artificial bait(total 17 times) was more than that of the pig-fat skin(total 3 times), and the case of the artificial bait with frozen squid attracted the octopuses more frequently than that of the pig-fat skin or the boiled fish paste. In the field experiment, the fishing boat A(Manseon-ho, 1.22tons) caught the total 93 octopuses, while the fishing boat B(Ilho-ho, 0.73tons) caught the total 154 octopuses, all of which weighed less than 9.0kg. In the comparison with the total catch, the case with the artificial bait was a little higher than that of the pig-fat skin($^{**}p\;<\;0.05$). In the analysis of the water quality in relation to the baits, the COD showed the descending order of frozen squid(0.57mg/g), boiled fish paste(0.18mg/g), and pig-fat skin(0.10mg/g), and the case with frozen squid was the highest and the case of the pig-fat skin, lowest. The total phosphorus, like the COD, showed the highest in frozen squid(0.02mg/g), and in case of the total nitrogen, unlike the COD, the pig-fat skin was shown to be the highest(0.006mg/g).