• 전기화학회지
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• 제18권3호
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• pp.115-120
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• 2015

Rayon 분리막에 poly(ethylene oxide) (PEO)를 코팅하고 potassium polyacrylate (PAAK)-KOH 하이드로겔 전해질을 사용하여 기계적 강도 및 전기화학적 성질을 시험하였고, 이를 활성탄 수퍼커패시터에 적용하여 커패시터 특성을 조사하였다. PEO 코팅량의 증가에 따라 기계적 강도는 증가하였으며, PEO 함량을 5 wt.% 이하로 유지하면 이온전도도가 $10^{-2}S\;cm^{-1}$ 이상을 유지하여 실제 커패시터에의 활용이 가능하였다. 결과적으로 Rayon/PEO 분리막과 PAAK/KOH 전해질을 적용한 활성탄 수퍼커패시터는 $1000mV\;s^{-1}$의 높은 스캔속도에서도 비축적용량이 1000 사이클까지 안정하게 나타나는데, 이는 PEO 코팅이 Rayon의 장섬유 필라멘트간 엉킴점을 고정시켜 고출력 안정성을 얻을 수 있기 때문이다.

• 한국세라믹학회지
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• 제50권6호
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• pp.364-371
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• 2013

The sintering behavior of monolithic SiC is examined using the binary sintering additive of $Al_2O_3$-rare earth oxide ($RE_2O_3$, where RE = Sc, Nd, Dy, Ho, or Yb). Through hot pressing at 20 MPa and $1750^{\circ}C$ for 1 h in an Ar atmosphere for 52 nm fine ${\beta}$-SiC powder added with 5 wt% sintering additive, a SiC density of > 97% is achieved, which indicates the effectiveness of $Al_2O_3-RE_2O_3$ system as a sintering of additive for SiC. Based on this result, 7 wt% of $Al_2O_3-Sc_2O_3$ is tested as an additive system for the fabrication of a continuous SiC fiber-reinforced SiC-matrix composite ($SiC_f$/SiC). Electrophoretic deposition combined with the application of ultrasonic pulses is used to efficiently infiltrate the matrix phase into the voids of $Tyranno^{TM}$-SA3 fabric. After hot pressing, a composite density of > 97% is obtained, along with a maximum flexural strength of 443 MPa.

• Geomechanics and Engineering
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• 제10권6호
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• pp.757-774
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• 2016

Soils are usually weak in tension therefore different materials such as geosynthetics are used to address this inadequacy. Worldwide annual consumption of geosynthetics is close to $1000million\;m^2$, and the value of these materials is probably close to US$1500 million. Since the total cost of the construction is at least four or five times the cost of the geosynthetic itself, the impact of these materials on civil engineering construction is very large indeed. Nevertheless, there are several significant problems associated with geosynthetics, such as creep, low modulus of elasticity, and susceptibility to aggressive environment. Carbon fiber reinforced polymer (CFRP) was introduced over two decades ago in the field of structural engineering that can also be used in geotechnical engineering. CFRP has all the benefits associated with geosynthetics and it boasts higher strength, higher modulus, no significant creep and reliability in aggressive environments. In this paper, the performance of a CFRP reinforced retaining wall is investigated using the finite element method. Since the characterization of behavior of soils and interfaces are vital for reliable prediction from the numerical model, soil and interface properties are obtained from comprehensive laboratory tests. Based on the laboratory results for CFRP, backfill soil, and interface data, the finite element model is used to study the behavior of a CFRP reinforced wall. The finite element model was verified based on the results of filed measurements for a reference wall. Then the reference wall simulated by CFRP reinforcements and the results. The results of this investigations showed that the safety factor of CFRP reinforced wall is more and its deformations is less than those for a retaining wall reinforced with ordinary geosynthetics while their construction costs are in similar range.

• 한국전산구조공학회논문집
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• 제22권6호
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• pp.597-605
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• 2009

본 연구에서는 철근 보강된 Engineered Cementitious Composite(ECC) 면내요소에 대한 2축응력 상태에서의 면내전단거동에 관한 예측 모델을 제시하였다. 기존의 철근콘크리트와 상이한 특성, 즉 ECC 요소의 복수미세균열 현상에 의한 높은 연성의 인장 거동, 일반 콘크리트에 비하여 연성적인 압축 연화 거동, 그리고 ECC 균열면에서의 전단전달 거동 특성 등을 모델에 반영하였다. 면내 순수전단거동에 대한 실험 및 해석결과를 통하여 개발된 R-ECC-MCFT 모델은 ECC 면내전단거동 예측에 효과적인 것으로 평가되었다. 또한 철근 보강된 ECC 면내요소는 철근콘크리트 면내요소에 비하여 최대전단강도 및 전단변형률이 증가하기 때문에 면내전단변형에서 높은 연성을 확보하는 것으로 평가되었다.

• Macromolecular Research
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• 제12권1호
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• pp.119-126
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• 2004

In this study, the influence of silane coupling agents, featuring different organo-functional groups on the interlaminar and thermal properties of woven glass fabric-reinforced nylon 6 composites, has been by means of short-beam shear tests, dynamic mechanical analysis, scanning electron microscopy, and thermogravimetric analysis. The results indicate that the fiber-matrix interfacial characteristics obtained using the different analytical methods agree well with each other. The interlaminar shear strengths (ILSS) of glass fabric/nylon 6 composites sized with various silane coupling agents are significantly improved in comparison with that of the composite sized commercially. ILSS of the composites increases in the order: Z-6076 with chloropropyl groups in the silanes > Z-6030 with methacrylate groups> Z-6020 with diamine groups; this trend is similar to that of results found in an earlier study of interfacial shear strength. The dynamic mechanical properties, the fracture surface observations, and the thermal stability also support the interfacial results. The improvement of the interfacial properties may be ascribed to the different chemical reactivities of the reactive amino end groups of nylon 6 and the organo-functional groups located at the ends of the silane chains, which results from the increased chemical reactivity in order chloropropyl > methacrylate > diamine.

• Elastomers and Composites
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• 제1권1호
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• pp.49-55
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• 1966

Based upon the results of the previous work, the experiments are concentrated on the improvement of the durability of rubber coated fabrics as a rain garment material. To obtain a much lighter and durable coated fabric, several kinds of light weight cotton prints having almost equal density in warp and fillingwise were chosen. Rubber coating on these prints was made by topping and spreading process using rubber compound of various viscosity, and the physical properties of final product were analysed and interpreted in terms of adhesion and durability. The results are as follows. 1. Any noticeable difference between two coating processes was not found in terms of physical properties. 2. Base fabrics should be dipped once into a dilute rubber compound before coating operation in order to obtain a uniform adhesion and physical properties, and the optimum range of the viscosity of dipping paste are from 100 poise to 200 poise. 3. Generally, the tearing strength of the coated fabrics is inversely proportional to the adhesion. 4. It was assumed that the increase of the water proofness after water immersion on the finished material which have dense base fabric is chiefly due to the swelling of the cellulosic fiber.

• 한국지반공학회논문집
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• 제19권2호
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• pp.279-289
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• 2003

국내에 보강토 옹벽이 도입된지 20여 년이 다 되어가고, 많은 구조물들이 시공되었다. 특히, 콘크리트 패널식 전면체와 섬유보강재를 적용하는 시스템은 국내에 가장 널리 알려진 공법이다. 이 공법의 섬유보강재는 고강도 폴리에스테르 섬유와 LDPE 피복층을 갖는 구조를 가지고 있으며, 섬유보강재를 이용한 설계에서는 몇가지 합리적이지 못한 부분이 존재해 왔다. 설계인자의 결정이 선행된 외국데이터를 기준으로 하여 간접적인 방법에 의해 이루어졌으며 보강재의 장기크리프 거동에 대해서도 마찬가지로 인용된 자료를 이용하여 왔다. 따라서 본 연구에서는 실내시험을 통하여 직접적으로 섬유보강재의 설계인자를 도출하고자 하였으며, 그 결과, 설계연한동안 예상되는 크리프 허용강도는 최대파단강도의 약 60%였으며 크리프 감소계수는 1.67로 나타났다.

• 한국건설관리학회논문집
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• 제15권4호
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• pp.49-57
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• 2014

최근 건설 구조물의 다양화, 대형화, 고층화 및 장지간화 되면서 콘크리트 구조재료에 관한 고성능화가 요구되고 있으며, 특히 콘크리트의 고강도 및 고성능화가 대두되고 있다. 콘크리트의 고성능화 및 재료 특성을 개선하는 방법으로 주로 첨단소재 기술에 의해 개발된 첨단 섬유를 적용하는 방법이 사용되어 왔으며, 고성능 섬유시멘트 복합체(이하 HPFC)를 적용한 콘크리트 기둥 공법이 그 중 하나이다. 본 연구는 시뮬레이션 기법을 활용해, 일반 RC 기둥 대비 프리캐스트 기법이 적용된 HPFC 기둥 공법 공정에 대한 작업프로세스를 분석함과 동시에, 수집한 작업데이터를 통해 HPFC 기둥 공법의 공정계획상 이슈를 도출하였다. 그 결과 생산성에 가장 영향이 큰 작업(노드)로 '콘크리트 작업조', '형틀 작업조'로 도출되었으며, 특히 '콘크리트 작업조'가 공정계획상 가장 중요한 요소로 작용함을 확인할 수 있었다. 해당 작업(노드)에 투입되는 작업조 수 변화를 통한 생산성 향상을 확인하였으며 본 연구를 바탕으로 HPFC 기둥 공법의 실용화 단계에 도움이 될 것으로 예상된다.

• Carbon letters
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• 제18권
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• pp.18-23
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• 2016

Polyacrylonitrile (PAN)-based carbon fibers have high specific strength, elastic modulus, thermal resistance, and thermal conductivity. Due to these properties, they have been increasingly widely used in various spheres including leisure, aviation, aerospace, military, and energy applications. However, if exposed to air at high temperatures, they are oxidized, thus weakening the properties of carbon fibers and carbon composite materials. As such, it is important to understand the oxidation reactions of carbon fibers, which are often used as a reinforcement for composite materials. PAN-based carbon fibers T300 and T700 were isothermally oxidized in air, and microstructural changes caused by oxidation reactions were examined. The results showed a decrease in the rate of oxidation with increasing burn-off for both T300 and T700 fibers. The rate of oxidation of T300 fibers was two times faster than that of T700 fibers. The diameter of T700 fibers decreased linearly with increasing burn-off. The diameter of T300 also decreased with increasing burn-off but at slower rates over time. Cross-sectional observations after oxidation reactions revealed hollow cores in the longitudinal direction for both T300 and T700 fibers. The formation of hollow cores after oxidation can be traced to differences in the fabrication process such as the starting material and final heat treatment temperature.

• 한국안전학회지
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• 제20권4호
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• pp.14-19
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• 2005

One area in which composites have been used rather extensively is for fabricating pressure vessel. These structures can be readily manufactured by filament winding, which is, as far as composite fabrication techniques are concerned, a relatively inexpensive method for producing composite structures. Unfortunately, the higher strength material and fabrication costs are not the only disadvantages of fiber-reinforced polymer composites when they are compared to metals. Additionally, these materials tend to exhibit brittle behavior. This is of particular concern when they are subjected to a low-velocity impact during routine handling a significant amount of structural damage can be introduced into the composites. The goals of this paper are to understand the impact damage behavior and identify the effect of surface coating materials on impact resistance in filament wound composite pressure vessels. For these, a series of low velocity impact tests was performed on specimens cutting from the full scale pressure vessel by the instrumented impact testing machine. The specimens are classified into two types with and without surface protective material. The visualization for impact damage is made by metallurgical microscope. Based on the impact force history and damage, the resistance parameters were employed and its validity in identifying the damage resistance of pressure vessel was reviewed. As the results, the impact resistance of the filament wound composites and its dependency on the protective material were evaluated quantitatively.