• Journal of Korean Society on Water Environment
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• v.23 no.5
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• pp.600-606
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• 2007

Livestock wastewater containing concentrated organic matters and nutrients has been known as one of the major pollutants. It is difficult to apply the conventional activated sludge process to treat livestock wastewater because of high Non-biodegradable (NBD) matter and ammonia. The objectives of this study are to remove NBD matters including aromatic compounds and ammonia in livestock wastewater using Coagulation-Fenton oxidation-Zeolite (CFZ) processes and ascertain applicable feasibility in the field through pilot plant experiment. NBD matters and color remained in the treated water were removed over 92% by Fenton oxidation as the second treatment process. Ammonia was removed by over 99.5% in the zeolite ion exchange process as the last treatment method. From $UV_{254}$, $E_2/E_3$ ratio and GC/MS analyses of treated water at each process, the aromatic compound was converted to aliphatic and aromaticity was decreased. In pilot scale test, organics and ammonia removal efficiencies were not much different from the result of lab-scale test at various operation conditions. Furthermore, reaction time and dosage of Fenton reagent in pilot scale experiment reduced by 40 min and 50% rather than in lab-scale test. $BOD_5$, $COD_{Mn}$, SS, T-N and T-P of treated water in the pilot-scale experiment also met the effluent standards.

• Journal of Photoscience
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• v.9 no.2
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• pp.138-141
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• 2002

A photo-labile compound which is bioinactive but, upon irradiation with light, yields bioactive species is called as "caged compound". Photolysis of caged compounds generating bioactive species, has become a general method to produce a desired amounts of bioactive species in the specific time interval at the desired place or area of the target biological systems. For this purpose, we designed and synthesized caged hydroxyl radical., "Photo-Fenton Reagent" NP-IIl. NP-IIl has a strong absorption maximum at 377 nm and yields hydroxyl radicals upon UV light irradiation. The antioxidant activity of the ${\alpha}$ -lipoic acid and other naturally occurring compounds has been examined by using NP-IIl as a molecular probe. For example, upon photoirradiation of NP-lII with BSA or apolipoprotein of human low density (LDL), the significant oxidative modifications were observed in both cases. The oxidation was completely suppressed in the presence of ${\alpha}$-lipoic acid, which clearly demonstrates the strong hydroxyl radical scavenging activity of ${\alpha}$-lipoic acid. Other applications of NP-lII will also be described

• Proceedings of the Korean Environmental Health Society Conference
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• 2002.04a
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• pp.23-25
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• 2002

This study was conducted to understand characteristics of wastewater which is discharged from small-scale dyehouse located in Seoul downtown area and to Find the appliable treatment method on the spot. The results of this study were summarized as followings. 1. The method which is used at present is mostly flocculation by coagulant or fenton oxidation. But the treatment efficiency of them are not good. 2. The results of fenton oxidation experiment demonstrated that treatment efficiency of COD was limited, which showed the need of the additional process or the improvement of existing treatment method, while the color was reduced considerably in optimal condition. 3. The optimal condition of fenton oxidation are as followings. -Feasible pH was in the 3∼4 regardless of the kinds of iron ions, But the fluctuation of treatment efficiency with the change of pH was small - The mass ratio of H$_2$O/CODcr was used to evaluate the parameter of H$_2$O$_2$ The optimal range of this was in 0.7∼1,3 and it was observed that the ratio got higher as the quality got worse. -For iron ion, FeCl$_2$4H$_2$O turned out to be more effective for removal of color compared with was compared FeSO$_4$7H$_2$Oin. the mass ratio of Fe/H$_2$O$_2$ of 2.3∼2.8 for of FeSO$_4$7H$_2$O and 1.6∼1.8 for FeCl$_2$4H$_2$O resulted in good treatment efficiencies. 4. With adsorption process applied before fenton oxidation in order to treat the high concentration wastewater, the treatment efficiency increased by 61％ in CODcr, 55％ in color. and if the power activated carbon is injected in more than 2500mg/$\ell$, the wastewater can be treated within the effluent quality criteria.

• Journal of Soil and Groundwater Environment
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• v.18 no.1
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• pp.26-35
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• 2013

Outbreak of animal infectious diseases such as foot-and-mouth disease, avian influenza are becoming prevalent worldwide. For prevent the further infection, tremendous numbers of the infected or culled stocks are buried around farm. This burial method can generate a wide range of detrimental components such as leachate, nutrient, salt, and pathogenic bacteria, consequently. In this study, for the stabilization of livestock carcasses leachate, advanced oxidation processes utilizing the Fenton reaction was investigated in lab-scale experiments for the treatment for $COD_{Cr}$ of livestock carcass leachate. $COD_{Cr}$ reduction by the Fenton oxidation was investigated response surface methodology using the Box-Begnken methods were applied to the experimental results. A central composite design was used to investigate the effects of the independent variables of pH ($x_1$), dosage of $FeCl_2{\cdot}4H_2O$ ($x_2$) and dosage of $H_2O_2$ ($x_3$) on the dependent variables $COD_{Cr}$ concentration ($y_1$). A 1 M NaOH and $H_2SO_4$ was using for pH control, $FeCl_2{\cdot}4H_2O$ was used as iron catalyst and NaOH was used for Fenton reaction. The optimal conditions for Fenton oxidation process were determined: pH, dosage of $FeCl_2{\cdot}4H_2O$ and dosage of $H_2O_2$ were 3, 0.6 g (0.0151 M) and 7 mL(0.259 M), respectively. Statistical results showed the order of significance of the independent variables to be pH > initial concentration of ferrous ion > initial concentration of hydrogen peroxide.

• Journal of Korean Society on Water Environment
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• v.20 no.2
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• pp.110-119
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• 2004

The combination of biological and physical/chemical technologies is a promising technique to reduce highly concentrated pollutants in livestock wastewater. It is suggested to treat livestock wastewater efficiently as follows: firstly, biodegradable organic matters, nitrogen and some of phosphorus should be removed by a biological treatment process and then residual non-biodegradable organic matters, color and phosphorus be eliminated by physicochemical technologies. In this study, therefore, the integrations of chemical coagulation, activated carbon adsorption, Fenton oxidation and ozonation were evaluated to provide appropriate post-treatment processes for biologically pre-treated livestock wastewater. After chemical coagulation followed by ozonation or Fenton oxidation process, the quality of treated wastewater could meet the discharge limit in Korea. However, a yellowish brown color still remained in the treated wastewater after a single method such as coagulation and Fenton oxidation was applied. The ozonation was found to be the most effective technology for the decolorization. Neither simple biological nor physicochemical treatment provides adequate decolorization and sufficient depletion of organics in livestock wastewater so far. Consequently, the integration of Fenton oxidation and ozonation with a biological treatment process is recommended to treat livestock wastewater in terms of removal efficiency.

• Applied Chemistry for Engineering
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• v.16 no.5
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• pp.693-697
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• 2005

We researched in the optimization of unit process and the stabilization of discharged water quality through the treatment of the occurrence of wastewater classified by place of production which has high COD load and non degradable COD load in paper industry. As the result, using polymer, inorganic flocculants and alum at the same time is effective to advance the COD value through the colloid material removal with SS in the first treatment process. Moreover, it is determined to keep optimum of $FeCl_2/H_2O_2$ in the concentration of 1000 ppm in the ratio of 1/1. Because It is confirmed that to input excess chemicals using Fenton oxidation method gives adverse effect to water quality.

• Textile Coloration and Finishing
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• v.10 no.4
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• pp.45-52
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• 1998

Reuse of wastewater become an important consideration to solve the environmental pollution problems in recent industriallzation and urbanization. Especially, he characteristic of dyeing process is subject to use much water and thus has serious problems for removal of color and organic pollutants in their wastewater. This report is divided into two main parts ： The purpose of the first part was to determine if alkaline wastewater discharged from textile dyeing operation factory could be flocculated directly by Fenton oxidation method. This study was conducted to investigate Fenton reagent dose and reaction condition of Fenton method as pretreatment for dyeing wastewater in K dyeing industry were investigated. In the second part of this research, to treat dyeing wastewater it was found that the most effective way is to use ultrafiltation and reverse osmosis at the conditions of the pH 7.0~8.0 and operating pressure of $2.5~35kg_f/cm^2$. This paper is mainly dealt with the application on reuse system of dyeing wastewater treatment using ultrafiltration and reverse osmosis membranes. The results showed that dyeing wastewater could be reused by chemical, filter and membrane sequential treatment process.

• Advances in environmental research
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• v.10 no.1
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• pp.59-86
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• 2021

Landfilling is the most commonly adopted method for a large quantity of waste disposal. But, the main concern related to landfills is the generation of leachate. The leachate is high strength wastewater that is usually characterized by the presence of high molecular recalcitrant organics. Several conventional methods are adopted for leachate treatment. However, these methods are only suitable for young leachate, having high biodegradability and low toxicity levels. The mature and stabilized leachate needs advanced technologies for its effective treatment. Advanced oxidation processes (AOPs) are very suitable for such complex wastewater treatment as reported in the literature. After going through the literature survey, it can be concluded that Fenton-based approaches are effective for the treatment of various high/low strength wastewaters treatment. The applications of the Fenton-based approaches are widely adopted and well recognized due to their simplicity, cost-effectiveness, and reliability for the reduction of high chemical oxygen demand (COD) as reported in several studies. Besides, the process is relatively economical due to fewer chemical, non-sophisticated instruments, and low energy requirements. In this review, the conventional and advanced Fenton's approaches are explained with their detailed reaction mechanisms and applications for landfill leachate treatment. The effect of influencing factors like pH, the dosage of chemicals, nature of reaction matrix, and reagent ratio on the treatment efficiencies are also emphasized. Furthermore, the discussion regarding the reduction of chemical oxygen demand (COD) and color, increase in biodegradability, removal of humic acids from leachate, combined processes, and the pre/post-treatment options are highlighted. The scope of future studies is summarized to attain sustainable solutions for restrictions associated with these methods for effective leachate treatment.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.10
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• pp.2771-2778
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• 2009

This study was performed to solve the problem of the 2nd contamination and excessive treatment cost by determining proper quantity of hydrogen peroxide, iron catalyst, mixing method, and input mode that should be provided when Fenton oxidation (this is mostly applied to small contaminated areas such as service station sites) is applied to the excavated and diesel-contaminated soil. Soil artificially contaminated with 10000mg/kg of diesel was used for the experiment. In the batch test, diesel removal seemed to increase as the concentration of hydrogen peroxide increases. When iron catalyst was added, removal efficiency of diesel was much higher than the time when hydrogen peroxide was added solely. The removal efficiency showed greater when Fe(III) was added compared to Fe(II). Column experiment was executed on the basis of results of the batch test to investigate adequate reagent mixing and input methods. The highest efficiency was acquired in the case of separate input mode. Also, it was found that when inputting Fe(III) iron catalyst and separately inputting hydrogen peroxide after dividing the bundle in the column, removal efficiency was 92.8%, which was 9 times greater than that of the first method, 10.5%, when only hydrogen peroxide was added. Thus, it is expected that if the result of this research is applied to Fenton oxidation for the remediation of soil contaminated by diesel, the problem of the 2nd contamination and excessive treatment charge caused by excessive addition of hydrogen peroxide and iron catalyst could be solved.

• Korean Journal of Materials Research
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• v.19 no.9
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• pp.481-487
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• 2009

The photocatalysts of Fe-ACF/$TiO_2$ compositeswere prepared by the sol-gel method and characterized by BET, XRD, SEM, and EDX. It showed that the BET surface area was related to adsorption capacity for each composite. The SEM results showed that ferric compound and titanium dioxide were distributed on the surfaces of ACF. The XRD results showed that Fe-ACF/$TiO_2$ composite only contained an anatase structure with a Fe mediated compound. EDX results showed the presence of C, O, and Ti with Fe peaks in Fe-ACF/$TiO_2$ composites. From the photocataytic degradation effect, $TiO_2$ on activated carbon fiber surface modified with Fe (Fe-ACF/$TiO_2$) could work in the photo-Fenton process. It was revealed that the photo-Fenton reaction gives considerable photocatalytic ability for the decomposition of methylene blue (MB) compared to non-treated ACF/$TiO_2$, and the photo-Fenton reaction was improved by the addition of $H_2O_2$. It was proved that the decomposition of MB under UV (365 nm) irradiation in the presence of $H_2O_2$ predominantly accelerated the oxidation of $Fe^{2+}$ to $Fe^{3+}$ and produced a high concentration of OH radicals.