• Title/Summary/Keyword: external carbon

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A Study of Carbon Nanotube Channel Field-Effect Devices (탄소 나노튜브 채널을 이용한 전계효과 이온-전송 소자 연구)

  • Lee, Jun-Ha;Lee, Hoong-Joo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.2
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    • pp.168-174
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    • 2006
  • We investigated field-effect ion-transport devices based on carbon nanotubes by using classical molecular dynamics simulations under applied external force fields, and we present model schematics that can be applied to the nanoscale data storage devices and unipolar ionic field-effect transistors. As the applied external force field is increased, potassium ions rapidly flow through the nanochannel. Under low external force fields, thermal fluctuations of the nanochannels affect tunneling of the potassium ions whereas the effects of thermal fluctuations are negligible under high external force fields. Since the electric current conductivity increases when potassium ions are inserted into fullerenes or carbon nanotubes, the field effect due to the gate, which can modify the position of the potassium ions, changes the tunneling current between the drain and the source.

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Surface Characteristics of Direct Fluorinated Single-walled Carbon Nanotubes

  • Seo, Min-Kang;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.30 no.9
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    • pp.2071-2076
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    • 2009
  • The single-walled carbon nanotubes (SWCNTs) produced by chemical vapor deposition (CVD) were directly fluorinated with fluorine ($F_2$) gas in a temperature range 20 ~ 400 ${^{\circ}C}$. The surface properties and morphology of the SWCNTs were investigated in terms of fluorination temperature. As a result, Raman spectra showed a pair of bands at 1340 and 1590 $cm^{-1}$ peculiar to disordered $sp^2$-carbons. These results indicated that C-F bonds were formed on the rear surfaces of the nanotubes by fluorination, while the external surfaces as well as the layers between the internal and external surfaces retained their $sp^2$-hybridization. XPS analysis exhibited that fluorine atoms were bonded to carbon atoms on internal surfaces (rear surfaces) of the nanotubes and the amount of fluorine attached on the nanotubes was increased with increasing the fluorination temperature. Consequently, the direct fluorination of carbon nanotubes led to functionalization and modification of pristine nanotubes with respect to surface and morphological properties.

Optimum Conditions for the Removal of External Organic Carbon Sources in a Submerged Denitrification Biofilter (탈질 여과조에서 외부 탄소원 제거를 위한 적정 체류 시간과 외부 탄소원 종류 및 질산염 농도에 대한 외부 탄소원의 적정 비율)

  • 오승용;조재윤;윤길하
    • Journal of Aquaculture
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    • v.12 no.1
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    • pp.47-56
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    • 1999
  • Denitrification by anaerobic bacteria is one of the most common processes of removing nitrate from recirculating aquaculture systems. This process is affected by many factors such as external carbon sources, hydraulic retention time (HRT), and $COD/NO_3-N$ ratio. Although external organic carbon sources are essential for the denitrification process, these also contribute to increase dissolved organic carbon concentration in recirculating aquaculture systems. So these external organic carbons must be removed from the systems. This study was conducted to find out the optimum operating conditions for the removal of external organic carbons in a submerged denitrification biofilter. Combinations of two external carbon sources (glucose and methanol), two HRT (4- and 8-hour), and four different C:N ratios (3, 4, 5, and 6) were used in this experiment. The removal efficiencies of organic carbon sources at 8-hour HRT were always better than those at 4-hour's (P<0.05). Maximum removal efficiencies were achieved when C:N ratio was 5 in both glucose and methanol. The removal efficiencies of methanol were always better than those of glucose. The maximum removal efficiencies of glucose and methanol were 76.5% and 84.0%, respectively and the removal rates were 223.5 $g/m^2/day$ and 247.1$g/m^2/day$. The maximum removal rates of glucose (290.9 $g/m^2/day$) and methanol (355.6 $g/m^2/day$) were achieved at 4-hour HRT and 5 C:N ratio. But the concentrations of SCOD in the effluent of both glucose ($52.5 mg/\ell$) and methanol ($40.9 mg/\ell$) were too high for rearing fish. Therefore, the optimum operating conditions for the removal of external carbon in a submerged denitrification biofilter were 8-hour HRT and 5 C:N ratio. And methanol showed better efficiency as an external carbon sources.

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Evaluation of the Effect of Nickel Powder on the Piezoresistivity Behavior of Carbon-Fiber/Rubber Composites (탄소섬유/고무 복합재료의 압저항과 니켈입자의 영향)

  • Lim, Dong-Jin
    • Composites Research
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    • v.34 no.6
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    • pp.412-420
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    • 2021
  • In this study, we measure the initial electrical conductivity of SCF/rubber specimens and SCF/rubber specimens with nickel particles respectively. The corresponding electrical conductivity with compressive strain on the specimens is also measured. Through this experiment, we observed the effects of the volume fraction of carbon fiber, nickel particles and external strain on the electrical conductivity. Experiments show that even a small difference in the volume fraction of SCF plays a major role in the change of the electrical conductivity and that the piezoresistivity increases due to fiber reorientation respond to external strain. In addition, the nickel particles contribute to improving the electrical conductivity in specimens with carbon fibers above the threshold volume fraction. It was confirmed that there is an effect of offsetting the increment in the piezoresistivity caused by the reorientation of carbon fibers according to external strain.

Recovery of high quality external carbon sources using crystallization from pretreated excess activated sludge by alkali and ozone (알칼리-오존 동시 전처리된 잉여슬러지로부터 결정화를 이용한 고품질 외부탄 소원 회수)

  • Seo, In S.;Kim, Hong S.;Kim, Byung G.;Kim, Youn K.
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.6
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    • pp.641-646
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    • 2008
  • In this research, recovery of high quality organics from excess activated sludge and its potential as a external carbon sources for BNR process was studied. By simultaneous treatment of alkali and ozone, TSS concentration was reduced by 32%, and RBDCOD fraction was increased by 76.2%, and major constitute of produced organic were acetic acid and propionic acid. Also, nitrogen and phosphorus were greatly solubilized. However, because acid-hydrolyzable phosphorus(AHP) was major part of solubilized phosphorus, $NH_4{^+}-N$ and $PO_4{^3}-P$ concentration were insufficient for effective formation of crystal like as MAP(Magnesium Ammonium Phosphate) and hydroxyapatite. By placing BPR reactor before alkali-ozone treatment reactor, $PO_4{^3}-P$ concentration in pretreated sludge was increased by 1.8 times, and improved potential of phosphorus recovery by crystallization. In experiment of crystallization, hydroxyapatite formation was more easily applied than MAP. By hydroxyapatite formation, $SCOD/PO_4-P$ ratio was greatly increased from 32.7 at control to 141.9 at $Ca^{2+}/PO{_4}^{3-}-P$ mole ratio of 2.4. The results based on this study indicated that the proposed system configuration has potential to reduce the excess sludge production, to recover phosphorus in usable forms as well as utilize organics as a external carbon source in BNR process.

Nitrongen and Phosphorus Removal using Elutriated Acids of Food Waste as an External Carbon Source in SBR (음식물쓰레기 세정산발효액을 외부탄소원으로 주입한 SBR 공정에서 질소 및 인 제거)

  • Kwon, Koo-ho;Kim, Si-won;Lee, Min-jae;Min, Kyung-sok
    • Journal of Korean Society on Water Environment
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    • v.22 no.3
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    • pp.462-467
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    • 2006
  • An improvement of nitrogen and phosphorus removal in SBR using the elutriated acids from the food waste as an external carbon source was investigated in this study. The food waste was elutriated at $35^{\circ}C$ and pH 9 to produce the external carbon source. The elutriate of food waste were continuously collected. The elutriated liquid contained VFAs of 39,180 mg/L representing soluble COD of 44,700 mg/L. The SBR showed poor denitrification and EBPR (enhanced biological phosphorus removal) without elutriated VFAs addition. An average denitrification rate was 0.4 mg NOx-N/g MLVSS/day. In turn, EBPR was also inhibited by this poor denitrification because the remaining nitrate in anaerobic phase resulting a poor denitrification. On the other hand, the denitrification in anoxic phase significantly improved with an elutriated VFAs addition. Nitrate removal was 82% while the denitrification rate was 2.9 mg NOx-N/g MLVSS/day with 18.4 mL/cycle of elutriated VFAs. With the enhanced denitrification, nitrate concentration in anaerobic phase could effectively be controlled to a very low level. The elimination of nitrate inhibition in anaerobic phase resulted enhancement of EBPR. The specific phosphate release rate was $1.9mg\;PO_4^{3-}-P/g\; MLVSS/day$ with less than 0.5 mg/L of $PO_4^{3-}-P$ concentration.

Linking nuclear energy, human development and carbon emission in BRICS region: Do external debt and financial globalization protect the environment?

  • Sadiq, Muhammad;Shinwari, Riazullah;Usman, Muhammad;Ozturk, Ilhan;Maghyereh, Aktham Issa
    • Nuclear Engineering and Technology
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    • v.54 no.9
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    • pp.3299-3309
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    • 2022
  • Nuclear energy has the potential to play an influential role in energy transition efforts than is now anticipated by many countries. Realizing sustainable human development and reducing global climate crises will become more difficult without significantly increasing nuclear power. This paper aims to probe the role of nuclear energy, external debt, and financial globalization in sustaining human development and environmental conditions simultaneously in BRICS (Brazil, Russia, India, China, and South Africa) countries. This study applied a battery of second-generation estimation approaches over the period from 1990 to 2019. These methods are useful and robust to cross-countries dependencies, slope heterogeneity, parameters endogeneity, and serial correlation that are ignored in conventional approaches to generate more comprehensive and reliable estimates. The empirical findings indicate that nuclear energy and financial globalization contribute to human development, whereas external debt inhibits it. Similarly, financial globalization accelerates ecological deterioration, but nuclear energy and external debt promote environmental sustainability. Moreover, the study reveals bidirectional feedback causalities between human development, carbon emissions and nuclear energy consumption. The study offers useful policy guidance on accomplishing sustainable and inclusive development in BRICS countries.

Optimization of Explosive Compounds (TNT and RDX) Biodegradation by Indigenous Microorganisms Activated by External Carbon Source (외부탄소원으로 활성화된 토착미생물에 의한 화약물질(TNT and RDX) 분해 최적화)

  • Park, Jieun;Bae, Bumhan
    • Journal of Soil and Groundwater Environment
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    • v.19 no.3
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    • pp.56-65
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    • 2014
  • Contamination of explosive compounds in the soils of military shooting range may pose risks to human and ecosystems. As shooting ranges are located at remote places, active remediation processes with hardwares and equipments are less practical to implement than natural solutions such as bioremediaton. In this study, a series of experiments was conducted to select a suitable carbon source and to optimize dosing rate for the enhanced bioremediation of explosive compounds in surface soils and sediments of shooting ranges with indigenous microorganisms activated by external carbon source. Treatability study using slurry phase reactors showed that the presence of indigenous microbial community capable of explosive compounds degradation in the shooting range soils, and starch was a more effective carbon source than glucose and acetic acid in the removal of TNT. However, at higher starch/soil ratio, i.e., 2.0, the acute toxicity of the liquid phase increased possibly due to transformation products of TNT. RDX degradation by indigenous microorganisms was also stimulated by the addition of starch but the acute toxicity of the liquid phase decreased with the increase of starch/soil ratio. Taken together, the optimum range of starch/soil ratio for the degradation of explosive compounds without significant increase in acute toxicity was found to be 0.2 of starch/soil.

Sequencing batch reactor treating ship sewage and external carbon source (연속 회분식 공정을 이용한 선박오수와 외부탄소원의 혼합처리)

  • Park Sang-Ho;Choi Jeong-Hye;Ko Sung-Chul;Kim In-Soo
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2004.11a
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    • pp.147-152
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    • 2004
  • In Sequence Batch Reactor (SBR), the removal efficiencies if nutrient materials such as nitrogen and phosphate depend highly on quantity and quality of organic carbon source. Food waste thai contains abundant organic materials has been produced in ship. The applicability if anaerobically fermented if food waste (AFFW) as an external carbon source was examined in the lab-scale SBR process operated at $25^{\circ}C$. With the addition if AFFW increased, average removal efficiencies if $COD_cr$, T-N, T-P changed to $98.5\%,\;95\%,\;93\%$, respectively. Denitrification rate is 0.30g $NO_3-N/g\;VSS{\cdot}day$. In summary, it was suggested tint AFFW sould be used as an economical and effective carbon source for the biological nitrogen and phosphate removal.

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