• 소성∙가공
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• 제18권5호
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• pp.401-409
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• 2009

The change of the thermal properties of exothermic and insulating materials with the mixing condition of raw materials which is the most important factor for exothermic & insulating materials was investigated by using the evaluation system of the thermal properties of exothermic and insulating materials. In this study, the effect of the thermal properties of the exothermic & insulating materials such as exothermic properties, endothermic properties, insulating properties, maximum temperature of molten metal, ignition time of exothermic & insulating materials and temperature recovery time on the mixing ratio of reductant and oxidant, types of reductant, and particle sizes of reductants was examined. It could be expected to design the mixing condition of raw materials for various exothermic and insulating materials.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2009년도 춘계학술대회 논문집
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• pp.118-126
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• 2009

The change of the thermal properties of exothermic & insulating materials with mixing condition of raw materials which is the most important factor for exothermic & insulating materials was investigated by using the evaluation system of the thermal properties of exothermic & insulating materials. In this study, the effect of the thermal properties of the exothermic & insulating materials such as exothermic properties, endothermic properties, insulating properties, maximum temperature of molten metal, ignition time of exothermic & insulating materials and temperature recovery time on the mixing ratio of reductant and oxidant, types of reductant, and particle sizes of reductants was examined. It could be expected to design the mixing condition of raw materials for various exothermic & insulating materials.

• Computers and Concrete
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• 제19권6호
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• pp.659-666
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• 2017

Based on the Arrhenius equations, several hydration exothermic models that precisely calculate the influence of concrete's self-temperature duration on its hydration exothermic rate have been presented. However, the models' convergence is difficult to achieve when applied to engineering projects, especially when the activation energy of the Arrhenius equation is precisely considered. Thus, the models' convergence performance should be improved. To solve this problem and apply the model to engineering projects, the relationship between fast iteration and proper expression forms of the adiabatic temperature rise, the coupling relationship between the pipe-cooling and hydration exothermic models, and the influence of concrete's self-temperature duration on its mechanical properties were studied. Based on these results, the rapid convergence of the hydration exothermic model and its coupling with pipe-cooling models were achieved. The calculation results for a particular engineering project show that the improved concrete hydration exothermic model and the corresponding mechanical model can be suitably applied to engineering projects.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2008년도 춘계학술대회 논문집
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• pp.46-51
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• 2008

In this study, evaluation system of the thermal properties of the exothermic agents was investigated. Exothermic agents property evaluation system was developed by metering variation of power supply. Thermal properties of exothermic agents was affected by material mixture condition of exothermic agents, however, it was not affected by temperature. It is possible to make various exothermic agents by means of regulating thermal properties which is based on property evaluation system of exothermic agents.

• 대한치과의사협회지
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• 제10권8호
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• pp.531-534
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• 1972

The author measured exothermic temperature of the 5 kinds of zinc phosphate cement and 3 kinds of copper phosphate cement during setting process. Cements were mixed on the glass slab with flexible steel spatula at room temperature (25.8℃) for one minute (spatulating speed was 100 strokes per minute) and placed in the incubator of which temperature was held at 37℃ and thermometer was inserted into the cement mass. The powder liquid ration was 3.0gm:1ml and 1.5gm:1ml. The results were as follows. 1) The heat generated after mixing these cements was under 47.22℃. 2) The range of thermal change of the zinc phosphate cements during setting process was wider than copper phosphate cements. 3) The exothermic temperature from the thin mix was higher than thick mix. 4) The exothermic temperature of the zinc phosphate cements was higher than copper phosphate cements.

• 소성∙가공
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• 제17권5호
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• pp.356-363
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• 2008

An evaluation system of the thermal properties of exothermic & insulating materials was developed. By measuring the power supply of the induction furnace, the thermal property of exothermic & insulating materials could be evaluated with high reproducibility at elevated temperature of molten steel. The thermal properties of exothermic & insulating materials were affected by mixing condition of raw materials. The effect of main components of exothermic & insulating materials such as metallic aluminum and $Fe_2O_3$ powder on the exothermic and insulating properties was examined. It could be expected to design and develop various exothermic & insulating materials by means of the evaluation system of the thermal properties.

• Carbon letters
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• 제10권3호
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• pp.202-207
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• 2009

Pitch-based carbon fiber tows were prepared from naphtha cracking bottom oil by reforming and carbonization. The relationship between exothermic heat and carbon contents of the fiber was investigated by changing the carbonization conditions. The carbon contents and the crystallinities of isotropic pitch-based carbon fibers were 86.8~93.8 wt% and 33.7~40.1%, respectively, which were linearly proportional to the increase of carbonization temperature from 700 to $1000^{\circ}C$. The exothermic heat (temperature increase) of fiber tows was measured in a short time, which was also linearly proportional to the increase of carbon contents due to the increase of crystallinity, even though the crystallinity was low. Therefore, the carbon contents or carbonization degree of fibers can rapidly and indirectly be estimated by measuring the surface temperature increase of fibers.

• 한국안전학회지
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• 제17권2호
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• pp.39-44
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• 2002

This study was investigated the thermal decomposition characteristics of azo type sponge blowing agent azodicarbonamide(ADCA) using differential scanning calorimeter(DSC). The experimental results showed that the exothermic onset $temperatures(T_{o})$ for ADCA were about $201{\sim}206^{\circ}C$ and evolution heats(Q) were about $144{\sim}150cal/g$. The exothermic onset $temperatures(T_{o})$, exothermic maximum $temperature(T_{m})$ and exothermic final $temperature(T_{f})$ were decreased by decreasing particle size of ADCA and evolution heats(Q) were increased with it. $T_{o}$ and Q for $6.1{\sim}7.2{\mu}m$ ADCA were increased by increasing heating rate at constant sample weight and activation energy was about 37.29kcal/mol. A positive gas pressure was employed in the elucidation of the decomposition behavior of ADCA because it sublimes during linear heating at atmospheric pressure. $T_{o}$ and Q of ADCA tended to increase with a pressure in air or nitrogen. In the case of azo dye, experimental results showed that $T_{o}$ were about $280{\sim}420^{\circ}C$ and Q were about $2{\sim}30cal/g$.

• Archives of Metallurgy and Materials
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• 제64권3호
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• pp.931-934
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• 2019

Al-CuO is a thermite material exhibiting the exothermic reaction only when aluminum melts. For wide spread of its application, the reaction temperature needs to be reduced in addition to the enhancement of total reaction energy. In the present study, a thermite nanocomposite with a large contact area between Al and CuO was fabricated in order to lower the exothermic reaction temperature and to improve the reactivity. A cryomilling process was performed to achieve the nanostructure, and the effect of composition on the microstructure and its reactivity was studied in detail. The microstructure was characterized using SEM and XRD, and the thermal property was analyzed using DSC. The results show that as the molar ratio between Al and CuO varies, the fraction of uniform nanocomposite structure was changed affecting the exothermic reaction characteristics.

• 한국안전학회지
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• 제16권2호
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• pp.75-79
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• 2001

For handling and storage of reactive chemicals, the hazard evaluations have been extremely important. In the chemical industry, the most concerns are focused on the thermal harzards such as runaway reactions and thermal decompositions, which are mostly governed by thermodynamics and reaction kinetics or these reactive chemical in the system. This study no investigated the thermal decomposition characteristics of nitrophenylhydrazine isomers by using differential scanning calorimeter(DSC) and accelerating rate calorimeter(ARC). Experimental results showed that exothermic onset-temperatures in nitrophenylhydrazine(NPH) isomers were about 160-$210^{\circ}C$ by DSC and 100-$150^{\circ}C$ by ARC. The decomposition temperature acquired by ARC was about 50-$60^{\circ}C$ lower than that by DSC. Reaction heats were about 40-100cal/g by DSC and 330-750ca1/g by ARC. While ortho isomer of NPH show two distinct exothermic peaks, para isomer shows a single peak in DSC curves. The first exothermic peak for 2-NPH is mainly due to intramolecular dehydration forming 1-hydroxybenzotriazole(HOBT) and the second exothermic peak is mainly due to the decomposition of HOBT formed in the first step of decomposition. The exothermin peak in the DSC curve for 4-NPH is mainly due to dissociation of hydrazino and nitro groups.