• 제목/요약/키워드: fast swelling

검색결과 41건 처리시간 0.02초

Microfiltration/ultrafiltration polyamide-6 membranes for copper removal from aqueous solutions

  • El-Gendi, Ayman;Ali, Sahar;Abdalla, Heba;Saied, Marwa
    • Membrane and Water Treatment
    • /
    • 제7권1호
    • /
    • pp.55-70
    • /
    • 2016
  • Microfiltration/ultrafiltration (MF/UF) Adsorptive polyamide-6 (PA-6) membranes were prepared using wet phase inversion process. The prepared PA-6 membranes are characterized by scanning electron microscopy (SEM), porosity and swelling degree. In this study, the membranes performance has examined by adsorptive removal of copper ions from aqueous solutions in a batch adsorption mode. The $PA-6/H_2O$ membranes display sponge like and highly porous structures, with porosities of 41-73%. Under the conditions examined, the adsorption experiments have showed that the $PA-6/H_2O$ membranes had a good adsorption capacity (up to 120-280 mg/g at the initial copper ion concentration ($C_0$) = 680 mg/L, pH7), fast adsorption rates and short adsorption equilibrium times (less than 1.5-2 hrs) for copper ions. The fast adsorption in this study may be attributed to the high porosities and large pore sizes of the $PA-6/H_2O$ membranes, which have facilitated the transport of copper ions to the adsorption. The results obtained from the study illustrated that the copper ions which have adsorbed on the polyamide membranes can be effectively desorbed in an Ethylene dinitrilotetra acetic acid Di sodium salt ($Na_2$ EDTA) solution from initial concentration (up to 92% desorption efficiency) and the PA-6 membranes can be reused almost without loss of the adsorption capacity for copper ions. The results obtained from the study suggested that the $PA-6/H_2O$ membranes can be effectively applied for the adsorptive removal of copper ions from aqueous solutions.

Physicomechanical Properties Enhancement of Fast-Growing Wood Impregnated with Wood Vinegar Animal Adhesive

  • Efrida BASRI;SAEFUDIN;Mahdi MUBAROK;Wayan DARMAWAN;Jamal BALFAS;Yelin ADALINA;Yusuf Sudo HADI
    • Journal of the Korean Wood Science and Technology
    • /
    • 제51권6호
    • /
    • pp.542-554
    • /
    • 2023
  • This study is a continuation of our previous work, which focused on the resistance of jabon wood to termites after impregnation with wood vinegar (WV) and animal-based adhesive (kak). This paper presents the physicomechanical properties of fast-growing jabon wood impregnated with kak at two concentrations (8% and 10%) in wood vinegar or water as a solvent with and without 4% borax. The physical properties of the impregnation solution, that is, viscosity, density, pH, and solid content, were evaluated according to SNI 06-4567-1998. Some physical parameters, such as weight percent gain (WPG), density, water uptake, anti-swelling efficiency (ASE), crystallinity, and mechanical properties, i.e., modulus of elasticity (MOE), modulus of rupture (MOR), and compression strength parallel to the grain (CS), of the impregnated wood were determined. Based on these results, wood impregnated using a mixture of kak in WV presented better physical (increased WPG, density, dimensional stability, and crystallinity) and mechanical (increased MOE/MOR and compression strength) properties than wood impregnated with a water solvent or untreated wood. The wood impregnated using WV and water solvent improved the physical and mechanical properties. The density of the wood increased by 44%-58% and 32%-47%, ASE radial-tangential increased by 38%-45%; 15%-28% after 24 h of water immersion, crystallinity increased by 59%-74%; 36%, MOE increased by 46%-57%; 28%-31%, MOR increased by 29%-34%; 14%-27%, and compression strength increased by 40%-76%; 38%-72% values to untreated wood.

肛腸療法에 의한 辛蒲湯의 抗아나필락시 效果 (Antianaphylactic Effect of Sinpo-tang by Anal Therapy)

  • 이종범;문석재;문구;원진희;김태균;배남규
    • 한방안이비인후피부과학회지
    • /
    • 제14권1호
    • /
    • pp.240-249
    • /
    • 2001
  • Objective : Anal Therapy is another way of taking medicine and applies to each field of clinical treatment extensively. Sinpo-tang(SPT) has been used for the treatment of a allergic rhinitis. In this study, the auther investigated the anti anaphylactic action of Sinpo-tang by anal therapy was investigated on cutaneous allergic reaction models. Methods : Results : 1. Sinpo-tang (0,001-0.1 g/kg) dose-dependently inhibited the compound 48/80-induced ear swelling response in mice. Inhibitory effect of Sinpo-tang was significant (P < 0.05) at the doses of 0.01, 0.1 g/kg. 2. Sinpo-tang (0.001-0.1 g/kg) inhibited the cutaneous allergic reaction activated by anti-dinitrophenyl IgE in rats. Of special note, Sinpo-tang (0.1 g/kg) inhibited the cutaneous allergic reaction by $68\%$. 3. This inhibitory effect of Sinpo-tang was confirmed by observation of alcian blue/nuclear fast red stained-mast cells in the cutaneous tissue. 4. Sinpo-tang (0.01-1 g/L) dose-dependently inhibited the compound 48/80-induced histamine release from the peritoneal mast cells. Conclusions :These results indicate that anal therapy of Sinpo-tang may be beneficial in the treatment of mast cell-mediated anaphylaxis by inhibition of histamine release from mast cells in vivo and in vitro.

  • PDF

한식당 영업활성화 방안 연구 - 선행연구 문헌을 토대로 - (A Study of Activation plan for Korean restaurant business -Based on Literature of Preceding Studies-)

  • 계수경;진영일
    • 한국관광식음료학회:학술대회논문집
    • /
    • 한국관광식음료학회 2005년도 학술논문발표집
    • /
    • pp.109-122
    • /
    • 2005
  • In accordance with changes in life style, people's desire to eat out is getting changed in their preferring factors from whether they can buy food they want to eat fast and easily to mood of the dining space, content and quality of service, hygiene condition of restaurant, quiet location and surrounding circumstance, and discount coupon and price destruction. In addition, consumers who begin to recognize the seriousness of environmental pollution prefer health-oriented food. On the other hand, excessive presence of competitors, growing personnel expense, increasing expenditure in accordance with swelling price of rent and material expenditure, increase of tax burden, decrease of income because of credit card service charge and high expected level by consumers make it difficult for restaurant's owners to manage restaurant business. Therefore, this study purposes to establish development of menu from the consumer's and the supplier's point of view and propose how to develop menu aiming at convenience, health and diversity.

  • PDF

Development of Oriented Strand Board from Acacia Wood (Acacia mangium Willd): Effect of Pretreatment of Strand and Adhesive Content on the Physical and Mechanical Properties of OSB

  • Febrianto, Fauzi;Royama, Lincah Ida;Hidayat, Wahyu;Bakar, Edi S.;Kwon, Jin-Heon;Kim, Nam-Hun
    • Journal of the Korean Wood Science and Technology
    • /
    • 제37권2호
    • /
    • pp.121-127
    • /
    • 2009
  • Acacia wood (Acacia mangium Willd.) is the most popular fast growing tree species planted in timber estate in Indonesia and is considered to be very valuable raw materials for structural composite products. The objective of the research was to evaluate the properties of OSB prepared from A. Mangium wood with or without immersing the strands to hot water at $80^{\circ}C$ for 2 hours. MDI adhesive was used in 3 levels i.e., 3%, 5%, and 7%. The moisture content of strand was 7%. The results indicated that immersing strands in hot water for 2 hours at $80^{\circ}C$ prior to manufacture OSB improved significantly the mechanical peoperties (i.e., MOR and MOE) of OSB. The higher the adhesive content resulted in the better the dimensional stabilisation (i.e., water absorption and thickness swelling) and the mechanical properties (i.e., MOR, MOE and IB) of OSB. OSB prepared from hot-water immersed strands with 5% adhesive content has met all parameters requirement on the JIS A 5908 (2003) standard.

Effect of PVA Concentration on Strength and Cell Growth Behavior of PVA/gelatin Hydrogels for Wound Dressing

  • Kim, Soyeun;Lim, Hyunju;Kim, Sojeong;Lee, Deuk Yong
    • 대한의용생체공학회:의공학회지
    • /
    • 제41권1호
    • /
    • pp.1-7
    • /
    • 2020
  • Polyvinyl alcohol (PVA)/gelatin hydrogels were prepared by repeating freezing/thawing three times to evaluate the influence of PVA concentration on the strength and the cell growth behavior of the PVA/gelatin hydrogels. The swelling rate of the PVA/gelatin hydrogels decreased with raising the PVA content from 6 wt% to 12 wt% due to the formation of 3-D network inside the hydrogel. No appreciable degradation of the hydrogels was detected. As the PVA content increased from 6 wt% to 12 wt%, the strength of the PVA/gelatin hydrogels increased drastically from 6.4±0.9 kPa to 46.6±9.0 kPa. The PVA/gelatin hydrogels did not show any evidence of causing cell lysis or toxicity, implying that the hydrogels are clinically safe and effective. Although the strength increased with increasing the PVA content, the PVA/gelatin hydrogels containing 8 wt% exhibited the fastest cell growth, which is highly suitable for wound dressing requiring fast healing regeneration.

Microbial Diversity of Commercial Makgeolli and Its Influence on the Organoleptic Characteristics of Korean Rice Sourdough, Jeung-Pyun

  • Park, Jaehyung;Seo, Ji Sun;Kim, Seul-Ah;Shin, So-Yeon;Park, Jong-Hyun;Han, Nam Soo
    • Journal of Microbiology and Biotechnology
    • /
    • 제27권10호
    • /
    • pp.1736-1743
    • /
    • 2017
  • Sourdough is made by fermentation of dough by lactic acid bacteria (LAB) and yeast to improve bread properties like volume, flavor, and texture. A Korean traditional sourdough was made by fermenting rice flour with rice wine (makgeolli) and used to make sponge-like bread (jeung-pyun). The aim of this study was to investigate the microbial diversity of makgeolli products and their influence on the organoleptic quality of jeung-pyun. Three commercial makgeolli were tested for jeung-pyun production, with each product exhibiting varied dough swelling rates and organoleptic qualities, and among them, J-product was ranked highest in texture and taste. Microbial analysis of the three makgeolli also showed a big difference in their population and diversity. J-product had the highest LAB and yeast counts, and the predominant species were Lactobacillus casei, Lactobacillus brevis, Leuconostoc pseudomenteroides, and Saccharomyces cerevisiae. Using J-product, sourdough was fermented at $25^{\circ}C$, $30^{\circ}C$, and $35^{\circ}C$, and the microbial growth in and textural properties of jeung-pyun were examined by instrumental and sensory tests. At high temperature ($35^{\circ}C$), the rates of dough swelling and acidification were fast due to rapid microbial growth mainly caused by LAB, resulting in a short leavening time and soft and sour jeung-pyun. Sensory tests showed consumer preference for the soft and mild-sour jeung-pyun. This study shows that LAB in makgeolli play key roles in production of jeung-pyun, influencing the textural and sensory properties. For the production of high-quality jeung-pyun, development of LAB starters with high gas productivity and low acidity and establishment of an optimal fermentation procedure for rice dough are necessary.

HDTMA­, BDTDA­ 및 CP­스멕타이트의 물리­화학적 특성 (Physicochemical Properties of Organo­Smectites Modified by HDTMA, BDTDA, and CP)

  • 고상모;홍석정;송민섭
    • 한국광물학회지
    • /
    • 제16권4호
    • /
    • pp.295-305
    • /
    • 2003
  • 이 연구는 산업체에서 다양하게 활용될 수 있는 세 종류의 유기­스멕타이트를 제조하여 Na­스멕타이트와의 제반 물성을 비교함으로서 유기­스멕타이트의 활용을 위한 과학적인 자료를 제공하고자 한다. 이 연구를 위하여 제4가 암모늄 양이온에 속하는 Hexadecyl­trimethylammonium(HDTMA), Benzyldimethyltetradecylammonium(BDTDA) 및 Cetylpyridinium(CP) 염화물을 Na­스멕타이트에 치환시켜 세 종류의 유기­스멕타이트를 제조하였다. 유기­스멕타이트인 HDTMA­, BDTDA­ 및 CP­스멕타이트는 pH 9 정도로 비교적 높은 알칼리성을 나타내었다. 이들 유기­스멕타이트는 Na­스멕타이트에 비해 극히 낮은 팽윤도, 점도를 나타내고, 짧은 시간에 강한 응집이 초래되었다. 양이온 교환능과 동일한 양의 유기 양이온을 스멕타이트에 치환시켜 제조된 유기­스멕타이트의 저면간격은 HDTMA­스멕타이트가 $23.1\AA$, BDTDA­스멕타이트가 $19.2\AA$ 및 CP­스멕타이트가 $23.2\AA$로서, Na­스멕타이트의 $12.7\AA$에 비해 강한 격자 팽창이 초래 되었다. 유기­스멕타이트에 치환된 세 종류의 유기물은 $250^{\circ}C$에서 분해하기 시작하여 40$0^{\circ}C$ 부근의 온도에서 분해가 거의 종료되었다. 이는 연구된 세 종류의 유기­스멕타이트가 $250^{\circ}C$ 미만에서 안정함을 의미한다. 연구된 세 종류의 유기­스멕타이트는 대체로 유사한 광물학적, 물리­화학적 및 열적특성을 나타낸다. 이는 세 유기물의 화학적 성질의 유사성 때문일 것이다. 경제적인 면을 고려한다면 CP로 치환시킨 CP­스멕타이트의 활용이 매우 클 것으로 예측되며, 이에 대한 다양한 연구가 요구된다.

시멘트 모르타르용 cPSMA-PSMA 마이크로캡슐 흡수제 제조 및 적용 (Synthesis and Application of cPSMA-PSMA Microcapsule Absorbent for Cement Mortars)

  • 황기섭;장석수;정용욱;이승한;하기룡
    • 폴리머
    • /
    • 제36권2호
    • /
    • pp.216-222
    • /
    • 2012
  • 콘크리트 제조 시 잉여수의 지연 흡수를 위하여 가교된 crosslinked poly(styrene-$alt$-maleic anhydride)(PSMA)가 core이고, PSMA가 shell인 마이크로캡슐 흡수제를 침전중합법으로 제조하였다. Shell의 두께를 조절하기 위하여 (core 단량체의 질량)/(shell 단량체의 질량) 비가 1/1, 1/2 및 1/3이 되도록 하여 cPSMA-PSMA를 중합하였다. FTIR spectrometer를 사용하여 시멘트 포화 수용액 내에서 PSMA가 가수 분해 반응이 일어남을 확인하였다. TEM 분석으로 core/shell 단량체 비가 1/2(cPSMA #3)일 때 마이크로캡슐 구조를 잘 형성하는 것을 관찰하였고, 1/1(cPSMA #2)과 1/3(cPSMA #4)은 불완전한 마이크로캡슐 구조임을 관찰하였다. 시멘트 포화 수용액에서 cPSMA #3의 팽윤비는 초기 20분까지 증가한 후 2시간까지는 감소하였으며, 그 후 24시간까지는 다시 증가하였다. 제조된 cPSMA #3을 시멘트 페이스트에 첨가한 후 시간에 따른 점도 측정 결과 1시간까지는 거의 변화가 없었지만, 그 후 급격한 점도 증가가 일어났다. Core로만 구성된 cPSMA #1을 0.5 wt% 첨가한 시멘트 모르타르의 압축강도는 무첨가 시멘트 모르타르에 비해 약 5% 높게 나타났으며, cPSMA #3을 첨가한 모르타르는 약 7% 증가로 가장 높게 나타났다.

Utilization of Pyrolysis Oil from Pine Wood as Thermosetting Wood Adhesive Resins

  • Kim, Jae-Woo;Myers, Deland J.;Brown, Robert C.;Kuo, Monlin
    • Journal of the Korean Wood Science and Technology
    • /
    • 제35권2호
    • /
    • pp.51-60
    • /
    • 2007
  • In this study, the possibility of using pyrolysis oil as wood adhesives was explored. Especially, adhesives were formulated by reacting pyrolysis oil and formaldehyde and also partially replacing phenol with pyrolysis oil in phenol-formaldehyde (PF) adhesive and soy hydrolizate/PF adhesive formulation. The pine wood was fast pyrolyized and the oils were obtained from a series of condensers in the pyrolysis system. The oils from each condenser were first reacted with formaldehyde to explore potential use of the oil itself as adhesive. The lap-shear bond strength test results indicated that the oil itself could be polymerized and form bonds between wood adherends. The oils from each condenser were then mixed together and used as partial replacement of phenol (25, 33, and 50% by weight) in phenol-formaldehyde adhesive. The bond strength of the oil containing PF adhesives was decreased as percent phenol replacement level increased. However, no significant difference was found between 25 and 33% of phenol replacement level. The oil-contained PF resins at 25, 33, and 50% phenol replacement level with different NaOH/Phenol (Pyrolysis oil) molar ratio were further formulated with soy hydrolizate to make soy hydrolizate/pyrolysis oil-phenol formaldehyde adhesive at 6:4 weight (wt) ratio and used for fiberboard manufacturing. Surface internal bond strength (IB) of the boards bonded with 33% replacement at 0.3 NaOH/Phenol (Pyrolysis oil) molar ratio performed better than other replacement levels and molar ratios. Thickness swelling after 24 hr cold water soaking and after 2 hr in boiling water was increased as % replacement of pyrolysis oil increased.