• 제목/요약/키워드: extinction coefficient

검색결과 210건 처리시간 0.031초

소형 Magnetron sputtering 방법에 의한 썬글라스 렌즈용 Ti 박막의 특성연구 (The Study of the Characteristic of Ti Thin Film Using Small Magnetron Sputtering Method for Sunglass Lens)

  • 박문찬;정부영;이종근;주경복;이화자
    • 한국안광학회지
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    • 제13권1호
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    • pp.59-63
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    • 2008
  • 목적: 소형 magnetron sputtering 장치를 이용하여 CR-39 안경렌즈와 glass위에 코팅한 썬글라스 렌즈용 Ti박막의 광학적 특성에 관한 연구이다. 방법: SEM 단면 사진으로 Ti 코팅 박막의 두께를 측정하였고, spectrophotometer를 이용하여 Ti 박막의 투과율과 반사율을 측정하였다. Variable angle spectroscopic ellipsometry (VASE)를 이용하여 파장에 따라 Ti 박막의 굴절률과 소멸계수를 구하였다. 결과: 두께가 60 nm, 120 nm, 140 nm인 시료에 대한 투과율은 가시광선 영역인 파장 400 nm에서 750 nm까지 변화가 크지 않았으며 모두 silver tone에 가까운 color를 보였다. 가까운 파장 400 nm 근처에서 약간 올라가는 경향을 보였고, He d선 (587.6 nm)을 기준으로 할 때 Ti 박막의 두께가 60 nm에서 투과율이 33%, 두께가 120 nm에서 투과율이 25%, 두께가 140 nm에서 투과율이 20%를 보였다. 결론: Ti 박막의 경우 60~140 nm의 모든 두께에서 선글라스용으로 적합한 것을 알 수 있었다. Ti박막에 대한 굴절률이 작게 나오는 것은 Ti박막의 두께가 얇기 때문이라고 여겨진다.

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고공간분해능 연속 광원을 이용한 미세먼지 라이다의 신호 특성에 관한 연구 (A Study of the Characteristics of Highly Spatially Resolved CW-laser-based Aerosol Lidar)

  • 심주현;김태경;주소희;노영민;김덕현
    • 한국광학회지
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    • 제33권1호
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    • pp.1-10
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    • 2022
  • 본 연구에서는 고가의 일반 펄스 레이저 없이 비교적 근거리에서 강한 거리 분해능을 지니며, 원거리에서도 공간 분해능을 지닌 연속광원 레이저를 이용한 미세먼지 라이다를 제안한다. 일반적인 라이다 시스템은 짧은 펄스의 레이저를 사용하고, 특정 거리 사이의 time-of-flight (TOF) 왕복시간을 측정하여 거리 정보를 얻고 있으나, 본 연구에서는 상용 카메라와 연속광 레이저 빔을 조사하여 얻은 영상을 사용하여 공간 분해능을 얻는 새로운 에어로졸 라이다를 소개한다. 본 연구에서는 라이다 신호와 함께 얻은 레이저의 이미지를 사용하여 주어진 하나의 화소에 해당하는 산란 에어로졸까지의 거리와 그 화소에 기여하는 에어로졸의 범위를 계산하였다. 이러한 거리와 기여 범위를 사용하여 거리 분해능을 갖는 에어로졸의 소멸계수를 계산하였으며, 기존 에어로졸 라이더의 경우 400 m 이상에서만 에어로졸 소산계수를 얻을 수 있었지만 제안 된 방법과 주어진 카메라의 조건을 사용하면 수십 미터 이하까지 그 소산계수를 얻을 수 있음을 알 수 있었다.

GIST/ADEMRC 다파장 라만 라이다 시스템을 이용한 안면도 지역에서의 라이다 비 연구 (Determination of the Lidar Ratio Using the GIST / ADEMRC Multi-wavelength Raman Lidar System at Anmyeon Island)

  • 노영민;김영민;김영준;최병철
    • 한국대기환경학회지
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    • 제22권1호
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    • pp.1-14
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    • 2006
  • Tropospheric aerosols are highly variant in time and space due to non-uniform source distribution and strong influence of meteorological conditions. Backscatter lidar measurement is useful to understand vertical distribution of aerosol. However, the backscatter lidar equation is undetermined due to its dependence on the two unknowns, extinction and backscattering coefficient. This dependence necessitates the exact value of the ratio between two parameters, that is, the lidar ratio. Also, Iidar ratio itself is useful optical parameter to understand properties of aerosols. Tropospheric aerosols were observed to understand variance of lidar ratio at Anmyeon island ($36.32^{/circ}N$, $126.19^{/circ}E$), Korea using a multi-wavelength raman lidar system developed by the Advanced Environmental Monitoring Research Center (ADEMRC), Gwangju Institute Science and Technology (GIST), Korea during measurement periods; March 15$\sim$April $16^{th}$, 2004 and May 24$\sim$ $8^{th}$ 2005. Extinction coefficient, backscattering coefficient, and lidar ratio were measured at 355 and 532 nm by the Raman method. Different types of aerosol layers were distinguished by the differences in the optical properties such as Angstrom exponent, and lidar ratio. The average value of lidar ratio during two observation periods was found to be $50.85\pm4.88$ sr at 355 nm and $52.43\pm15.15$ sr at 532 nm at 2004 and $57.94\pm10.29$ sr at 355 nm and $82.24\pm15.90$ sr at 532 nm at 2005. We conduct hysplit back-trajectory to know the pathway of airmass during the observation periods. We also calculate lidar ratio of different type of aerosol, urban, maritime, dust, continental aerosols using OPAC (Optical Properties of Aerosols and Clouds), Remote sensing of atmospheric aerosol using a multi-wavelengh lidar system with Raman channels is quite and powerful tool to characterize the optical propertises of troposheric aerosols.

서울시의 1993년 가을철 시정 및 입자 특성 측정 및 분석 (Measurement and Analysis of Visibility and the Characteristics of Particles during the Fall, 1993 in Seoul)

  • 백남준;김태오;김성주;김용표;문길주
    • 한국대기환경학회지
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    • 제10권1호
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    • pp.32-40
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    • 1994
  • Continuous measurements of the extinction coefficient( $b_{ext}$ ) and scattering coefficient due to Particle( $b_{sp}$ ) were made during the fall 1993 in Seoul along with the measurements of the size distribution, ionic composition of particles. On the average, $b_{sp}$ values are 55% and 79% of $b_{ext}$ values during the clear and smoggy Periods respectively. Also the average values of $b_{ext}$ and $b_{sp}$ were 0.791$\times$10$^{-3}$ $m^{-1}$ (visual range 4.9km) and 0.628$\times$10$^{-3}$ $m^{-1}$ (visual range 6.2km) during the smoggy Period, and 0.297$\times$10$^{-3}$ $m^{-1}$ (visual range 13.1km) and 0.164$\times$10$^{-3}$ $m^{-1}$ (visual range 23.8km) during the clear period, respectively. The Peak at about 1${\mu}{\textrm}{m}$ of the Particle size distribution during the smoggy period is about four times higher than that during the clear period while the peaks at about 5${\mu}{\textrm}{m}$ during both periods are similar. Also, the concentrations of sulfate and nitrate at about 1${\mu}{\textrm}{m}$ during the smoggy Period are much higher than these during the clear Period.eriod.

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Relation between Chemical Structure of Yellow Disperse Dyes and Their Lightfastness

  • Kim, Sung-Dong;Park, Eun-Jin
    • Fibers and Polymers
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    • 제2권3호
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    • pp.159-163
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    • 2001
  • Five yellow disperse dyes were synthesized and their dyeing, fastness and photodegradation behaviors were investigated. It was found that dyes derived from phenylindole and N-alkylaminobenzene showed dye uptake directly proportional to the dye concentration, but the build-up of dyes derived from carbazole and pyridone were not good. The wavelength at maximum absorption. molar extinction coefficient. and the tendency to the photodegradation were strongly dependent on the electron donating ability of the coupling component. The dye, whose coupling component was phenylindole, possessed the excellent dyeing properties and the high degree of lightfastness. UVA had an effect on the inhibition of the photodegradation especially for the easily photodegradabte dyes.

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수용성 치자 색소의 추출에 관한 연구 (A Study on the Extraction of Soluble Colorants of the Gardenia jasminoides Ellis)

  • Kim, Kwang Soo;Kim, Yeon Joong
    • 한국염색가공학회지
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    • 제9권3호
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    • pp.10-17
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    • 1997
  • The study was performed to obtain the optimum extraction conditions for crocin from gardenia fructus. Generally crocin is unstable on heat, light, acid and base solution. The extraction efficiency of crocin from gardenia depended upon the extraction time, extraction temperature, pH in the extraction bath and the optimum conditions of crocin extraction were determined as 60 minutes of extraction time, 4$0^{\circ}C$ of extraction temperature, pH 7 of extraction bath. The molar extinction coefficient of crocin was 12,515 and the color yield of purified crocin was about six times higher than that of non-purified crocin. The heat-stability at extraction temperature and lightstability in irradiation with xenon lamp for one hour of the purified crocin were higher than those of non-purified crocin. Intensity of &{\lambda}_{max}&of crocin was decreased by irradiation for one hour but UV-Vis. spectra of crocin was not changed. The colors of purified and non-purified crocin dissolved wit methanol was evaluated by means of CIE L* a* b* system.

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플라즈마 중합법에 의한 유기 박막의 광학 특성에 관한 연구 (II) (A Study on the Optical Properties of the Organic Thin Films by Plasma Polymerization(II))

  • 최충석;정윤;이덕출;박구범;박상현;박복기
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1992년도 하계학술대회 논문집 B
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    • pp.875-878
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    • 1992
  • In this study, We made use of inter-electrode capacitively coupled type plasma polymerization apparatus in order to make the organic optical thin films. We adopted in Benzen. Vinyl-Pyridine and Styrene, which have optical function in the organic world and manufactured double later. It is examined optics properties by it respectively. At the middle wave length as 550[nm], the transmittance is double layer smaller than one of single layer. The refractive index with wave length is various from 1.55 to 1.65. Then, it is known that measured results are valid because the extinction coefficient(K) is about $10^{-4}$ for variation of refractive index.

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페노시아진을 이용한 염료감응형 태양전지 고효율 염료합성 (Synthesis and Photovoltaic Properties of Organic Photosensitizers for Application of Dye Sensitized Solar Cells)

  • 양현식;신소연;김연지;김재홍
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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    • pp.119.2-119.2
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    • 2011
  • Dye-sensitized solar cells (DSSC) are currently attracting wide spread academic and commercial interest for the conversion of sunlight into electricity because of their easy manufacturing process and high efficiency. The solar energy conversion efficiencies of DSSC are strongly dependent on dye molecules adsorbed on the TiO2 surface which used for photosensitization of sun light, since an excited state of dye could inject an electron into the conduction band of semiconductor. We have developed novel organic dyes which have phenothiazine moieties as an electron donor in their charge-transfer chromophore for application of DSSCs. We had synthesized a series of phenothiazine derivatives which have different wave length absorbing chromophore in the molecule with high molar extinction coefficient. The photovoltaic performance of DSSC composed of organic chromophores with broad wavelength absorption property were measured and evaluated by comparison with that of pristine ruthenium dye.

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Atomic Layer Deposition of $Sb_2S_3$ Thin Films on Mesoporous $TiO_2$

  • 한규석;정진원;성명모
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.282-282
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    • 2013
  • The antimony sulfide ($Sb_2S_3$) thin films were deposited using the gas phase method which known as atomic layer deposition (ALD) on mesoporous micro-films. Tris (dimethylamido) antimony (III[$(Me_2N)_3Sb$] and hydrogensulfide ($H_2S$) were used as precursors to deposit $Sb_2S_3$. Self-terminating nature of $(Me_2N)_3Sb$ and $H_2S$ reaction were demonstrated by growth rate saturation versus precursors dosing time. Absorption spectra and extinction coefficient were investigated by UV-VIS spectroscopy. Scanning electron microscopic analysis and X-ray photoelectron spectroscopy (XPS) depth profile were employed to determine the conformal deposition.

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Enhancement of Aerosol Concentration in Korea due to the Northeast Asian Forest Fire in May 2003

  • In, Hee-Jin;Kim, Yong-Pyo;Lee, Kwon-H.
    • Asian Journal of Atmospheric Environment
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    • 제3권1호
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    • pp.1-8
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    • 2009
  • Enhancement of aerosol optical thickness (AOT) and surface aerosol mass concentration in Korea for an active forest fire episode in Northeast Asia were estimated by Community Multi-scale Air Quality (CMAQ) model. MODIS/TERRA remote detects of fires in Northeast Asia for May 2003 gave a constraint for estimation of wildfire emissions with an NDVI distribution for recent five years. The simulated wildfire plumes and enhancement of AOT were evaluated and well resolved by comparing multiple satellite observations such as MODIS, TOMS, and others. Scatter plots of observed daily mean aerosol extinction coefficient versus $PM_{10}$ concentration in ground level in Korea showed distinctively different trends based on the ambient relative humidity.