• Title/Summary/Keyword: ferrous iron

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Long Term Evaluation of UF Membrane process using River-bed Water (복류수를 이용한 한외여과공정의 장기운전 평가)

  • Kim, Chung H.;Lim, Jae L.;Kang, Suk H.;Kim, Su H.
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.4
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    • pp.429-436
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    • 2008
  • Membrane system has been increasingly considered as a safe and cost-effective water treatment process especially in case of small scale water works. This research is a basis of membrane application in water works through a long period test with obtaining operation skills and evaluation of water quality and cost competitiveness. For the research, the UF membrane system was installed in small water treatment plant that uses river-bed water as raw water. The system was consisted of 2 stage membrane and operated in constant flow mode (Flux: 1.5, 1.0, 0.9, 0.6). In each different flux condition, TMP trends were showed better results at lower flux condition. And through the high flux condition test, it is certified that membrane system could deal with breakdown of one stage. Water quality of permeate was satisfied the water quality standards especially turbidity. To know what mainly causes fouling on membrane, the test by membrane with several cleaning agents and EDX analysis have done in lab. Through the tests, ferrous concentration in raw water, backwashing water and membrane surface etc. was high and it causes fouling inside and outside of membrane. So acid cleaning using organic acid such as oxalic acid is necessary in Chemical in Place (CIP). At the economical aspect the electrical cost of membrane system is higher than that of slow sand filtration but labor cost can be reduced by automation. However, the use of labor should be determined considering effectiveness and stability of operation. Because during the operation, there are several breakdown such as electrical shock by lightning, water drop in summer, etc.

Analysis and Separation of Constituent Materials of Old Car by Shredding Process (폐자동차 파쇄를 통한 주요구성물질의 분리 및 분석평가)

  • Lee Hwa-Young;Oh Jong-Kee;Kim Sung-Gyu
    • Resources Recycling
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    • v.11 no.4
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    • pp.11-16
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    • 2002
  • Analysis and separation of constituent materials of old car have been performed by using the industrial shredding line. For this aim, three old cars made by domestic automobile manufacturers, Sonata II, Sephia and Prince were chosen and delivered in pressed form without engine, tires and doors, etc. Shredding line was substantially composed of pre- and main-shredder. cyclone, magnetic separation, eddy current separation and man-power separation. From the separation of shredder products, iron scrap was observed to be the major material of old car accounting for 60.1 % of total weight and non-ferrous metals involving Al, Cu and Zn, etc. were about 2%. Light fluff, about 90% of total fluff product, was comprised with plastic, fiber and sponge, etc. and the fraction of 5 cm undersize in light fluff was 70.5%. In case of heavy fluff, however. rubber and plastic were found to be the major constituent materials of it. Among the constituent materials of fluff, plastic showed the highest calorific value, more than 10,000 cal/gr and leather and rubber showed relatively high chlorine content, 10.3 and 2.55 wt%, respectively.

The Effect of Organic Acids in Decontamination Solution on Ion Exchange of Metal Ions (제염용액내 유기산이 금속이온 이온교환에 미치는 영향)

  • Yang, Yeong-Seok;Kang, Young-Ho;Jheong, Gyeong-Rak
    • Applied Chemistry for Engineering
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    • v.4 no.1
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    • pp.171-177
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    • 1993
  • In decontamination process to remove radioactive materials of reactor cooling system, the metal ions dissolved by organic acids in decontamination solution are separated by use of ion exchange resin in the column. However, organic acids in decontamination solution decrease the apparent affinity of the resin to metal ions. In light of this, some experiments were carried out on the Amberlite IRN-77 cation resin with cobalt and iron to gain a better understanding of the complexation effects on the ion exchange process. Experimental results showed that EDTA among organic acids used as chemical decontaminants predominantly caused reduction of ion exchange capacity of cobaltous ion to resin since this reagent formed the complex with the cobaltous ion stronger than that with the ferrous ion. In contrast, the effects of oxalic acid and citric acid were found to be negligible. And, single and two-component nonlinear equilibrium relationships of the metal ions were established using experimental data.

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An Electrochemical Method to Predict Corrosion Rates in Soils

  • Dafter, M.R
    • Corrosion Science and Technology
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    • v.15 no.5
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    • pp.217-225
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    • 2016
  • Linear polarization resistance (LPR) testing of soils has been used extensively by a number of water utilities across Australia for many years now to determine the condition of buried ferrous water mains. The LPR test itself is a relatively simple, inexpensive test that serves as a substitute for actual exhumation and physical inspection of buried water mains to determine corrosion losses. LPR testing results (and the corresponding pit depth estimates) in combination with proprietary pipe failure algorithms can provideauseful predictive tool in determiningthe current and future conditions of an asset. Anumber of LPR tests have been developed on soil by various researchers over the years1), but few have gained widespread commercial use, partly due to the difficulty in replicating the results. This author developed an electrochemical cell that was suitable for LPR soil testing and utilized this cell to test a series of soil samples obtained through an extensive program of field exhumations. The objective of this testing was to examine the relationship between short-term electrochemical testing and long-term in-situ corrosion of buried water mains, utilizing an LPR test that could be robustly replicated. Forty-one soil samples and related corrosion data were obtained from ad hoc condition assessments of buried water mains located throughout the Hunter region of New South Wales, Australia. Each sample was subjected to the electrochemical test developed by the author, and the resulting polarization data were compared with long-term pitting data obtained from each water main. The results of this testing program enabled the author to undertake a comprehensive review of the LPR technique as it is applied to soils and to examine whether correlations can be made between LPR testing results and long-term field corrosion.

Effects of Holotrichia on damages of liver tissue induced by bromobenzene in rats (제조가 Bromobenzene에 의(依)한 흰쥐의 간손상(肝損傷)에 미치는 영향(影響))

  • Han, Jeong-Hoon;Shin, Hyeon-Chul;Yoon, Cheol-Ho;Kim, Jong-Dae;Jeong, Ji-Cheon;Shin, Uk-Seob
    • The Journal of Korean Medicine
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    • v.19 no.1
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    • pp.49-65
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    • 1998
  • Holotrichia was tested for the effects on damages of liver tissue induced by bromobenzene. Holotrichia was treated firstly into samples, and then bromobenzene intoxicated animal models were set with them. In vitro, the level of lipid peroxide in tissue of liver proportinally decreased with the level of concentration of extract prepared from Holotrichia It was much more decreased, when lipid peroxidation was induced with ferrous iron ($Fe&{+2}$). In vivo, after the extract was administered to the animal model for twenty days, the level of lipid peroxide in liver decreased compared to that of bromobenzene-treated group. The enzyme activities of epoxide hydrolase and glutathione S-transferase in liver highly increased in Holotrichia pre-medicating group compare with the group treated with only bromobenzene. And we can get the same results in the enzyme activities of superoxide dismutase, catalase and glutathione peroxidase. The level of glutathione followed by Holotrichia pre-medicationg administration, increased as highly as normal group in compare with the group treated with only bromobenzene. Also, the enzyme activities of AL T, AST and $\{gammer}-GTP$ in liver considerably decreased. In conclusion, Holotrichia recovers the damage of liver due to bromobenzene intoxication by the increased activities of lipid peroxidation and bromobenzene scavenging enzymes.

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Mössbauer Study of (Fe0.95Ni0.05)7Se8 ((Fe0.95Ni0.05)7Se8의 뫼스바우어 분광학적 연구)

  • Kim, Eng-Chan
    • Journal of the Korean Magnetics Society
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    • v.24 no.2
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    • pp.41-45
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    • 2014
  • By M$\ddot{o}$ssbauer spectroscopy and x-ray measurement $(Fe_{0.95}Ni_{0.05})_7Se_8$ has been studied. The crystal structure of $(Fe_{0.95}Ni_{0.05})_7Se_8$ is found to be a triclinic superstructure of the NiAs sturcture while $Fe_7Se_8$ has a orthohexagonal superstructure. Abrupt changes of quadrupole shifts near 125 K for $(Fe_{0.95}Ni_{0.05})_7Se_8$ suggests that the spin-rotation transition proceeds abruptly, in contrast with the gradual transition reported for $Fe_7Se_8$ with a triclinic superstructure. Isomer shifts indicate a ferrous state for the iron ions at all four states.

Machine vision applications in automated scrap-separating research (머신비젼 시스템을 이용(利用)한 스크랩 자동선별(自動選別) 연구(硏究))

  • Kim, Chan-Wook;Lee, Seung-Hyun;Kim, Hang-gu
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2005.05a
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    • pp.57-61
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    • 2005
  • In this study, the machine vision system for inspection using color recognition method have been designed and developed to automatically sort out a specified material such as Cu scraps or other non-ferrous metal scraps mixed in Fe scraps. The system consists of a CCD camera, light sources, a frame grabber, conveying devices and an air nozzled ejector, and is program-controlled by a image processing algorithm. The ejector is designed to be operated by an I/O interface communication with a hardware controller. The sorting examination results show that the efficiency of separating Cu scraps from the Fe scraps mixed with Cu scraps is around 90 % at the conveying speed of 15 m/min. and the system is proven to be excellent in terms of its efficiency. Therefore, it is expected that the system can be commercialized in shredder firms, if the high-speed automated sorting system will be realized.

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Urban Mine Resources and Metals Recycling Industries in Japan (일본(日本)의 도시광산(都市鑛山)(사용후제품) 자원(資源)과 금속(金屬) 재자원화산업(再資源化産業))

  • Oh, Jae-Hyun;Kim, Joon-Soo;Moon, Suk-Min;Min, Ji-Won
    • Resources Recycling
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    • v.19 no.6
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    • pp.11-26
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    • 2010
  • In order to review the recycling status of urban mine resources in Japan, metal consumption, metal recycling rate and metal recycling industry such as iron scrap, end of life vehiclcs(ELV), waste home appliances and spent IT equipments were surveyed. Japan took rank of top class in the world on the metal consumption and urban mine stock reserve. Metal recycling industries in Japan have been developed through excellent technologies for mineral processing and non-ferrous smelting. On the other hand, the technologies for recycling of rare metals are being developed now. Recycling rate of EL V, waste home appliances and personal computer are higher than the guidelines of the legislative standard.

Molecular Cloning and Characterization of a Flavanone-3-hydroxylase Gene from Rubus occidentalis L.

  • Lee, Seung Sik;Lee, Eun Mi;An, Byung Chull;Barampuram, Shyamkumar;Kim, Jae-Sung;Cho, Jae-Young;Lee, In-Chul;Chung, Byung Yeoup
    • Journal of Radiation Industry
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    • v.2 no.3
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    • pp.121-128
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    • 2008
  • Flavanone-3-hydroxylase (F3H) is one of the key enzymes for the biosynthesis of flavonals, anthocyanins, catechins and proanthocyanins. F3H catalyzes the $3{\beta}$-hydroxylation of (2S)-flavonones to form (2R, 3R)-dihydroflavonols. In this report, we isolated a full-length cDNA of RocF3H from black raspberry (Rubus occidentalis L.) using a reverse transcriptase-PCR and rapid amplification of the cDNA ends (RACE)-PCR. The full-length cDNA of RocF3H contains a 1,098 bp open reading frame (ORF) encoding a 365 amino acid protein with a calculated molecular weight of about 41.1 kDa and isoelectric point (pI) of 5.45. The genomic DNA analysis revealed that the RocF3H gene had three exons and two introns. Comparison of the deduced amino acid sequence of the RocF3H with other F3Hs revealed that the protein is highly homologous with various plant species. The conserved amino acids ligating the ferrous iron and the residues participating in the 2-oxoglutarate binding (R-X-S) were found in RocF3H at the similar positions to other F3Hs. Southern blot analysis indicated that RocF3H exist a multi-gene family. The isolation of RocF3H gene will be helpful to further study the role of F3H gene in the biosynthesis of flavonoids in R. occidnetalis.

Current Status of Zinc Smelting and Recycling (아연의 제련 및 리사이클링 현황)

  • Sohn, Ho-Sang
    • Resources Recycling
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    • v.28 no.5
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    • pp.30-41
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    • 2019
  • Global production of zinc is about 13 million tons and zinc is the fourth-most widely used primary metal in the world following iron, aluminum and copper. When zinc is recycled to produce secondary zinc, it can save about 75 % of the total energy that is needed to produce the primary zinc from ore, and in therms of $CO_2$ emissions reduced by about 40 %. However, since zinc is mainly used for galvanizing of steel, the recycling rate of zinc is about 25 %, which is lower than other metals. The raw materials for recycling of zinc include dusts generated in the production of steel and brass, sludge in the production process of non-ferrous metals, dross in the melting of zinc ingots or hot dip galvanizing, waste batteries, and metallic scrap. Among them, steelmaking dust and waste batteries are most actively recycled up to now. Most of the recycling process uses pyrometallurgical methods. Recently, however, much attention has been given to a combined process of pyrometallurgical and hydrometallurgical processes.