• Title/Summary/Keyword: fiber surface treatment

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Gas Adsorption Characteristics of by Interaction between Oxygen Functional Groups Introduced on Activated Carbon Fibers and Acetic Acid Molecules (활성탄소섬유에 도입된 산소작용기와 초산 분자와의 상호작용에 따른 가스 흡착 특성)

  • Song, Eun Ji;Kim, Min-Ji;Han, Jeong-In;Choi, Ye Ji;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.30 no.2
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    • pp.160-166
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    • 2019
  • In this study, oxygen functional groups were introduced on activated carbon fibers (ACFs) by oxygen plasma treatment to improve the adsorption performance on an acetic acid which is a sick house syndrome induced gas. The active species was generated more as the flow rate of the oxygen gas increased during the plasma treatment. For this reason, the specific surface area (SSA) of the ACFs decreased with much more physical and chemical etching. In particular, the SSA of the sample (A-O60) injected with an oxygen gas flow rate of 60 sccm was reduced to about $1.198m^2/g$, which was about 6.95% lower than that of the untreated samples. On the other hand, the oxygen content introduced into the surface of ACFs increased up to 35.87%. Also, the adsorption performance on the acetic acid gas of the oxygen plasma-treated ACFs was improved by up to 43% compared to that of using the untreated ACFs. It is attributed to the formation of the hydrogen bonding due to the dipole moments between acetic acid molecules and oxygen functional groups such as O=C-O introduced by the oxygen plasma treatment.

The Effect of Crystallization by Heat Treatment on Electromagnetic Interference Shielding Efficiency of Carbon Fibers (열처리 온도에 의한 구조 결정성이 탄소섬유의 전자파 차폐 성능에 미치는 영향)

  • Kim, Jong Gu;Chung, Choul Ho;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.22 no.2
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    • pp.138-143
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    • 2011
  • To investigate the electromagnetic interference shielding efficiency (EMI SE) property based on heat treatment effects of carbon fibers in various temperatures, the polyacrilonitrle-based carbon fibers were prepared by electrospinning method and treated at 1073, 1323, 1873 and 2573 K. The surface morphology of carbon fibers was investigated by using FE-SEM and the carbon crystallization was studied by Raman spectroscopy based on effects of reaction temperatures. The electrical conductivity was obtained by measuring the surface resistance with four probe method on carbon crystallization. The permittivity, permeability and EMI SE were investigated by using S-parameter in the range of 800~4500 MHz. In case of carbon fibers treated at 2573 K, the improved carbon crystallization was confirmed by Raman spectrum and the enhanced electrical conductivity showing 54.7 S/cm was also observed. The permittivity was dramatically improved by factor of 4 based on effect of high reaction temperature. Eventually, the highly improved EMI SE value was obtained showing around 41.7 dB.

A Three-dimensional Biomechanical Model for Numerical Simulation of Dynamic Pressure Functional Performances of Graduated Compression Stocking (GCS)

  • Liu, Rong;Kwok, Yi-Lin;Li, Yi;Lao, Terence-T;Zhang, Xin;Dai, Xiao-Qun
    • Fibers and Polymers
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    • v.7 no.4
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    • pp.389-397
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    • 2006
  • The beneficial effects of graduated compression stockings (GCS) in prophylaxis and treatment of venous disorders of human lower extremity have been recognized. However, their pressure functional performances are variable and unstable in practical applications, and the exact mechanisms of action remain controversial. Direct surface pressure measurements and indirect material properties testing are not enough for fully understanding the interaction between stocking and leg. A three dimensional (3D) biomechanical mathematical model for numerically simulating the interaction between leg and GCS in dynamic wear was developed based on the actual geometry of the female leg obtained from 3D reconstruction of MR images and the real size and mechanical properties of the compression stocking prototype. The biomechanical solid leg model consists of bones and soft tissues, and an orthotropic shell model is built for the stocking hose. The dynamic putting-on process is simulated by defining the contact of finite relative sliding between the two objects. The surface pressure magnitude and distribution along the different height levels of the leg and stress profiles of stockings were simulated. As well, their dynamic alterations with time processing were quantitatively analyzed. Through validation, the simulated results showed a reasonable agreement with the experimental measurements, and the simulated pressure gradient distribution from the ankle to the thigh (100:67:30) accorded with the advised criterion by the European committee for standardization. The developed model can be used to predict and visualize the dynamic pressure and stress performances exerted by compression stocking in wear, and to optimize the material mechanical properties in stocking design, thus, helping us understand mechanisms of compression action and improving medical functions of GCS.

A Study on the Ignition Delay Effect by Flame-Resistance Paint Treatment (방염 처리에 따른 화재지연 효과 연구)

  • Oh, Kyu-Hyung;Kim, Hwang-Jin;Lee, Sung-Eun
    • Fire Science and Engineering
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    • v.23 no.2
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    • pp.111-116
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    • 2009
  • 17 kinds of fire resistant paint which are currently used were painted on the MDF(middle density fiber board), which suitable to the regulation of Fire Service Act. And we investigate a ignition delay effect under a exposure condition of radiative heat of fire. Radiative heat flux was controlled from $10kW/m^2$ to $30kW/m^2$ using the cone heater. Ignition time, ignition type and surface temperature of the sample were measured. Based on the experimental result, critical heat flux of the fire resistant paint treated sample was $10kW/m^2$ and there were no ignition delay effect above the $30kW/m^2$. And it was found that it will be difficult to expect the fire resistant effect above $400^{\circ}C$ of sample surface temperature.

Conservation of a Bronze Incense Burner from Chungung-dong, Hanam (하남시 춘궁동 출토 청동현향로(靑銅懸香爐)의 제작기술과 보존처리)

  • Jeong, Subin;Park, Haksoo
    • Conservation Science in Museum
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    • v.16
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    • pp.32-45
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    • 2015
  • The bronze incense burner, discovered in Chungung-dong, Hanam, Gyeonggi-do in 1971, is a hanging incense burner dating from the Goryeo period. The incense burner was covered with a thick layer of clay. The object was in a severely deteriorated state, affected by bronze disease which resulted in extensive corrosion. Numerous cracks were present across its surface, and some parts had been broken off. To preserve and display the bronze incense burner in a stable condition, deposits of foreign material were removed from the surface, and the weakened metal was strengthened. Cracked and broken areas were reinforced using woven glass fiber, followed by the application of epoxy resin to restore the shape. To investigate the method of production, a chemical analysis was performed, and the microstructure was examined. The chemical analysis revealed that the body of the incense burner as well as the ear, loop, lid and the knob were cast in a ternary alloy of Cu-Sn-Pb. Moreover, copper nails with high copper content were used to securely join the ear to the body of the incense burner. The microstructure was mainly α-phase, and non-intermetallic inclusions composed of Cu and S were detected.

Investigation of Paper Characteristics on Old Documents Related to the Head Family of Admiral Yi Sun-sin (이충무공 종가 관련 고문서의 지질 특성 조사)

  • Ahn, Ji Yoon;Bae, Su Bin
    • Journal of Conservation Science
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    • v.34 no.5
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    • pp.407-420
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    • 2018
  • Old documents related to the head family of admiral Yi Sun-shin have been preserved by the descendants of Deoksu Yi clan and various kinds of documents have remained even today. Seven documents issued by the king,"Goshin Gyoji", "Jeunggik Gyoji", "Gyochub", "Gyoseo", "Yuseo", "Hongpae", and "Chikmyung", showed the time when they were made. Because they have been kept in their original form, these documents make it possible to identify the characteristics of the paper used to create documents during that time and to compare the records in those documents with other cultural properties based on scientific investigation and analysis of conservation treatment processing. The characteristics of Oebal-tteugi(Heulim-tteugi) in the papermaking process were identified through the shape of the surface fibers, and Dochim processing was found in most of the old documents with the help of density measurement and paper surface analysis. All the papers were found to be made of paper mulberry, and bast fibers of mature mulberry were mainly used for the process.

Evaluation of cavitation characteristics for anodized 5000 series Al alloy with various sealing treatment in sea water (양극산화 기술이 적용된 5000계열 알루미늄 합금의 다양한 실링처리에 따른 해수 내 캐비테이션 특성 평가)

  • Jo, Chung-Hui;Park, Il-Cho;Kim, Seong-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.146-146
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    • 2016
  • 최근 국민 소득향상과 더불어, 여가시간 증가에 따라 해양레저에 대한 관심이 크게 높아지고 있으며, 그에 따라 레저용 선박 수요도 증가하고 있다. 기존 국내 소형 선박의 경우 FRP(fiber-reinforced plastic)재료로 선박을 건조해 왔다. 그러나 해양환경 규제 강화로 FRP 선박의 건조가 감소하고 있으며, 친환경 선박에 대한 필요성이 대두되고 있다. 따라서 FRP재료를 대체하는 선박용 재료로 친환경적이고 가벼운 소재인 알루미늄 합금 재료가 선박건조 분야에서 각광을 받고 있다. 특히 5000계열 Al-Mg 합금은 가공성과 용접성이 우수하여 주로 구조용으로 많이 사용되고 있으나 경량화에 따른 빠른 선속이 유체충격을 증가시켜 선체에 캐비테이션 손상을 일으킬 수 있다. Al-Mg 합금의 경우에 부식성이 대단히 큰 해양환경에서 부식과 캐비테이션 침식이 복합적으로 일어나면 손상이 빠르게 증가되는 경향을 나타내어 선박의 수명을 현저히 단축시켜 경제적인 손실을 초래한다. 따라서 본 연구에서는 해수 내에서 Al-Mg 합금의 캐비테이션 저항성을 향상시키기 위해 알루미늄 합금 표면에 내식성 뿐만 아니라 경도 및 내마모성 등의 기계적 특성이 우수한 산화피막을 형성시키는 양극산화 기술을 적용하고, 다양한 봉공처리(sealing)방법에 따른 캐비테이션 특성을 평가하였다. 캐비테이션 실험은 압전(piezoelectric) 효과를 이용한 진동발생 장치를 사용하여 $30{\mu}m$ 진폭으로 일정하게 유지하였으며, 시편과 혼 팁 사이의 간격은 1mm로 하였다. 캐비테이션 실험 후에는 시편을 초음파 세척하여 진공 건조기에서 24시간 이상 건조한 후 정밀저울로 무게를 측정하였으며, 표면 손상 형상을 분석하기 위해 주사전자현미경(SEM)과 3D현미경을 이용하여 관찰하였다.

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The Physical, Mechanical, and Sound Absorption Properties of Sandwich Particleboard (SPb)

  • ISWANTO, Apri Heri;HAKIM, Arif Rahman;AZHAR, Irawati;WIRJOSENTONO, Basuki;PRABUNINGRUM, Dita Sari
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.1
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    • pp.32-40
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    • 2020
  • While the utilization of wood as a raw material in related industries has been increasing with the population increasing, the availability of wood from natural forests has continued to decline. An alternative to this situation is the manufacture of particleboard from non-wood lignocellulose materials through the modification of sandwich particleboard (SPb) using bamboo strands as reinforcement. In this study, strandsof belangke bamboo (Gigantochloa pruriens W) and tali bamboo (Gigantochloa apus) were utilized. The non-wood particles included sugar palm fibers, cornstalk, and sugarcane bagasse. The board was made in a three-layer composition of the face, back, and core in a ratio of 1: 2: 1. The binder used was 8% isocyanate resin. The sheet was pressed at a temperature of 160℃ for 5 min under a pressure of 3.0 N/㎟. Testing included physical and mechanical properties based on the JIS A 5908 (2003) standard, while acoustic testing was based on ISO 11654 (1997) standards. The results showed that using bamboo strands as reinforcement has an effect on the mechanical and physical properties of SPb. Almost all the types of boards met the JIS A 5908 (2003) standards, with the exception of thickness swelling (TS) and internal bond (IB) parameters. Based on the thickness swelling parameter, the C-type board exhibited the best properties. Overall, the B-type board thatused a belangke bamboo strand for the surface and sugarcane bagasse as the core underwent the best treatment. Based on the acoustical parameter, boards using a tali bamboo strand for the surface and sugar palm fiber as the core (E-type board) exhibited good sound absorption properties.

Effect of Preparation Conditions of PAN-based Carbon Fibers on Electrochemical Characteristics of Rechargeable Lithium ion Battery Anode (PAN계 탄소섬유 제조조건에 따른 리튬이온 이차전지 음극의 전기화학적 특성)

  • An K. W.;Lee J. K.;Lee S. W.;Kim Y. D.;Cho W. I.;Ju J. B.;Cho B. W.;Park D. G.;Yun K. S.
    • Journal of the Korean Electrochemical Society
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    • v.2 no.2
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    • pp.81-87
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    • 1999
  • Poly-acrylonitrile (PAN) based carbon fibers were stabilized under various tensions in the presence of air at about $200^{\circ}C$ and sequentially carbonized under some different gas environments in the range of 700 to $1500^{\circ}C$. The prepared carbon fibers were used for rechargeable lithium ion battery anode to investigate preparation parameters effects on electrochemical characteristics. It was found that the tension during stabilization, carbonization temperature and gas atmospheres affect the carbon fiber properties such as conductivity, mechanical strength, surface morphology and diffusion coefficient of lithium ion, which are closely related to the on electrolchemical properties as well as the charge/discharge characteristics.

Morphological features of Cyclosprin A-induced Gingial Hyperplasia (Cyclosporin A에 의한 치은 과증식의 형태학적 특성)

  • Moon, Hyun-Ju;Kim, Chang-Sung;Suh, Jong-Jin;Park, Ji-Sook;Yoon, Jung-Hoon;Cho, Kyoo-Sung;Choi, Seong-Ho
    • Journal of Periodontal and Implant Science
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    • v.30 no.3
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    • pp.609-619
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    • 2000
  • Cyclosporin A(CsA) is now widely used to treat organ transplant recipients. But CsA has various short-and long-term side effects. Especially, gingival hyperplasia is not easy to resolve since its nature is still unknown. This study discusses the pathogenesis of CsA-induced gingival hyperplasia on the basis of data obtained from light and electron microscopic studies of biopsis from patients on CsA treatment after kidney transplantation. Light microscopically, the multilayered squamous epithelium showed an irregular surface of parakeratosis and deep invaginations in the subepithelial tissue. At lamina propria, we observed bundles of irregularly arranged collagen fiber, some fibroblasts, numerous capillary vessels and a large diffuse infiltration of plasma cells. Ultrastructurally, many fibroblasts, collagen fibers, collagen fibrils were present in lamina propria. On the basis of the data collected, we propose that the morphological features of the dimensional increase in gingival tissue associated with CsA treatment in kidney transplant patients may be considered proliferative fibroblasts, collagen fibers, collagen fibrils in lamina propria.

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