• 반도체디스플레이기술학회지
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• 제18권1호
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• pp.105-111
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• 2019

The TADF (Thermally Activated Delayed Fluorescence)-based OLED patents were analyzed and 4410 of patents were selected at the first step. And 975 patents were screened at second step. Finally, 39 key patents were selected. Patent qualitative analysis was performed in these patents to find which of the four property (lifetime, efficiency, color purity, driving voltage) of TADF was improved. Also, the variation of the hosts and dopants in patented TADF material were surveyed and their combination was analyzed. According to the analysis of the variation and the combination, some of TADF compounds were used as an assistant dopant to transfer energy. In addition, it tended to transfer energy by forming exciplex that shows TADF characteristics. These were similar to the mechanism of the introduced hyper fluorescence and could solve the inherent TADF problems. Finally, patent citation network was illustrated to visualize the patent citations and citations relationship of the major applicants in the current TADF-based OLED technology. The leading patent applicant organization was revealed as Idemitsu Kosan, Semiconductor Energy Laboratory, UDC, Princeton University, Merck and Nippon Steel & Sumikin Chemical, which had lots of reference patents 559, 524, 477, 310, 258, and 167, respectively.

• 동력기계공학회지
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• 제13권6호
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• pp.13-21
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• 2009

This basic study is required to examine spray or jet behavior depending on fuel phase. In this study, analyses of diesel fuel(n-Tridecane, $C_{13}H_{28}$) spray and natural gas fuel(Methane, $CH_4$) jet under high temperature and pressure are performed by a general-purpose program, ANSYS CFX release 11.0, and the results of these are compared with experimental results of diesel fuel spray using the exciplex fluorescence method. The simulation results of diesel spray is analyzed by using the combination of Large-Eddy Simulation(LES) and Lagrangian Particle Tracking(LPT) and of a natural gas jet is analyzed by using Multi-Component Model(MCM). There are two study variables considered, that is, ambient pressure and injection pressure. In a macroscopic analysis, the higher ambient pressure is, the shorter spray or jet tip penetration is at each time after start of injection. And the higher injection pressure is, the longer spray or jet tip penetration is at each time after start of injection. When liquid fuel is injected, droplets of the fuel need some time to evaporate. However, when natural gas fuel is injected, the fuel does not need time to evaporate. Gas fuel consists of minute particles. Therefore, the gas fuel is mixed with the ambient gas more quickly at the initial time of injection than the liquid fuel is done. The experimental results also validate the usefulness of this analysis.

• Journal of Mechanical Science and Technology
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• 제16권12호
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• pp.1702-1709
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• 2002

This paper analyzes heterogeneous distribution of branch-like structure at the downstream region of the spray. The liquid and vapor phase of the spray are obtained using a 35㎜ still camera and CCD camera in order to investigate spray structure of evaporating diesel spray. There have been many studies conducted on diesel spray structure but have yet only focused on the analyses of 2-D structure. There are a few information which is concerned with 3-D structure analysis of evaporating spray. The heterogeneous distribution of droplets in inner spray affects the mixture formation of diesel spray and the combustion characteristics of the diesel engines. In this study, the laser beam of 2-D plane was used in order to investigate 3-D structure of evaporating spray The incident laser beam was offset on the central axis of the spray. From the analysis of images taken by offset laser beam, we will examine the formation mechanism of heterogeneous distribution of the diesel spray by vortex flow at the downstream of the spray. The images of liquid and vapor phase of free spray are simultaneously taken through an exciplex fluorescence method. Through this, the branch-like structure consisting of heterogeneous distribution of the droplets forms high concentrated vapor phase at the periphery of droplets and at the spray tip.

• International Journal of Automotive Technology
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• 제7권5호
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• pp.585-593
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• 2006

The effect of the shape of the side wall on vaporization and fuel mixture were investigated for the impinging spray of a direct injection(DI) gasoline engine under a variety of conditions using the LIEF technique. The characteristics of the impinging spray were investigated under various configurations of piston cavities. To simulate the effect of piston cavity configurations and injection timing in an actual DI gasoline engine, the parameters were horizontal distance from the spray axis to side wall and vertical distance from nozzle tip to impingement plate. Prior to investigating the side wall effect, experiments on free and impinging sprays for flat plates were conducted and these results were compared with those of the side wall impinging spray. For each condition, the impingement plate was located at three different vertical distances(Z=46.7, 58.4, and 70 mm) below the injector tip and the rectangular side wall was installed at three different radial distances(R=15, 20, and 25 mm) from the spray axis. Radial propagation velocity from spray axis along impinging plate became higher with increasing ambient temperature. When the ambient pressure was increased, propagation speed reduced. High ambient pressures tended to prevent the impinging spray from the propagating radially and kept the fuel concentration higher near the spray axis. Regardless of ambient pressure and temperature fully developed vortices were generated near the side wall with nearly identical distributions, however there were discrepancies in the early development process. A relationship between the impingement distance(Z) and the distance from the side wall to the spray axis(R) was demonstrated in this study when R=20 and 25 mm and Z=46.7 and 58.4 mm. Fuel recirculation was achieved by adequate side wall distance. Fuel mixture stratification, an adequate piston cavity with a shorter impingement distance from the injector tip to the piston head should be required in the central direct injection system.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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• pp.1520-1521
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• 2008

There are several ways to demonstrate white organic light emitting diodes (OLEDs) for displays and solid state lighting applications. Among these approaches are the stacked three primary or two complementary colors light-emitting layers, multiple-doped emissive layer, and excimer and exciplex emission [1-10]. We report on white phosphorescent excimer devices by using two light emitting materials based on platinum complexes. These devices showed a peak EQE of 15.7%, with an EQE of 14.5% (17 lm/W) at $500\;cd/m^2$, and a noticeable improvement in both the CIE coordinates (0.381, 0.401) and CRI (81). Devices with the structure ITO/PEDOT:PSS/TCTA (30 nm)/26 mCPy: 12% FPt (10 nm) /26 mCPy: 2% Pt-4 (15 nm)/BCP (40 nm)/CsF/Al [device 1], ITO/PEDOT:PSS/TCTA (30 nm)/26 mCPy: 2% Pt-4 (15 nm)/26 mCPy: 12% FPt (10 nm)/BCP (40 nm)/CsF/Al [device 2], and ITO/PEDOT:PSS/TCTA (30 nm)/26 mCPy: 2% Pt-4: 12% FPt (25 nm)/BCP (40 nm)/CsF/Al [device 3] were fabricated. In these cases, the emissive layer was either the double-layer of 26 mCPy:12% FPt and 15 nm 26 mCPy: 2% Pt-4, or the single layer of 26mCPy with simultaneous doping of Pt-4 and FPt. Device characterization indicates that the CIE coordinates/CRI of device 2 were (0.341, 0.394)/75, (0.295, 0.365)/70 at 5 V and 7 V, respectively. Significant change in EL spectra with the drive voltage was observed for device 2 indicating a shift in the carrier recombination zone, while relatively stable EL spectra was observed for device 1. This indicates a better charge trapping in Pt-4 doped layers [10]. On the other hand, device 3 having a single light-emitting layer (doped simultaneously) emitted a board spectrum combining emission from the Pt-4 monomer and FPt excimer. Moreover, excellent color stability independent of the drive voltage was observed in this case. The CIE coordinates/CRI at 4 V ($40\;cd/m^2$) and 7 V ($7100\;cd/m^2$) were (0.441, 0.421)/83 and (0.440, 0.427)/81, respectively. A balance in the EL spectra can be further obtained by lowering the doping ratio of FPt. In this regard, devices with FPt concentration of 8% (denoted as device 4) were fabricated and characterized. A shift in the CIE coordinates of device 4 from (0.441, 0.421) to (0.382, 0.401) was observed due to an increase in the emission intensity ratio of Pt-4 monomer to FPt excimer. It is worth noting that the CRI values remained above 80 for such device structure. Moreover, a noticeable stability in the EL spectra with respect to changing bias voltage was measured indicating a uniform region for exciton formation. A summary of device characteristics for all cases discussed above is shown in table 1. The forward light output in each case is approximately $500\;cd/m^2$. Other parameters listed are driving voltage (Bias), current density (J), external quantum efficiency (EQE), power efficiency (P.E.), luminous efficiency (cd/A), and CIE coordinates. To conclude, a highly efficient white phosphorescent excimer-based OLEDs made with two light-emitting platinum complexes and having a simple structure showed improved EL characteristics and color properties. The EQE of these devices at $500\;cd/m^2$ is 14.5% with a corresponding power efficiency of 17 lm/W, CIE coordinates of (0.382, 0.401), and CRI of 81.