• Title/Summary/Keyword: fiber surface treatment

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Preparation of highly hydrophobic PVDF hollow fiber composite membrane with lotus leaf-like surface and its desalination properties

  • Li, Hongbin;Zi, Xingchen;Shi, Wenying;Qin, Longwei;Zhang, Haixia;Qin, Xiaohong
    • Membrane and Water Treatment
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    • v.10 no.4
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    • pp.287-298
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    • 2019
  • Lotus leaf has a special dual micro and nano surface structure which gives its highly hydrophobic surface characteristics and so-called self cleaning effect. In order to endow PVDF hollow fiber membrane with this special structure and improve the hydrophobicity of membrane surface, PVDF hollow fiber composite membranes was obtained through the immersion coating of poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) dilute solution on the outside surface of PVDF support membrane. The prepared PVDF composite membranes were used in the vacuum membrane distillation (VMD) for the desalination. The effects of PVDF-HFP dilute solution concentration in the dope solution and coating time on VMD separation performance was studied. Membranes were characterized by SEM, WCA measurement, porosity, and liquid entry pressure of water. VMD test was carried out using $35g{\cdot}L^{-1}$ NaCl aqueous solution as the feed solution at feed temperature of $30^{\circ}C$ and the permeate pressure of 31.3 kPa. The vapour flux reached a maximum when PVDF-HFP concentration in the dilute solution was 5 wt% and the coating time was kept in the range of 10-60 s. This was attributed to the well configuration of micro-nano rods which was similar with the dual micro-nano structure on the lotus leaf. Compared with the original PVDF membrane, the salt rejection can be well maintained which was greater than 99.99 % meanwhile permeation water conductivity was kept at a low value of $7-9{\mu}S{\cdot}cm^{-1}$ during the continuous testing for 360 h.

Adhesion Improvement of Polymer/Metal Interface Produced by Surface Treatment (표면 처리에 의한 고분자/금속 계면에서의 접착력 향상)

  • 박수진;서민강;김학용;이덕래
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.489-492
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    • 2002
  • 고분자/금속 복합재료는 현대 전자산업에 중요한 역할을 하고 있다. 그러나 이들간의 계면은 고분자의 수축 또는 계면 안정성의 저하로 인하여 박리가 일어나게 된다. 즉, 계면의 접합이 떨어지게 되면 전기 화학적인 반응이 계면에서 발생하여 드러난 금속부위는 산화되고 산소가 환원될 때 발생하는 OH기와 같은 라디칼들에 의해 금속과 고분자 사이의 결합이 파괴되어 금속표면으로부터의 고분자의 박리가 발생한다. (중략)

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The Effect of Oxygen Low Temperature Plasma Treatment on the Wettability of Polypropylene Fabrics (폴리프로필렌 직물의 젖음성에 관한 연구)

  • Kwon, Young-Ah
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.307-308
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    • 2003
  • Improved wettability and dyeability of Polypropylene(PP) fabrics were obtained using glow discharge plasma by grafting nitrogen-containing active groups on the surface. Few studies of glow discharge plasma on PP fabrics exist. The objective of this study was to give a fabric a good affinity for water. (omitted)

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Surface Treatment of Activated Carbon Fibers in Increasing Ammonia Removal (암모니아 제거를 위한 활성탄소섬유의 표면처리)

  • 신준식;박수진;김학용;이덕래
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.153-154
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    • 2003
  • 최근 대기오염이 건강에 미치는 영향에 대한 연구가 본격적으로 시작되면서 대기오염의 심각성을 보여주는 각종 사례들이 보고 되고 있으며, 일반인도 더 이상 도시 대기오염의 수준이 안전하지 않다는 인식을 갖게 되었다. 이러한 대기 오염의 원인으로는 여러 가지가 있겠으나, 이 중 암모니아는 무색의 가연성 가스로 보통 재래식 화장실에서 맡을 수 있는 특유의 자극적인 냄새로 고농도의 암모니아를 맡으면 인체에 만성적 질환뿐만 아니라 지속적인 흡입 시에는 호흡정지를 일으킬 수 있다고 보고 되고 있다. (중략)

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Alkaline Softening of $TiO_2$ Delustered Polyester Fabrics ($TiO_2$로 소광가공된 폴리에스테르 직물의 알칼리 유연가공에 관한 연구)

  • 이정순
    • Journal of the Korean Society of Clothing and Textiles
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    • v.20 no.1
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    • pp.157-169
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    • 1996
  • Polyester yarns and fabrics containing three levels of $TiO_2$ delusterant were hydrolyzed with NaOH and examined for physical and morphological changes. The mechanical propertis and hand values of alkaline hydrolyzed polyester fabrics were measured using KES-FB system. Also, the relationship between the morphology and the mechanical property of alkaline hydrolyzed polyester fabrics was analyzed. The results are as follows: 1. At an initial stage of alkaline treatment, the concentration of $TiO_2$ did not affect the weight loss of the treated yarns. But by increasing treatment time, the effect of the concentration of $TiO_2$ on the weight loss of the fiber became more pronounced. The weight loss were increased in the following order; fulldull> semidull> clear 2. The effect of hydrolysis on yarn tensile strength seems to be more related to the size of the pits on the fibers rather than the number of pits. 3. Axially oriented pits occurred along the hydroyzed, delustered fiber surfaces, while such pitting was absent on hydrolyzed fiber containing no $TiO_2$. The number of voids across the surface of a fiber increased with an increase in the amount of TiOa incorporated into the fibers. The size of the voids depended on the treatment time of hydrolysis rather than the concentration of TiOa. 4. The mechanical properties and hand values of polyester fabrics were changed by alkaline treatment but were identical regardless of the concentration of TiOa. While the mechanical properties of polyester fabrics depended on the structural change of the fibers and the yarns within the fabrics as the fiber diameter became progressively smaller rather than the size and number of pits.

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Modification of Wool Fiber by Enzymatic Treatment(II) -The Dyeing Behavior of Wool Fiber Enzyme-treated- (효소처리에 의한 양모섬유의 개질 (II) -효소처리 양모의 염색성 고찰 -)

  • 김태경;심창섭;조민정;임용진
    • Textile Coloration and Finishing
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    • v.5 no.3
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    • pp.206-215
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    • 1993
  • In the prior study, wool gabardines were treated with alkaline proteases which were some kinds of enzyme to decompose protein, and their tensile strengths were determined, and the surface of the fibers were also observed using a scanning electron microscope. Enzylon ASN 30 and Alkalase 2.5L DX did not show much effect on the weight loss of wool, however, the weight loss of wool increased considerably with treating Esperase 8.0L. Pretreatment of wool with dichloloisocyanuric acid before protease-treatment increased the weight loss of wool to a great extent. In this study, the enzyme treated wools dyeing behaviors with acid dye, Milling Cyanine 5R, were mainly investigated. The protease-treatment remarkably increased not only the rate of dyeing but also the saturation dye uptake. From these results, it seemed likely that the structural relaxation of adhesive filler of interscale or intercellular cement facilitated the dye penetration into the fibers, at the same time, the change in the inner structure of the wool fibers by the protease made the fixation of the dyes more efficient.

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Preparation and properties of glass fiber-reinforced endodontic (root canal therapy) posts (유리섬유 강화 근관치료 포스트의 제조 및 특성에 대한 연구)

  • Son, Jae-Yong;Kim, Kyoung-Ja;Kim, Kyoung-Hun;Park, Joo-Seok;Shim, Kwang-Bo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.3
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    • pp.105-110
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    • 2015
  • The fiber-reinforced endodontic posts were prepared using a photocurable resin and a glass fiber. The mechanical property of the posts increased with increasing density of glass fiber and the micro-pores in the post were removed by a vacuum impregnation process. To improve the interfacial adhesion between glass fiber and polymer, silane coupling agent was used. The surface treatment of glass fiber increased the surface wettability of resing on glass fiber and increased the adhesion property with resin, consequently improved the mechanical property of posts.

Preparation of Fine Silk Powder and It′s Application for Surface Modification (폐견사류의 미세분말화 및 표면 가공제 적용)

  • 이용우;이광길;여주홍;김종호
    • Journal of Sericultural and Entomological Science
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    • v.43 no.1
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    • pp.41-48
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    • 2001
  • The purification, dissolution and powdering of stained waste silk obtained from weaving and dyeing process were studied for the surface modification of textile fabric and plastic materials. The whiteness of stained waste silk could be improved through degumming and bleaching with sodium hydrosulfite. The water-soluble fibroin solution can be obtained by dissoving the degummed waste silk in a boiling solution of 50% calcium chloride for 60 minutes. The salts and heavy metals contained in fibroin solution were removed by electric dialysis, wool fiber filtration and gel filtration chromatography. The fibroin powder was prepared by using a fine grinder after the alkali treatment for weakening the silk fiber. The fine fibroin powder of particle size around 30 ㎛ was obtained with a ultra fine-mill, while it was finer below 10 ㎛ with a ball-mill. The dissolved or powdered silk was applied to the surface of fabric with addition of the binder (a urethane resin). The moisture content of polyester and nylon fabrics treated with the silk solution was improved due to hygroscopic property of silk. The fine fibroin powder mixed with the binder ws coated on the surface of synthetic film by use of the air pressed sprayer. It was revealed that the hygroscopicity as well as the softness of fibroin powder coated film was much improved. Therefore, it is thought that the fine silk fibroin powder is applicable as an coating agent for the surface modification of plastic and synthetic leather.

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Influence of high energy electron beam treatment on the photocatalytic activity of $TiO_2$ nanoaparticles on carbon fiber

  • Sim, Chae-Won;Kim, Myeong-Ju;Seo, Hyeon-Uk;Kim, Gwang-Dae;;Kim, Dong-Un;Nam, Jong-Won;Jeong, Myeong-Geun;Lee, Byeong-Cheol;Park, Ji-Hyeon;Kim, Yeong-Dok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.441-441
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    • 2011
  • $TiO_2$ nanoparticles were grown on carbon fiber by atomic later deposition (ALD) with TTIP $(Ti(OCH(CH_3)_2)_4$ and $H_2O$ precusors. After sampe surfaces were treated by electron beam (1 MeV, 5 KGy), an improvement in the photocatalytic reacitivity of $TiO_2$ nanoparticles on carbon fiber was observed. An increase in the population of hydroxyl group on $TiO_2$ particles and the oxidation of carbon fiber were found upon e-beam exposure, whereas there was no noticeable changes of their morphology. It implies that those changes in O and C 1s state of $TiO_2$ particles/carbon fiber induced by e-beam treatment could be related to the enhancement of the photocatalytic activity. In contrast, when carbon fiber fully covered with $TiO_2$ thick films was treated with high-energy electron beam under same conditions, the improvement of photocatalytic activity as well as any changes in XPS spectra (Ti 2p, O 1s and C 1s) could not be found.

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