• Applied Biological Chemistry
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• v.32 no.2
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• pp.170-177
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• 1989

In order to seek the molecular basis of higher insecticidal activity of the carbamates with two methyl groups, m-xylyl-N-methylcarbamate(MXNMC) than the corresponding unsubstituted phenyl N-methylcarbamate(PNMC), these two derivatives have been studied by molecular orbital(MO) theoretically using extended $H\ddot{u}ckel$ theory(EHT), and analysis of regression and linear free energy relationship(LFER). The most stable stereo structure(Z, Z) shows that the phenyl group occupies vertical(${\theta}=90^{\circ}$) position on the plane of the N-methylcarbamyl group. Regression analysis shows that especially good correlation exists between the $pI_{50}$ values and the calculated MO quantities when the hydrogen atomic charge of metaposition and of m-methyl groups, and LUMO energy are taken as variables. The LFER analysis on the carbamylation indicates that field(F) effect(60%) is slightly larger than resonance(R) effect(40%) in PNMC(E>R), whereas, in case of MXNMC, R effect(98.6%) is much larger than F effect(1.4%)($R{\gg}F$). From the basis on the findings, the enhancement of insecticidal activity of MXNMC may be the result of hyperconjugation by m-methyl groups.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.459-459
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• 2012

Recently, the discharge of global warming gases in dry etching process of TFT-LCD display industry is a serious issue because perfluorocarbon compound (PFC) gas causes global warming effects. PFCs including CF4, C2F6, C3F8, CHF3, NF3 and SF6 are widely used as etching and cleaning gases. In particular, the SF6 gas is chemically stable compounds. However, these gases have large global warming potential (GWP100 = 24,900) and lifetime (3,200). In this work, we chose C3F6O gas which has a very low GWP (GWP100 = <100) and lifetime (< 1) as a replacement gas. This study investigated the effects of the gas flow ratio of C3F6O/O2 and process pressure in dual-frequency capacitively coupled plasma (CCP) etcher on global warming effects. Also, we compared global warming effects of C3F6O gas with those of SF6 gas during dry etching of a patterned positive type photo-resist/silicon nitride/glass substrate. The etch rate measurements and emission of by-products were analyzed by scanning electron Microscopy (SEM; HITACI, S-3500H) and Fourier transform infrared spectroscopy (FT-IR; MIDAC, I2000), respectively. Calculation of MMTCE (million metric ton carbon equivalents) based on the emitted by-products were performed during etching by controlling various process parameters. The evaluation procedure and results will be discussed in detail.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.24 no.2
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• pp.161-168
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• 2000

Lean combustion in a SI engine is one of the best solution for the improvement of fuel economy and reduction of pollutant emission. In order to access a lean combustion engine, stable combustion at lean AlF ratio is needed. In this paper, the effect of fuel injection timing on lean misfire limit has been investigated in an MPI engine. To investigate the interaction of injection timing and intake flow characteristics, three different swirl generating SCV(swirl control valve) configurations were considered, and investigated their effects on lean misfire limit and torque at full load operation. Also the effects of spark timing on lean combustion has been investigated. Lean combustion has been examined and the results are reported in this paper. SCV B has been developed to satisfy the requirements of sufficient swirl generation to improve lean combustion and stable performance. It is found that injection timing, spark timing and intake air motion govern the stable lean combustion.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 2002.10a
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• pp.219-224
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• 2002

This paper aims to derive a mathematical model of the dynamics of handling tasks in robot finger which stable grasping and manipulates a rigid object with some dexterity. Firstly, a set of differential equation describing dynamics of the manipulators and object together with geometric constraint of tight area-contacts is formulated by Lagrange's equation. Secondly, problems of controlling both the internal force and the rotation angle of the grasped object under the constraints of area-contacts of tight area-contacts are discussed. The effect of geometric constraints of area-contacts on motion of the overall system is analyzed and a method of computer simulation for overall system of differential-algebraic equations is presented. Thirdly, simulation results are shown and the effects of geometric constraints of area-contact is discussed. Finally, it is shown that even in the simplest case of dual single D.O.F manipulators there exists a sensory feedback from sensing data of the rotational angle of the object to command inputs to joint actuators and this feedback connection from sensing to action eventually realizes secure grasping of the object, provided that the object is of rectangular shape and motion is confined to a horizontal plane.

• Archives of Pharmacal Research
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• v.7 no.1
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• pp.47-52
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• 1984

Four polymorphic forms (I, II, III and IV) of hydrochlorothiazide have been characterized on the basis of x-ray diffractometry and differential thermal analysis. Form I was obtained by crystallization from N, N-dimethylformamide and Form II was crystallized from hot methanol. Form III was precipitated from sodium hydroxide aqueous solution by treatment with hydrochloric acid and Form IV was crystallized from 50% methanol. The metastable form I was a most stable form among four polymorphs, which was stable more than ten months at room temperature. The thermodynamic parameters such as heat of solution, enthalpy, entropy, free energy difference and transition temperature were determined by the measurement of intrinsic dissolution rate. The transition temperature and the heat of transition between the metastable Form I an Form II were determined to be $299.15^{\circ}$K and 5.03 Kcal/mole, respectively and free energy difference ($\delta$ F) was 302. 13 cal/mole. Diuretic action of these four polymorphic forms was also evaluated by monitoring the difference in urinary excretion of sodium, potassium and magnesium in rats.

• Smart Structures and Systems
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• v.16 no.6
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• pp.1147-1167
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• 2015

Wireless smart sensors, which have become popular for monitoring applications, are an attractive option for implementing structural control systems, due to their onboard sensing, processing, and communication capabilities. However, wireless smart sensors pose inherent challenges for control, including delays from communication, acquisition hardware, and processing time. Previous research in wireless control, which focused on semi-active systems, has found that sampling rate along with time delays can significantly impact control performance. However, because semi-active systems are guaranteed stable, these issues are typically neglected in the control design. This work achieves active control with smart sensors in an experimental setting. Because active systems are not inherently stable, all the elements of the control loop must be addressed, including data acquisition hardware, processing performance, and control design at slow sampling rates. The sensing hardware is shown to have a significant impact on the control design and performance. Ultimately, the smart sensor active control system achieves comparable performance to the traditional tethered system.

• Journal of Environmental Science International
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• v.5 no.4
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• pp.441-451
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• 1996

The surface meteorological and upper layer meteorological observation carried out to investigate influences of sea breeze effect on lower layer atmosphere at Gori nuclear power plant for 29∼30 July, 1996. According to surface meteorological data, the inflow of sea breeze was occurred 11:30 on 29 July, 10:30-on 30 July, respectively, at observation site. And the meteorological tower data showed that wind direction of sea breeze was identified as south-westerly, and wind speed of 58 m was 2 times stronger than that of 10 m. It is notworthy that surface inversion layer which built from the night time to daybreak of next day was not broken off by seab reeze's inflow for daytime, and strong inversion layer observed at 47∼243 m with moderately stable class (F) by URC. It was found that strong stable layer of potential temperature appeared at that layer, maximum relative humidity observed at the bottom of inversion layer and maximum mixing ratio observed in the low of inversion layer.

• 한국전산유체공학회:학술대회논문집
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• 2001.05a
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• pp.99-104
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• 2001

This paper deals with the development of shock stable scheme that is free from shock instability. Roe's FDS is known to preserve good accuracy but to suffer from shock instability, i.e. the carbuncle phenomenon. As the first step toward the shock stable scheme, Roe's FDS is compared with HLLE scheme to identify the source of shock instability. Then control function f is introduced into the pressure term in Roe's FDS to cure shock instability. Various numerical tests concerned with shock instability are performed to demonstrate the shock stability of the proposed scheme.

• 한국정보디스플레이학회:학술대회논문집
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• 2008.10a
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• pp.975-978
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• 2008

Novel sulfur-containing aromatic compounds were developed as stable, high-performance organic semiconductors for OTFT applications. Of them, dinaphtho[2,3-b:2',3'-f]thieno[3,2-b]thiophene (DNTT) consisting of six aromatic rings gave high quality thin films by vapor deposition, which acted as a superior FET channel showing FET mobility as high as $3.0\;cm^2V^{-1}s^{-1}$. On the other hand, highly soluble 2,7-dialkyl[1]benzothieno[3,2-b][1]benzothiophenes ($C_n$-BTBTs) gave solution-processible OTFTs with FET mobility higher than $1.0\;cm^2V^{-1}s^{-1}$.

• 한국정보디스플레이학회:학술대회논문집
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• 2006.08a
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• pp.357-362
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• 2006

OLEDs are becoming established as a commercially viable flat panel display technology of choice of the $21^{st}$ century because of its lightweight, fast response time, lower thickness than LCD's and potentially low cost (1-2). For the OLEDs to function effectively, highly thermally stable materials, which offer high efficiency and long operational lifetimes are required. To achieve long lifetime, highly stable charge (both holes and electrons) transporters are essential. OLED-T provides these materials as well as fluorescent and phosphorescent dopants. This paper reports a unique patented hole injector (E9363) and an electron transporter (E246) that increases the lifetime and efficiency and reduces operating voltage. Further, an electron injector, EEI-101, which evaporates at a very low temperature of $300^{\circ}C$ as opposed to the conventional LiF, which requires $580^{\circ}C$, is also presented.