• Title/Summary/Keyword: fast-curing

Search Result 80, Processing Time 0.028 seconds

Development of precast channel structure using polymer concrete (폴리머 콘크리트를 이용한 프리캐스트 수로구조물 개발)

  • 김관호;조태열;박광수;신수균;연규석
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2001.11a
    • /
    • pp.135-140
    • /
    • 2001
  • This study was developed high-quality a large size precast channel structure using polymer concrete to improve quality of the product as well as to enhance construction quality. Precast PC represent the fastest growing segment of the polymer concrete industry. The fast curing, high strength, and low impermeability permit thin section and rapid reuse of moulds. Developed precast channel structure will be structural experiment and analysis. Also, through an example to construct will be develop the most suitable section survey and make practicable.

  • PDF

EVOLUTION OF TRANSMISSION LOSS AND STRUCTURE IN EPOXY CURING

  • Song Hyeon-Hun;Park Jong-Hui;No Geun-Ae
    • Proceedings of the Korean Fiber Society Conference
    • /
    • 1998.10a
    • /
    • pp.280-282
    • /
    • 1998
  • Communications, data storage or computation by manipulating the optical signals have the strong advantages over the traditional electronic circuits in regard to the data handling speed and capacity. Effective manipulation of the optical signals, however, requires materials of large nonlinear coefficients and of fast response time. Polymeric materials are one of the promising materials to meet the requirements for nonlinear optical (NLO) materials. (omitted)

  • PDF

Material and rheological properties of (glycidoxypropyl) trimethoxysilane modified colloidal silica coatings

  • Kang Hyun Uk;Park Jung Kook;Kim Sung Hyun
    • Korea-Australia Rheology Journal
    • /
    • v.16 no.4
    • /
    • pp.175-182
    • /
    • 2004
  • Colloidal coating solution was prepared to enhance the hydrophilic property of the film surface. Water and ethanol were used as the dispersion media and (glycidoxypropyl) trimethoxysilane (GPS) as a binder in the colloidal silica coatings. Ethylene diamine was added to the colloidal silica solution as the curing agent. The colloidal silica solution was regarded as a hard-sphere suspension model with low volume fraction of the silica particles. Rheological properties of the silica suspensions modified with GPS have been investigated as a function of pH and concentration. The acidic solution showed high viscosity change by fast hydrolysis reaction and adsorption of the organic binders on the surface of silica particles. However, the hydrolysis was slow at the basic condition and the binders combined with themselves by condensation. The viscosity change was smallest at pH 7. The viscosity increased with the curing time after adding ethylenediamine, and the increase of viscosity at low pH was higher than that at high pH. The hydrophilic properties of the coating film were investigated by the contact angle of water and film surface. The smallest contact angle was shown under the strong acidic condition of pH 2.

Characterization of Electrically Conductive Adhesives for Shingled Array Photovoltaic Cells (전도성 접착제 물성에 따른 슁글드 어레이 태양전지 특성 평가)

  • Jee, Hongsub;Choi, Wongyong;Lee, Jaehyeong;Jeong, Chaehwan
    • Current Photovoltaic Research
    • /
    • v.5 no.3
    • /
    • pp.95-99
    • /
    • 2017
  • The interconnecting shingled solar cells method shows extremely high ratio active area per total area and has the excellent potential for high power PV (photovoltaic). Compared to the conventional module, it can have much more active area due to busbar-free structure. The properties of ECA (electrically conductive adhesives) are significant to fabricate the shingled array PV since it should be used in terms of electric and structural connection. Various ECA were tried and characterized to optimize the soldiering conditions. The open circuit voltage of shingled array cells showed a three-fold increase and efficiency was also increased by 1.63%. The shingled array cells used in CE3103WLV showed the highest power and in CA3556HF the lowest curing temperature and very fast curing time.

Study on Low Temperature Curing Emulsion of PLA Fiber for Bedding (침장용 PLA 섬유에 대한 저온 경화유제에 관한 연구)

  • Ahn, Young-Moo
    • Journal of Fashion Business
    • /
    • v.16 no.1
    • /
    • pp.41-51
    • /
    • 2012
  • Polyester is mainly used as a bedding filler material. PLA fiber as an eco-friendly material for substituting polyester has a low melting temperature and therefore a hardening process is impossible. This study is to develop the oil for feather touch that can treat at the melting temperature of PLA. The slippery and soft aminosilicone emulsion, and the bulky epoxysilicone emulsion were used. They had proper viscosity and particle size for flexibility and elasticity. When using methoxy aminosilane [$H_2NSi(OCH_3)_3$] as an aminosilane and [$Zn(OCOCH_3)_2$] as a catalyst, the hardening reaction was fast and effective. Feather touch process were treated by 2 steps. At first step, aminosilicone emulsion, epoxysilicone emulsion and methylaminosilane were mixed and homogenized, and at second step, 5% blened solution of the first step, Zn catalyst 1%, distilled water 94% were treated at PLA fiber. After treatment the static friction coefficient and dynamic friction coefficient were reduced to 23.5-60.8% and 30.0-61.3% respectively, and the laundry and sun light fastnesses have not shown any decrease.

Thermal Stability and Surface Hardnes of UV-curable Epoxy Acrylate Coatings for Wooden Flooring (마루바닥재용 자외선 경화형 에폭시 아크릴레이트 도료의 열안정성과 표면경도)

  • Hwang, Hyeon-Deuk;Choi, Jae-Hoon;Moon, Je-Ik;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
    • /
    • v.36 no.6
    • /
    • pp.121-129
    • /
    • 2008
  • Environmental friendly UV-curable coatings, having excellent hardness, gloss, mar and chemical resistance, are commonly used for the wooden flooring coatings. Especially epoxy acrylate oligomers are chosen for the wooden flooring coatings, due to their thermal stability and fast curing. In this study, we investigated the effect of the acrylate functionality on the thermal stability and surface hardness. The thermal degradations of monomers, oligomer, photoinitiator and formulated coatings with different acrylate functionality were measured using a thermogravimetric analysis (TGA). And the surface hardness was also measured with a pendulum hardness tester to compare relationship between the thermal stability and the physical property. The cured coatings became thermally stable by crosslinking during UV-curing. Both the thermal stability and surface hardness of cured coatings were improved with increasing acrylate functionality.

Improvement of Hard Coating Characteristics by UV-curable Organic/Inorganic Hybrids (자외선 경화형 유기/무기 하이브리드에 의한 하드코팅 특성 향상)

  • Han, Ji-Ho;Kim, Hyung-Il
    • Applied Chemistry for Engineering
    • /
    • v.28 no.6
    • /
    • pp.626-631
    • /
    • 2017
  • Transparent plastic substrates require an improvement in properties such as surface hardness and thermal stability for optical applications. In this study, UV-curable organic/inorganic hybrids were synthesized to improve those properties. In order to make the optimum dispersion of inorganic component into the organic matrix, an in situ synthetic method was applied based on sol-gel reaction. Dispersion of the inorganic component in the organic urethane acrylate matrix was improved by using a proper combination of sol-gel reaction and fast UV-curing resulting in the formation of the transparent coating layer. Various alkoxy silanes were employed to vary both the degree of curing and coating properties of UV-curable organic/inorganic hybrids. UV-cured organic/inorganic hybrid coatings showed an improved surface hardness and thermal resistance depending on the content of inorganic component.

Effects of Resin Compositions and Additives on Gelation Properties and Bonding Characteristics of Urea-Melamine-Formaldehyde resin adhesives (요소·멜라민 수지 접착제의 겔화성 및 접착특성에 미치는 수지조성과 첨가물의 영향)

  • Roh, Jeang-Kwan
    • Journal of the Korean Wood Science and Technology
    • /
    • v.27 no.1
    • /
    • pp.72-78
    • /
    • 1999
  • To accelerate the curing and to improve the bonding properties of urea-melamine-formaldehyde (UMF) resin adhesives for plywood, the effects of resin compositions and additives on gelation time and bonding strength were discussed. The gelation time of UMF resin prepared by simultaneous reaction with urea(U), melamine(M) and formaldehyde(F) at M/U molar ratio 0.2 was shortened as the molar ratio of formaldehyde to urea was increased. However, at F/U molar ratios higher than 2.5, the amounts of free fomaldehyde of resin could not satisfy with KS standard, Therefore, it was difficult to increase the amount of formaldehyde in resin composition for the purpose of fast gelation time. With increasing the molar ratio of melamine to urea(M/U) from 0.3 to 0.6 at constant F/U molar ratio 3.4, the gelation time of UMF resin was slightly decreased, while gradually increased at M/U molar ratio higher than 0.6. The gelation properties of UMF resin and bonding strength of UMF-bonded plywood could be enhanced by using ammonium chloride and p-toluene sulfonic acid as a curing-agent together with wheat flour and corngluten powder as a extender.

  • PDF

Study on Cure Behavior of Low Temperature and Fast Cure Epoxy with Mercaptan Hardener (Mercaptan 경화제에 의한 저온속경화 에폭시의 경화거동에 관한 연구)

  • Eom, Se Yeon;Seo, Sang Bum;Lee, Kee Yoon
    • Polymer(Korea)
    • /
    • v.37 no.2
    • /
    • pp.240-248
    • /
    • 2013
  • The curing behaviors of diglycidyl ether of bisphenol A (DGEBA) with mercaptan hardener were studied by the comparison with amine-adduct type hardener. Curing behaviors were evaluated by DSC at dynamic and isothermal conditions. In the DSC, the dynamic experiments were based on the method of Kissinger's equation, and the isothermal experiments were fitted to the Kamal's kinetic model. Activation energy of epoxy/amine-adduct type hardener was ca. 40 kcal/mol. As the functional group of mercaptan hardener, -SH increased, on epoxy/mercaptan hardeners, the activation energies decreased from 28 to 19 kcal/mol. Epoxy/amine-adduct type hardener was initiated at $90^{\circ}C$ or higher. However, epoxy/mercaptan hardeners reduced the initiation temperatures below $80^{\circ}C$ and shortened the durations of curing reaction within 10 min. We found out that the reaction kinetics of epoxy with mercaptan hardener followed the autocatalytic reaction models, and the maximum reaction rates were shown at the conversions of 20~40%.

Thermo-rheological behaviors of Phenolic Resins Blended with Petroleum-based Pitches for High Temperature Carbon Composites (석유계 피치가 첨가된 고온 탄소복합재용 페놀수지의 열 유변학적 거동 연구)

  • Yang, Jae-Yeon;Kuk, Yun-Su;Seo, Min-Kang;Kim, Byoung-Suhk
    • Composites Research
    • /
    • v.33 no.6
    • /
    • pp.329-335
    • /
    • 2020
  • In this study, the thermo-rheological behaivors of petroleum pitches with different softening points were studied, and a B-stage phenolic resins/petroleum pitches blends were prepared by adding petroleum pitches to the phenolic resins. As a result, the petroleum pitch with different softening points decreased the fluidity of the petroleum pitch as the Quinoline insoluble (QI) content increased and showed the viscous properties of the solid. In addition, the effect of adding petroleum pitches having different softening points on the thermo-rheological properties of phenolic resins was investigated. When petroleum pitch with a high softening point was added, the fluidity of the phenolic resin was reduced, and the hardening behavior was fast. It was possible to control the curing rate and curing behavior of the phenolic resin by adding petroleum pitches of different softening points. Among them, the phenolic resin mixture to which P-Pitch 2 was added has a higher fluidity than other blends under the same curing temperature condition.