• Journal of the Mineralogical Society of Korea
• /
• v.30 no.2
• /
• pp.59-70
• /
• 2017

$SiO_2$ is one of the most abundant constituents of the Earth's crust and mantle. Probing its electronic structures at high pressures is essential to understand their elastic and thermodynamic properties in the Earth's interior. The in situ high-pressure x-ray Raman scattering (XRS) experiment has been effective in providing detailed bonding transitions of the low-z materials under extreme compression. However, the relationship between the local atomic structures and XRS features at high pressure has not been fully established. The ab initio calculations have been used to overcome such experimental difficulties. Here we report the partial density of states (PDOS) of O atoms and the O K-edge XRS spectra of ${\alpha}-quartz$, ${\alpha}-cristobalite$, and $CaCl_2$-type $SiO_2$ phases calculated using ab initio calculations based on the full-potential linearized augmented plane wave (FP-LAPW) method. The unoccupied O PDOSs of the $CaCl_2$-type $SiO_2$ calculated with and without applying the core-hole effects present significantly distinctive features. The unoccupied O p states of the ${\alpha}-quartz$, ${\alpha}-cristobalite$ and $CaCl_2$-type $SiO_2$ calculated with considering the core-hole effect present similar features to their calculated O K-edge XRS spectra. This confirms that characteristic features in the O K-edge XRS stem from the electronic transition from 1s to unoccupied 2p states. The current results indicate that the core-hole effects should be taken in to consideration to calculate the precise O K-edge XRS features of the $SiO_2$ polymorphs at high pressure. Furthermore, we also calculated O K-edge XRS spectrum for $CaCl_2$-type $SiO_2$ at ~63 GPa. As the experimental spectra for these high pressure phases are not currently available, the current results for the $CaCl_2$-type $SiO_2$ provide useful prospect to predict in situ high-pressure XRS spectra.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.10 no.8
• /
• pp.1795-1801
• /
• 2009

In this study, a portable flashlight which can manually generate the electricity by using sunlight was developed so that it can be used in the extreme environmental condition such as no-electricity condition. Battery is charged by using solar battery during the day, but when sunlight is not avalible during the night or rainy day, a handle is rotated to generate the electricity in order to charge the battery manually. To improve the brightness of the light, light is concentrated by using the optical lens. Low electric consumption circuit is used for the longer operating time by suppress electrical consumption while lamp is discharged. A circuit is designed and used for steady electrical curris dand voltage to insure steady battery charging. Super-discharge circuit and protection circuit are used for the super discharge of battery when it is not used for a long time. Also the constant charge is possible by using houseware adapter. As a result, a portable flashlight is designed to charge with sunlight during day, and with houseware adapter during night. A portable flashlight is also designed to irradiate longer distances by improvement of the brightness of the light using the optical lens. Thus, it forms white natural ray of light making possible for night reading.