• Title/Summary/Keyword: external Na supply

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Production of Tantalum Powder and Characteristics by External Supply of Feed Material and Reductant (원료물질과 환원제의 외부공급에 따른 탄탈륨 분말의 제조 및 특성)

  • 윤재식;박형호;배인성;김병일
    • Journal of Powder Materials
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    • v.10 no.5
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    • pp.349-352
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    • 2003
  • This study examined the correlation of various operational factors including reaction temperature and the quantity of reductant and diluent with the characteristics of powder using $K_2$ TaF$_{7}$ as feed materials, Na as a reductant and KCl/KF as a diluent. Also to control the particle size and shape, external supply system developed, it can provide a feed material and a reductant at a fixed quantity and evaluated the characteristics of tantalum powder. When the external supply system was applied instead of the batch type process that charges feed material, reductant and diluent at the same time, it was possible to induce regular reduction reaction between feed material and reductant, which increased the recovery rate and reduced the mixture of impurities. In particular, the application of the external supply system enabled the control of reaction temperature and reaction speed according to the feeding rate of feed material during reduced reaction, and resultantly it enabled the manufacturing of granular-shaped powder with a regular granularity of 2∼3 ${\mu}{\textrm}{m}$ and purity of 99.5%.

Na Doping Properties of Cu(In,Ga)Se2 Absorber Layer Using NaF Interlayer on Mo Substrate (Mo 기판위의 NaF 중간층을 이용한 Cu(In,Ga)Se2 광흡수층의 Na 도핑특성에 관한 연구)

  • Park, Tae-Jung;Shin, Dong-Hyeop;Ahn, Byung-Tae;Yun, Jae-Ho
    • Korean Journal of Materials Research
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    • v.19 no.8
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    • pp.452-456
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    • 2009
  • In high-efficiency Cu(In,Ga)$Se_2$ solar cells, Na is doped into a Cu(In,Ga)$Se_2$ light-absorbing layer from sodalime-glass substrate through Mo back-contact layer, resulting in an increase of device performance. However, this supply of sodium is limited when the process temperature is too low or when a substrate does not supply Na. This limitation can be overcome by supplying Na through external doping. For Na doping, an NaF interlayer was deposited on Mo/glass substrate. A Cu(In,Ga)$Se_2$ absorber layer was deposited on the NaF interlayer by a three-stage co-evaporation process As the thickness of NaF interlayer increased, smaller grain sizes were obtained. The resistivity of the NaF-doped CIGS film was of the order of $10^3{\Omega}{\cdot}cm$ indicating that doping was not very effective. However, highest conversion efficiency of 14.2% was obtained when the NaF thickness was 25 nm, suggesting that Na doping using an NaF interlayer is one of the possible methods for external doping.

Fabrication of wide-bandgap β-Cu(In,Ga)3Se5 thin films and their application to solar cells

  • Kim, Ji Hye;Shin, Young Min;Kim, Seung Tae;Kwon, HyukSang;Ahn, Byung Tae
    • Current Photovoltaic Research
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    • v.1 no.1
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    • pp.38-43
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    • 2013
  • $Cu(In,Ga)_3Se_5$ is a candidate material for the top cell of $Cu(In,Ga)Se_2$ tandem cells. This phase is often found at the surface of the $Cu(In,Ga)Se_2$ film during $Cu(In,Ga)Se_2$ cell fabrication, and plays a positive role in $Cu(In,Ga)Se_2$ cell performance. However, the exact properties of the $Cu(In,Ga)_3Se_5$ film have not been extensively studied yet. In this work, $Cu(In,Ga)_3Se_5$ films were fabricated on Mo-coated soda-lime glass substrates by a three-stage co-evaporation process. The Cu content in the film was controlled by varying the deposition time of each stage. X-ray diffraction and Raman spectroscopy analyses showed that, even though the stoichiometric Cu/(In+Ga) ratio is 0.25, $Cu(In,Ga)_3Se_5$ is easily formed in a wide range of Cu content as long as the Cu/(In+Ga) ratio is held below 0.5. The optical band gap of $Cu_{0.3}(In_{0.65}Ga_{0.35})_3Se_5$ composition was found to be 1.35eV. As the Cu/(In+Ga) ratio was decreased further below 0.5, the grain size became smaller and the band gap increased. Unlike the $Cu(In,Ga)Se_2$ solar cell, an external supply of Na with $Na_2S$ deposition further increased the cell efficiency of the $Cu(In,Ga)_3Se_5$ solar cell, indicating that more Na is necessary, in addition to the Na supply from the soda lime glass, to suppress deep level defects in the $Cu(In,Ga)_3Se_5$ film. The cell efficiency of $CdS/Cu(In,Ga)_3Se_5$ was improved from 8.8 to 11.2% by incorporating Na with $Na_2S$ deposition on the CIGS film. The fill factor was significantly improved by the Na incorporation, due to a decrease of deep-level defects.

Comparison of Patterns of Mineral Ions and Growth Responses of 4 Legume Plants by Nitrogen Applications under Saline Conditions (염 환경에서 질소공급에 따른 4종 콩과식물의 생장반응과 무기이온양상의 비교)

  • 배정진;추연식;송승달
    • Journal of Life Science
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    • v.13 no.4
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    • pp.473-480
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    • 2003
  • We analyzed the patterns of mineral ions and growth responses among symbiotic nitrogen fixing legumes by external nitrogen applications under salt gradients. Glycine max, Phaseolus angularis and Albizzia julibrissin showed remarkable growth inhibition above 40 mM NaCl treatments, but Cassia tora did not exhibit any visible injury symptom up to 100 mM NaCl treatments. As to ionic pattern, the $Na^+$ and $Cl^-$contents in leaves of G. max, P. angularis and A. julibrissin progressively increased with higher contents of external salinity. Compared to other plants, C. tora excluded $Na^+$more efficiently and maintained rather constant ionic contents in spite of high salt levels. With a few exception, these 4 legume plants exhibited better growth by the external nitrogen supply rather than the contribution of symbiotic nitrogen fixation only under saline condition.

Basic Study of Distribution Management Model of the Free-Form Concrete Panels (SCM 기법에 의한 비정형 콘크리트 패널의 공급관리 모델 기초연구)

  • Cho, Wonhyun;Na, Youngju;Kim, Sunkuk
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.05a
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    • pp.115-116
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    • 2016
  • Numerous of free-form buildings come up with external appearances using various types of free-form panels. If the panel types produced, transport and installation order and maintenance history are not properly managed, it is difficult to complete a given project successfully. For free-form building projects that satisfy 5 factors (proper time, place, price, product and quantity), a supply chain management technique is applied for distribution management of free-form concrete panels. In addition, the study listed the whole production process of free-form concrete panels and any necessary information, and suggested a basic model for the management. The study result will be a great help in effective distribution management of free-form panels for free-form building projects.

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Heat Load Characteristics of Sea Water Cooling Apparatus on Inshore Fishing Boat (연근해 어선용 해수냉각장치의 열부하특성)

  • 한인근;문춘근;김재돌;윤정인
    • Journal of Advanced Marine Engineering and Technology
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    • v.25 no.6
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    • pp.1317-1323
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    • 2001
  • The circumstance is giving the blow against fishermen with the incoming-decreasing and the difficulty of crew's supply & demand and management. In addition, the depression of the external situation like the departure of WTO system and the plan of EEZ proclaim is forcing fishery into improving their fishing condition. By this international and domestic circumstance, development of the sea water cooling apparatus for fish hold storage is demanded sincerely. First of all, we Investigated load characteristics which based on development of sea water cooling system and optimum fish hold storage. The experimental results is as follows. In creasing the speed of compressor and mass blew rate of refrigerant, the temperature of NaCl solution is low. And the load characteristics experiment on fish hold storage outlet is as fellows. As time goes by, increasing the mass flow rate of NaCl solution, temperature difference between inlet and outlet is small in a model of fish hold storage. These results provide many useful informations applicable to an actual design of sea water cooling system and optimum fish hold storage.

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Effects of Salinity on Leaf Growth and Photosynthesis in Rice (염처리가 수도잎의 신장 및 광합성능에 미치는 영향)

  • Lee, Kang-Sae
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.36 no.1
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    • pp.22-33
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    • 1991
  • The studies aimed to distinguish between initial (ionic or osmotic) effects of salinisation on growth and the longer-term consequences of excessive salt accumulation. Tall and dwarf varieties of rice were used to provide different growth rates. There was no significant effect upon the day-to-day pattern of growth, upon the ultimate length of leaves that were developing at the time of, or shortly after, salinisation with 50 mM NaCl. Leaves that developed after prolonged exposure of the plants to salinity were shorter. Addition of NaCl, KCl or mannitol to the root medium brought about a cessation of leaf elongation within one minute. Growth at a reduced rate restarted abruptly after a lag period that depended upon the external concentration. Elongation rate recovered to its original value within 24 hours after exposure to 50 mM NaCl, though not at higher concentrations. Addition of NaCl at concentrations up to 100 mM elicited no short-term effect upon photsynthetic gas exchange. No change in turgor pressure was detectable in the growing zone with the resolution of the miniature pressure probe used (about 70 kPa). It is concluded that the initial growth reduction in rice caused by salinisation is due to a limitation of water supply. A clear distinction is made between the initial effects of salt which are recoverable, and the long-term effects which result from the accumulation of salt within expanded leaves.

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Effects of Nitrogen Application on the Patterns of Amino Acids, Nitrogen Contents and Growth Response of Four Legume Plants under Saline Conditions (염분 환경하에서 4종 콩과식물의 생장, 아미노산 및 질소함량에 미치는 질소원의 영향)

  • 배정진;추연식;김진아;노광수;송종석;송승달
    • The Korean Journal of Ecology
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    • v.26 no.3
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    • pp.135-142
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    • 2003
  • Four legume plants showed better growth by the external nitrogen supply rather than the symbiotic nitrogen fixation only under salt additions. In case of Glycine max and Phaseolus angularis, total nitrogen contents decreased by high salinity level but their amino acid levels significantly increased with the increase of salt treatments and indicated high soluble-/insoluble-N ratios. Cassia tora and Albizzia julibrissin contained less amino acids than G. max and P. angularis but total N (esp. insoluble N fraction) increased with higher salt levels. Asparagine occurred as a main amino acid especially in G. max and P. angularis and can be seen as potential N-storage form in these plants. It might be play an important role for the osmoregulation mechanism under the saline condition. Meanwhile, to investigate what kinds of nitrogen sources are effective for overcoming salt stress on soybean plants, various N forms and concentrations (NH₄NO₃-N, NO₃-N, NH₄NO₃-N; 2.5 and 5 mM) were additionally supplied to the salt gradient medium. Soybean plants treated with NH₄NO₃-N showed the best growth up to 40 mM NaCl and NO₃- fed plants indicated good growth even at 80 mM NaCl treatments. Contrary to NH₄NO₃- and NO₃- fed plants, NH₄/sup +/- fed plants showed remarkable growth reduction and died by 40 and 80 mM NaCl treatments after the first harvest (15th day). Consequently, these results suggest that salt excluding and resistant capacities of soybean plants under NaCl treatments are increased in order of NH₄ - N, control, NO₃- N and NH₄NO₃- N depending on N concentration except NH₄- N treatments.

Variation of Catecholamine Content in Rat Vline under the Immo bilization Stress (흰쥐의 구속 stress 에 의한 catecholamine 의 변화)

  • 김형석
    • Journal of environmental and Sanitary engineering
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    • v.6 no.2
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    • pp.59-68
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    • 1991
  • The word of stress was wsed in the field of physics as a external force from 17th century, but the meaning of this stress had chafed to the internal and exteral demand fort the human body in medical area. All the stumulants which make stress was called as j stressor. When animals get stress blucose excreted from liver to adapt for the emergent state ant some related hormone secrete convert protein and lipid to glucose for the purpose of energy supply to muscle. As a results heart rate, blood pressure, respiration rate are increased and musclse are strengthed. These physiolgical reactions ate controlled by autonomic nerve system under the control of hyothalamus in brain. Autonomic nerve system and endocrinary system are react harmoiously to stress reaction. According to the stress reaction, adrenomedullary system are stimulated, and epinephrine, morepinephrine are exceted. Author experimented the effect of the immobilizational stress to rat by analyzing the variaition of catecholamine secrction, the Na concentration and the effect of the antistresf effect by Panax Ginseng which is a traditional Korean herb medicine. The concentration of the norepinephrine, epinephrin, and dopamin in normal rat are 1 578 ng/ml, 0.365 ng/ml, and 0.731 ng/ml respectively, but in the immobilyzed stress groIn the concentration were increased to 1.915 ng.ml, 0.854 ng/ml, and 2,361 ng/ml which she the high show the higher concentration of catecholamine to stressor.

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Performance Test of the Ultralow Background Gamma-Ray Measurement System (극저준위 백그라운드 감마선 측정시스템의 성능시험)

  • Na, Won-Woo;Lee, Young-Gil
    • Journal of Radiation Protection and Research
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    • v.22 no.3
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    • pp.219-226
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    • 1997
  • Ultralow background gamma-ray measurement system was installed to measure and analyze gamma-rays emitted from environmental and swipe samples. The background reduction techniques applied on this system are the passive shielding to surround the HPGe detector, an active external anticosmic shield to shield cosmic-rays and the nitrogen gas supply to minimize the introduction of ubiquitous radon decay nuclei. The performance test result showed that the system background at energies between 50 keV and 2 MeV is reduced about $10^{-2}$ order and the MDA is so low as to be suitable for the environmental sample analysis. But it is appeared that the neutron produced by cosmic-ray increases the background at low energy region.

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