• 한국초전도ㆍ저온공학회논문지
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• 제21권1호
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• pp.40-44
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• 2019

This study investigates mixtures of water and cryoprotectant agents (CPAs) to store high-grade cold energy. Although water is an ideal material for a cold thermal storage (CTS) due to its high specific heat, undesirable volume expansion may cause structural stresses during freezing. The volume expansion can be alleviated by adding the CPAs to water. However, the CPA aqueous solutions not only have different thermal properties but also transit to amorphous state different from pure water. Therefore, these characteristics should be considered when using them as material of the CTS. In experiments, glycerol and dimethyl sulfoxide (DMSO) are selected as the candidate CPA. The volume expansion of the solution is measured by an in-situ strain gauge in low temperature region. The specific heat capacity of the solution is also measured by differential scanning calorimetry (DSC). Both the amount of volume expansion and the specific heat capacity of the CPA aqueous solution decrease in the case of higher concentration of CPA. These characteristics should be contemplated to select optimal aqueous solution for CTS for liquid air energy storage system (LAES). The CPA solutions have advantages of having wide temperature range to utilize the latent heat of water and higher sensible heat of the CPA. The CPA solutions which can satisfy the allowable stress of the structure are determined. Consequently, among the CPA solutions investigated, DMSO 20% w/w solution is the most suitable for the CTS.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 춘계학술발표대회 논문집
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• pp.73-76
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• 2002

This study developed SiC/Al composites for electronic packaging to which reinforcements were added with the volume fractions of 49%, 56% and 63% by the squeeze casting method. 0.8 wt.% of the inorganic binder as well as the $Al_2O_3$ fiber and SiC particles with the volume fraction of 1:10 were added to the SiC/Al composites For the produced SiC/Al composites, the CTEs (coefficients of thermal expansion) were measured from 30 to $300^{\circ}C$ and compared with the FEM numerical simulation to analyze the temperature dependent properties. The experiment showed the CTEs of SiC/Al composites that were intermediate values of those of Rule of Mixture and Turner's Model. The CTEs were close to Turner's Model in the room temperature and approached the Rule of Mixture as the temperature increases. These properties analyzed from the difference of the average stress acting between the matrix and the reinforcements proposed in this study

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2000년도 춘계학술대회논문집
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• pp.402-406
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• 2000

In the Over-The-Range, the outlet size is limited by the industrial standards. Therefor to enlarge the volume of cavity, the installation height of ventilation fan is become small, the system resistance is higher than before. For that reason, the important design variables such as the diameter of a fan, the scroll expansion angle, etc. which play the significant role on flow rate and noise, are confined. In this study, we made an experiment of the diameter of fans relation to scroll expansion angle and investigated flow rate of the length of fans in enlarged cavity volume of OTR, and then we designed the new scroll to improve the flow rate and noise level. As a result, flow rate increased to 110% compared to current scroll and the blade passing frequency of a fan is disappeared by inclined cut-off shapes.

• 한국자동차공학회논문집
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• 제4권4호
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• pp.179-189
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• 1996

An unstructured grid finite-volume method has been applied to predict the linear and nonlinear attenuation characteristics of the expansion chamber silencer system. In order to achieve a grid flexibility and a solution adaptation for geometrically silencer system. In order to achieve a grid flexibility and a solution adaptation for geometrically complex flow regions associated with the actual silencers, the unstructured mesh algorithm in context with the node-centered finite volume method has been employed. The present numerical model has been validated by comparison with the analytical solutions and the experimental data for the acoustic field of the concentric expansion chamber with and without pulsating flows, as well as the axisymmetric blast flowfield with open end. Effects of the chamber geometry on the nonlinear wave attenuation characteristics is discussed in detail.

• 설비공학논문집
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• 제9권1호
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• pp.23-32
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• 1997

Swirling turbulent flows downstream of an abrupt axisymmetric expansion in a pipe are analyzed numerically by a second-order turbulence closure. Predictions for the flows without swirl and with strong swirl are obtained. The governing differential equations are discretized by finite volume approach. The results show that the on-axis recirculation induced by the strong swirl is correctly reproduced. The predictions for mean velocity components and turbulent normal stresses agree well with experimental data far downstream of expansion, but show large discrepancies in wall-bounded recirculation zone.

• Geomechanics and Engineering
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• 제23권6호
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• pp.561-573
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• 2020

The creep and consolidation behaviors of clays subjected to thermal cycles are of fundamental importance in the application of energy geostructures. This study aims to numerically investigate the physical mechanisms for the temperature-triggered volume change of saturated clays. A recently developed thermodynamic framework is used to derive the thermo-mechanical constitutive model for clays. Based on the model, a fully coupled thermo-hydro-mechanical (THM) finite element (FE) code is developed. Comparison with experimental observations shows that the proposed FE code can well reproduce the irreversible thermal contraction of normally consolidated and lightly overconsolidated clays, as well as the thermal expansion of heavily overconsolidated clays under drained heating. Simulations reveal that excess pore pressure may accumulate in clay samples under triaxial drained conditions due to low permeability and high heating rate, resulting in thermally induced primary consolidation. Results show that four major mechanisms contribute to the thermal volume change of clays: (i) the principle of thermal expansion, (ii) the decrease of effective stress due to the accumulation of excess pore pressure, (iii) the thermal creep, and (iv) the thermally induced primary consolidation. The former two mechanisms mainly contribute to the thermal expansion of heavily overconsolidated clays, whereas the latter two contribute to the noticeable thermal contraction of normally consolidated and lightly overconsolidated clays. Consideration of the four physical mechanisms is important for the settlement prediction of energy geostructures, especially in soft soils.

• 한국표면공학회지
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• 제51권1호
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• pp.47-53
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• 2018

Sn-based lithium-ion batteries have low cost and high theoretical specific capacity. However, one of major problem is the capacity fading caused by volume expansion during lithiation/delithiation. In this study, 3-dimensional foam structure of Cu-Sn alloy is prepared by co-electrodeposition including large free space to accommodate the volume expansion of Sn. The Cu-Sn foam structure exhibits highly porous and numerous small grains. The result of EDX mapping and XPS spectrum analysis confirm that Cu-Sn foam consists of $SnO_2$ with a small quantity of CuO. The Cu-Sn foam structure electrode shows high reversible redox peaks in cyclic voltammograms. The galvanostatic cell cycling performances show that Cu-Sn foam electrode has high specific capacity of 687 mAh/g at a current rate of 50 mA/g. Through SEM observation after the charge/discharge processes, the morphology of Cu-Sn foam structure is mostly maintained despite large volume expansion during the repeated lithiation/delithiation reactions.

• 한국재료학회지
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• 제34권7호
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• pp.370-376
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• 2024

In this study, we report significant improvements in lithium-ion battery anodes cost and performance, by fabricating nano porous silicon (Si) particles from Si wafer sludge using the metal-assisted chemical etching (MACE) process. To solve the problem of volume expansion of Si during alloying/de-alloying with lithium ions, a layer was formed through nitric acid treatment, and Ag particles were removed at the same time. This layer acts as a core-shell structure that suppresses Si volume expansion. Additionally, the specific surface area of Si increased by controlling the etching time, which corresponds to the volume expansion of Si, showing a synergistic effect with the core-shell. This development not only contributes to the development of high-capacity anode materials, but also highlights the possibility of reducing manufacturing costs by utilizing waste Si wafer sludge. In addition, this method enhances the capacity retention rate of lithium-ion batteries by up to 38 %, marking a significant step forward in performance improvements.

• Nuclear Engineering and Technology
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• 제54권7호
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• pp.2359-2366
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• 2022

Selecting graphite grades with superior irradiation characteristics is important task for designers of graphite moderation reactors. To provide reference information and data for graphite selection, the effects of irradiation on three fine-grained, iso-molded nuclear grade graphites, ETU-10, IG-110, and NBG-25, were compared based on irradiation-induced changes in volume, thermal conductivity, dynamic Young's modulus, and coefficient of thermal expansion. Data employed in this study were obtained from reported irradiation test results in the high flux isotope reactor (HFIR)(ORNL) (ETU-10, IG-110) and high flux reactor (HFR)(NRL) (IG-110, NBG-25). Comparisons were made based on the irradiation dose and irradiation temperature. Overall, the three grades showed similar irradiation-induced property change behaviors, which followed the historic data. More or less grade-sensitive behaviors were observed for the changes in volume and thermal conductivity, and, in contrast, grade-insensitive behaviors were observed for dynamic Young's modulus and coefficient of thermal expansion changes. The ETU-10 of the smallest grain size appeared to show a relatively smaller VC to IG-110 and NBG-25. Drastic decrease in the difference in thermal conductivity was observed for ETU-10 and IG-110 after irradiation. The similar irradiation-induced properties changing behaviors observed in this study especially in the DYM and CTE may be attributed to the assumed similar microstructures that evolved from the similar size coke particles and the same forming method.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2000년도 제20회 KOSCO SYMPOSIUM 논문집
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• pp.189-196
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• 2000

A numerical simulation was conducted to analyze the interaction of flame and vortices. The characteristic scales of flame and vortices were limited in the thin laminar flamelet regime. Within this regime, flame is assumed as discontinuity surface and its motion in flow field was described by G-equation instead of full governing equations. Additional approximations include distribution of line volume sources on flame surface to simulate effect of volume expansion. Contrast to previous calculations, current study employed vortex transport equation to evaluate attenuation and smearing of vortices. Two extreme conditions of frozen vortex and frozen flame were considered to validate the current method. Comparison with direct numerical simulation resulted in satisfactory quantitative agreement with higher computational efficiency which warrants the usefulness of the present model in more complex situation.